methyldioctylsilane | 51502-63-7

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: methyldioctylsilane
• 英文别名: Di-n-Octylmethylsilane；methyl(dioctyl)silane
• CAS: 51502-63-7
• 化学式: C₁₇H₃₈Si
• 分子量: 270.574
• InChiKey: QDLASXFKKFTCAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.56
• 重原子数：
  18
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  methyldioctylsilane 在 四氯化碳 、 palladium dichloride 作用下， 反应 2.0h， 以88%的产率得到chloromethyldioctylsilane
  参考文献：
  名称：

  Trialkylsilylethynyl-substituted triphenylenes and hexabenzocoronenes: highly soluble liquid crystalline materials and their hole transport abilities

  摘要：

  Four triphenylene (TP) and four hexa-peri-hexabenzocoronene (HBC) derivatives with trialkylsilylethynyl groups were prepared and characterized by differential scanning calorimetry, polarizing optical microscopy, and X-ray diffraction measurements. All compounds were highly soluble in less-polar organic solvents and exhibited a columnar phase, Col(h) or Col(r) for the TPs, and Col(h) for the HBCs. The hole transport ability in the HBCs' columnar phase, 0.4-1.5x10(-3) cm(2) V-1 s(-1) at 40-180 degrees C, and its temperature dependence were determined by the time-of-flight method using a solution technique. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2015.05.071
• 作为产物：
  描述：

  甲基二乙氧基硅烷 、 正癸烯 在 C₂₄H₃₀ClN₃NiO₂ 、 sodium t-butanolate 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以75%的产率得到methyldioctylsilane
  参考文献：
  名称：

  烷氧基氢硅烷作为气态硅烷的替代物，用于烯烃的氢化硅烷化

  摘要：

  Me 2 SiH 2，MeSiH 3和SiH 4是气态易燃的硅烷，不方便用于化学反应。据报道，催化量的镍夹杂物和NaO t Bu可以从烯烃和烷氧基氢硅烷合成烷基氢硅烷，从而导致Me 2 SiH 2，MeSiH 3和SiH 4被Me 2（MeO）SiH取代，烯烃的氢化硅烷化反应中的Me（EtO）2 SiH和（MeO）3 SiH。还描述了反应的范围和机理。

  DOI：

  10.1021/acs.orglett.6b00792

文献信息

• Calcium Hydride Catalysts for Olefin Hydrofunctionalization: Ring‐Size Effect of Macrocyclic Ligands on Activity
  作者：Thomas Höllerhage、Danny Schuhknecht、Alisha Mistry、Thomas P. Spaniol、Yan Yang、Laurent Maron、Jun Okuda

  DOI：10.1002/chem.202004931

  日期：2021.2.10

  benzyl cation. The calcium hydride catalyzed the hydrogenation and hydrosilylation of unactivated olefins faster than the analogous calcium complex stabilized by the twelve‐membered NNNN macrocycle Me4TACD (Me4TACD=1,4,7,10‐tetramethyl‐1,4,7,10‐tetraazacyclododecane). Kinetic investigations indicate that higher catalytic efficiency for the Me5PACP stabilized calcium hydride is due to easier dissociation

  十五元NNNNN大环Me 5 PACP（Me 5 PACP=1,4,7,10,13-五甲基-1,4,7,10,13-五氮杂环十五烷）稳定了[CaH] +片段作为二聚体，具有钙处扭曲的五边形双锥体配位几何形状。通过二苄基钙与Me 5 PACP的共轭酸质子化，然后氢解或用中间体苄基钙阳离子的n OctSiH 3处理来制备氢化物络合物。氢化钙催化未活化烯烃的氢化和硅氢加成反应比十二元 NNNN 大环 Me 4 TACD 稳定的类似钙配合物更快（Me 4 TACD=1,4​​,7,10-四甲基-1,4,7,10 ‐四氮杂环十二烷）。动力学研究表明，与 Me 4 TACD 类似物相比，Me 5 PACP 稳定的氢化钙具有更高的催化效率，这是因为二聚体在溶液中更容易解离。
• Strontium Hydride Cations Supported by a Large NNNNN Type Macrocycle: Synthesis, Structure, and Hydrofunctionalization Catalysis
  作者：Thomas Höllerhage、Thomas P. Spaniol、Ambre Carpentier、Laurent Maron、Jun Okuda

