perfluoronorbornene | 33649-91-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: perfluoronorbornene
• 英文别名: Decafluor-bicyclo<2.2.1>hept-2-en；Decafluor-bicyclo[2.2.1]hept-2-en；1,2,3,4,5,5,6,6,7,7-decafluorobicyclo[2.2.1]hept-2-ene
• CAS: 33649-91-1
• 化学式: C₇F₁₀
• 分子量: 274.061
• InChiKey: JIUPHDOASPDSEF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  六氟环丁烯 生成 perfluoronorbornene
  参考文献：
  名称：

  CHAMBERS, R. D.;JONES, C. G. P.;TAYLOR, G.;POWELL, R. L., J. FLUOR. CHEM., 1981, 18, N 4, 407-412

  摘要：

  DOI：

文献信息

• Reactions involving fluoride ion. Part 24 [1]. Syntheses from perfluorocyclobutene
  作者：Richard D. Chambers、Colin G.P. Jones、Graham Taylor、Richard L. Powell

  DOI：10.1016/s0022-1139(00)82658-5

  日期：1981.10

  Passage of perfluorocyclobutene, in a flow system, over caesium fluoride at 590–600o provides a synthesis of hexa- fluoro-2-butyne in high yield. In a similar process, using glass tubes, tricyclo[3.3.0.02,6]octane and bicyclo[2.2.1] -2-heptene were obtained.

  在流动系统中，全氟环丁烯在590-600 o的氟化铯上通过可高产率地合成六氟-2-丁炔。在类似的过程中，使用玻璃管，获得了三环[3.3.0.0 2，6 ]辛烷和双环[2.2.1] -2-庚烯。
• FLUORINATED CYCLOOLEFIN POLYMERS, PROCESSES FOR PREPARATION OF FLUORINATED CYCLOOLEFIN MONOMERS AND POLYMERS THEREOF, AND USE OF THE SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1298156A1

  公开（公告）日：2003-04-02

  The present invention is to provide a fluorine-containing polymer having excellent light transmission in the vacuum ultraviolet region of not more than 193 nm, a monomer favorably used for preparing the fluorine-containing polymer, a process for preparing the fluorine-containing polymer, and uses of the fluorine-containing polymer. The fluorine-containing polymer has at least a repeated unit structure represented by the following formula (1) and has an absorption coefficient of not more than 3.0 µm-1 at 157 nm of ultraviolet rays. wherein R1 to R12 are each fluorine, a fluorine-containing alkyl group of 1 to 20 carbon atoms, or the like; X1 is -CRaRb-, -NRa- or -PRa- (Ra and Rb are each fluorine, a fluorine-containing alkyl group of 1 to 20 carbon atoms, hydrogen, -O-, -S-, an alkyl group of 1 to 20 carbon atoms, or the like); at least one of R1 to R12 and X1 is fluorine or a fluorine-containing group; and n is 0 or an integer of 1 to 3.

  本发明旨在提供一种在不超过 193 纳米的真空紫外线区域具有优异透光性的含氟聚合物、一种可用于制备该含氟聚合物的单体、一种制备该含氟聚合物的工艺以及该含氟聚合物的用途。含氟聚合物至少具有下式（1）所代表的重复单元结构，并且在 157 纳米紫外线下的吸收系数不超过 3.0 µm-1。 其中 R1 至 R12 分别是氟、1 至 20 个碳原子的含氟烷基或类似物；X1 是-CRaRb-、-NRa- 或-PRa-（Ra 和 Rb 分别是氟、1 至 20 个碳原子的含氟烷基、氢、-O-、-S-、1 至 20 个碳原子的烷基或类似物）；R1 至 R12 和 X1 中至少有一个是氟或含氟基团；以及 n 是 0 或 1 至 3 的整数。
• METHOD FOR PRODUCING FLUORINE-CONTAINING POLYMER
  申请人：Asahi Glass Company, Limited

  公开号：EP3257885A1

  公开（公告）日：2017-12-20

  An object of the present invention is to provide a method for producing a fluorine-containing polymer from a fluorine-containing cycloolefin compound through ring-opening metathesis polymerization. The present invention relates to a method for producing a fluorine-containing polymer. The method includes subjecting at least one kind of fluorine-containing cycloolefin compound selected from the group consisting of a fluorine-containing cycloolefin compound represented by the following formula (41) and a fluorine-containing cycloolefin compound represented by the following formula (42) to ring-opening metathesis polymerization in the presence of a metal-carbene complex compound (10) having an olefin metathesis reaction activity.

  本发明的目的是提供一种通过开环偏析聚合从含氟环烯烃化合物生产含氟聚合物的方法。本发明涉及一种生产含氟聚合物的方法。该方法包括在具有烯烃偏析反应活性的金属羰基络合物（10）存在下，将至少一种选自由下式（41）表示的含氟环烯烃化合物和下式（42）表示的含氟环烯烃化合物组成的组中的含氟环烯烃化合物进行开环偏析聚合。
• Fluorinated cycloolefin polymers, processes for preparation of fluorinated cycloofefin monomers and polymers thereof, and use of the same
  申请人：——

  公开号：US20030187168A1

  公开（公告）日：2003-10-02

  The present invention is to provide a fluorine-containing polymer having excellent light transmission in the vacuum ultraviolet region of not more than 193 nm, a monomer favorably used for preparing the fluorine-containing polymer, a process for preparing the fluorine-containing polymer, and uses of the fluorine-containing polymer. The fluorine-containing polymer has at least a repeated unit structure represented by the following formula (1) and has an absorption coefficient of not more than 3.0 &mgr;m −1 at 157 nm of ultraviolet rays. 1 wherein R 1 to R 12 are each fluorine, a fluorine-containing alkyl group of 1 to 20 carbon atoms, or the like; X 1 is —CR a R b —, —NR a — or —PR a — (R a and R b are each fluorine, a fluorine-containing alkyl group of 1 to 20 carbon atoms, hydrogen, —O—, —S—, an alkyl group of 1 to 20 carbon atoms, or the like); at least one of R 1 to R 12 and X 1 is fluorine or a fluorine-containing group; and n is 0 or an integer of 1 to 3.

  本发明旨在提供一种在不超过 193 纳米的真空紫外区具有优异透光性的含氟聚合物、一种可用于制备该含氟聚合物的单体、一种制备该含氟聚合物的工艺以及该含氟聚合物的用途。含氟聚合物至少具有下式（1）表示的重复单元结构，其吸收系数不超过 3.0 &mgr;m -1 在 157 纳米紫外线下的吸收系数不超过 3.0 &mgr;m -1 。 1 其中 R 1 至 R 12 各自为氟、1 至 20 个碳原子的含氟烷基或类似物； X 1 是-CR a R b -，-NR a - 或-PR a - (R a 和 R b 均为氟、1 至 20 个碳原子的含氟烷基、氢、-O-、-S-、1 至 20 个碳原子的烷基或类似基团）；R 1 至 R 12 和 X 1 是氟或含氟基团；以及 n 是 0 或 1 至 3 的整数。
• FLUORINATED CYCLOOLEFIN POLYMERS, PROCESSES FOR THEIR PREPARATION AND THEIR USE
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1298156B1

  公开（公告）日：2005-08-17