4-methoxybenzoic dithioperoxyanhydride | 15088-73-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-methoxybenzoic dithioperoxyanhydride
• 英文别名: 4.4'-Dimethoxy-dibenzoyldisulfid；Disulfide, bis(4-methoxybenzoyl)；S-(4-methoxybenzoyl)sulfanyl 4-methoxybenzenecarbothioate
• CAS: 15088-73-0
• 化学式: C₁₆H₁₄O₄S₂
• 分子量: 334.417
• InChiKey: GUFGNMICNIJBSE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4-methoxybenzoic dithioperoxyanhydride 在 potassium sulphide 作用下， 生成 potassium 4-methoxythiobenzoate
  参考文献：
  名称：

  Removal of the connector on the laryngeal mask airway provides a useful alternative to the intubating laryngeal mask

  摘要：

  Purpose: We describe two cases in which fiberoptic intubation through the standard laryngeal mask airway (LMA) was successful with large-bore tracheal tubes (TTs) when an intubating LMA (ILMA) could not be used.Clinical features: Patient #, with obstructive sleep apnea, underwent elective surgical repair. His mouth opening was just under 25 mm, but difficult intubation was not anticipated. We induced general anesthesia, easily ventilated the patient by mask, and established neuromuscular blockade. Direct laryngoscopy and attempts to insert either a #5 or a #4 ILMA into the mouth failed. A standard #4 LMA, with the connector removed, was inserted, through which a 7.0 mm nasal RAE (TM) TT; fiberoptically guided, passed into the trachea at the first attempt. Patient #2, with a loosened implant after left hip arthroplasty, underwent revision prosthesis. Her neck movement was limited. We thus planned awake securing of the airway, but the patient refused. We induced anesthesia and established bag-mask-valve ventilation. The limited neck movement prevented direct laryngoscopy. Visualizing the laryngeal inlet with the fiberoptic bronchoscope (FOB) proved impossible as bloody secretions obscured the FOB's tip. Ventilation by mask was easy. As an ILMA was not available, we removed a #5 LMA's connector and passed an 8.0 mm nasal RAE (TM) TT through the LMA. fiberoptic-guided intubation was easy, In both cases, the remainder of the intraoperative course was uneventful.Conclusion: A standard LMA whose connector has been removed to allow passage of TTs of >6.0 mm internal diameter may be substituted for the ILMA when necessary.

  DOI：

  10.1007/bf03016839
• 作为产物：
  描述：

  对甲氧基苯甲酰氯 在 N,N'-dibutyl-N,N,N',N'-tetramethylethylenediammonium tetrahydroborate 、 sulfur 作用下， 以 甲醇 为溶剂， 反应 0.05h， 以81%的产率得到4-methoxybenzoic dithioperoxyanhydride
  参考文献：
  名称：

  从烷基和酰基卤快速有效地合成二硫化物

  摘要：

  使用 N ， N'-二 丁基 -N ， N ， N '， N' - N'- 四甲基-乙二胺四氢硼酸酯（ BTMETB ）或 轻度和非水条件， 可以轻松地从相应的烷基卤化物和酰基卤化物以高收率制备各种对称的二烷基二酰基和二酰基二硫化物。 N ， N'- 二苄基 -N ， N ， N '， N'- 四甲基 硼酸四氢硼酸铵（ BZTMETB ）和元素硫。通过在室温下用硼氢化钠的碱性溶液处理相应的氯化季铵或溴化季铵，可以轻松制备季铵化硼氢化物。

  DOI：

  10.1007/s00706-008-0950-0

文献信息

• Aroyl disulfides as promoter-modifiers for copolymerization of butadiene and styrene
  作者：Robert L. Frank、James R. Blegen、Archie Deutschman

  DOI：10.1002/pol.1948.120030108

  日期：1948.2

  veratroyl, p-bromobenzoyl, p-phenylbenzoyl, p-benzoylbenzoyl, p-methylsulfonylbenzoyl, p(N,N-dimethylsulfonamido)-benzoyl and -naphthoyl disulfides are promoters of the emulsion copolymerization of butadiene and styrene, but exhibit little effect on the polymer properties. Furoyl, phenyl, p-chlorophenyl and p-bromophenyl disulfides are neither promoters nor modifiers.

  苯甲酰基、茴香酰基、藜芦酰基、对溴苯甲酰基、对苯基苯甲酰基、对苯甲酰基苯甲酰基、对甲磺酰基苯甲酰基、对(N,N-二甲基磺酰氨基)-苯甲酰基和-萘甲酰基二硫化物是丁二烯和苯乙烯乳液共聚的促进剂，但表现出很小对聚合物性能的影响。呋喃酰基、苯基、对氯苯基和对溴苯基二硫化物既不是促进剂也不是改性剂。
• Diacyl Disulfide: A Reagent for Chemoselective Acylation of Phenols Enabled by 4-(<i>N</i>,<i>N</i>-Dimethylamino)pyridine Catalysis
  作者：Hong-Xin Liu、Ya-Qian Dang、Yun-Fei Yuan、Zhi-Fang Xu、Sheng-Xiang Qiu、Hai-Bo Tan