  DOI：10.1021/acs.inorgchem.1c03894

  日期：2022.2.21

  (Me5PACP = 1,4,7,10,13-pentamethyl-1,4,7,10,13-pentaazacyclopentadecane) allowed the isolation of two cationic strontium hydride complexes by hydrogenolysis of benzyl precursors. Treatment of sparingly soluble [(Me5PACP)Sr(CH2Ph)2] with dihydrogen gave free Me5PACP, toluene, and oligomeric strontium hydride [SrH2]n, while hydrogenolysis in the presence of 1 equiv of the benzyl cation [(Me5PACP)Sr(CH2Ph)][B(C6H3-3

  使用 15 元 NNNNN 大环配体 Me 5 PACP（Me 5 PACP = 1,4,7,10,13-pentamethyl-1,4,7,10,13-pentaazacyclopentadecane）允许分离两种阳离子氢化锶苄基前体的氢解络合物。用二氢处理微溶的 [(Me 5 PACP)Sr(CH 2 Ph) 2 ] 得到游离的 Me 5 PACP、甲苯和低聚氢化锶 [SrH 2 ] n，同时在 1 equiv 的苄基阳离子存在下进行氢解[(Me 5 PACP)Sr(CH 2 Ph)][B(C 6 H 3 -3,5-Me 2 ) 4]能够分离热不稳定的三氢化物阳离子[(Me 5 PACP) 2 Sr 2 (μ-H) 3 ][B(C 6 H 3 -3,5-Me 2 ) 4 ]。当苄基阳离子 [(Me 5 PACP)Sr(CH 2 Ph)][BAr 4 ] 2 (Ar = C 6 H 3 -3
• Preparation of Tetraalkylsilanes from Trichloromethylsilane and Trioctylaluminum
  作者：Edward T. Sabourin、Anatoli Onopchenko

  DOI：10.1246/bcsj.62.3691

  日期：1989.11

  The synthesis of methyltrioctylsilane has been achieved in a single-step from commercially available trichloromethylsilane and trioctylaluminum. Co-products resulting from alkyl group redistribution are minimized by addition of sodium or lithium halides. Use of potassium or rubidium halides drastically changes the course of the reaction to produce methyldioctylsilane as the major product.

  利用市售的三氯甲基硅烷和三辛基铝，一步即可合成甲基三辛基硅烷。通过加入钠或锂卤化物，可将烷基重新分布产生的副产物降至最低。使用钾或铷卤化物会大大改变反应的过程，从而生成主要产品甲基二辛基硅烷。
• Silahydrocarbons from alkylchlorosilanes
  申请人：Gulf Research & Development Company

  公开号：US04595777A1

  公开（公告）日：1986-06-17

  A process for the production of tetra- and trialkylsilanes which comprises reacting (A) an alkylchlorosilane having the formula R.sub.x SiCl.sub.(4-x) wherein R is an alkyl radical containing from one to three carbon atoms per molecule and x is an integer from 0 to 3, with (B) a trialkylaluminum compound having the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different and represent alkyl radicals containing from 6 to 20 carbon atoms per molecule, in a reaction zone, said reaction being conducted under hydrosilylation conditions. Selectivity to tetra- or trialkylsilanes, respectively, is controlled by the addition of particular alkaline metal salts to the reaction zone.

  一种生产四烷基和三烷基硅烷的方法，包括将（A）化学式为R.sub.x SiCl.sub.(4-x)的烷基氯硅烷与（B）化学式为##STR1##的三烷基铝化合物在反应区反应，其中R是每个分子含有1至3个碳原子的烷基基团，x是0至3的整数。该反应在加氢硅化条件下进行。通过向反应区添加特定的碱金属盐来控制四烷基或三烷基硅烷的选择性。
• Synthesis of triorganylchlorosilanes by catalytic reaction of triorganylsilanes with chlorobenzene
  作者：Yu. I. Khudobin、N. A. Andreeva、N. P. Kharitonov、M. G. Voronkov

  DOI：10.1007/bf00923508

  日期：1974.4