  DOI：10.1021/acs.orglett.6b02818

  日期：2016.11.4

  A general and excellent acylation reagent, diacyl disulfide, was uncovered for efficient ester formation enabled by DMAP (4-(N,N-dimethylamino)pyridine) catalysis. This protocol offered a promising synthetic platform on site-selective acylation of phenolic and primary aliphatic hydroxyl groups, which greatly expanded the realm of protecting group chemistry. The importance of the reagent was also reflected

  为了通过DMAP（4-（N，N-二甲基氨基）吡啶）催化实现有效的酯形成，发现了通用且优异的酰化试剂二酰基二硫化物。该方案为酚和伯脂族羟基的位点选择性酰化提供了一个有希望的合成平台，这大大扩展了保护基化学的领域。该试剂的重要性还体现在其出色的耐湿性，高效率以及在合成化学和生物学上有意义的天然产物修饰方面的潜力。
• PROCESS FOR PRODUCING POLYMER TERMINATED WITH OPTIONALLY PROTECTED FUNCTIONAL GROUP
  申请人：KURARAY Co. LTD.

  公开号：EP0704460A1

  公开（公告）日：1996-04-03

  A process for producing polymers having terminal functional group which may be protected, comprises polymerizing a radical-polymerizable monomer with a polymerization initiator comprising at least one member selected from the group (A) consisting of thio-S-carboxylic acids represented by the following general formula (1) and dithiocarboxylic acids represented by the following general formula (2) and at least one member selected from the group (B) consisting of polysulfides represented by the following general formula (3), polysulfides represented by the following general formula (4) and sulfoxides: wherein R¹ represents a hydrocarbon group which may have a substituent including functional group; wherein R² represents a hydrocarbon group which may have a substituent including functional group; wherein R³ and R⁴ each represents a hydrocarbon group which may have a substituent including functional group and n is an integer of 2 or more; and         R⁵- (S)m- R⁶     (4) wherein R⁵ and R⁶ each represents a hydrocarbon group having a functional group and m is an integer of 2 or more. This process can produce polymers with which functional groups have been introduced into one end or both ends thereof, irrespective of the rate of polymerization or the degree of polymerization of the polymer that forms.

  一种生产具有可被保护的末端官能团的聚合物的工艺，包括用聚合引发剂聚合可自由基聚合的单体，聚合引发剂包括至少一种选自以下通式(1)代表的硫代-S-羧酸和以下通式(2)代表的二硫代羧酸组成的基团(A)，以及至少一种选自以下通式(3)代表的多硫化物、以下通式(4)代表的多硫化物和氧化硫组成的基团(B)： 其中 R¹ 代表烃基，该烃基可能具有包括官能团在内的取代基； 其中 R² 代表可具有包括官能团在内的取代基的烃基； 其中 R³ 和 R⁴ 各自代表一个可具有包括官能团在内的取代基的烃基，且 n 为 2 或 2 以上的整数；以及 R⁵- (S)m- R⁶ (4) 其中，R⁵ 和 R⁶ 分别代表具有官能团的烃基，m 为 2 或 2 以上的整数。无论聚合速度或形成的聚合物的聚合度如何，该工艺都能生产出在一端或两端引入官能团的聚合物。
• COMPOSITION AND METHOD FOR TEMPORARILY FIXING SOLID
  申请人：JSR Corporation

  公开号：EP1522567A1

  公开（公告）日：2005-04-13

  The present invention relates to a method of temporarily and firmly fixing two solids to each other and to a composition used in the method, which is a method of temporarily fixing, comprising temporarily fixing the two solids to each other with a liquid crystal compound or a composition comprising the liquid crystal compound. This method is used for a method of temporarily fixing a pad for chemical mechanical polishing, for example, to polish a wafer for a semiconductor device fixed on a surface of a base plate, when one solid is a pad for chemical mechanical polishing of a wafer for a semiconductor device and the other is a base plate to fix the pad.

  本发明涉及一种将两个固体暂时牢固地相互固定的方法以及用于该方法的组合物，该方法是一种暂时固定的方法，包括用液晶化合物或包含液晶化合物的组合物将两个固体暂时相互固定。该方法用于临时固定化学机械抛光垫的方法，例如，用于抛光固定在底板表面上的半导体器件晶片，其中一个固体是用于半导体器件晶片化学机械抛光的垫，另一个固体是用于固定垫的底板。
• Composition and method for temporarily fixing solid
  申请人：——

  公开号：US20040185187A1

  公开（公告）日：2004-09-23

  The present invention relates to a method of temporarily and firmly fixing two solids to each other and to a composition used in the method, which is a method of temporarily fixing, comprising temporarily fixing the two solids to each other with a liquid crystal compound or a composition comprising the liquid crystal compound. This method is used for a method of temporarily fixing a pad for chemical mechanical polishing, for example, to polish a wafer for a semiconductor device fixed on a surface of a base plate, when one solid is a pad for chemical mechanical polishing of a wafer for a semiconductor device and the other is a base plate to fix the pad.

  本发明涉及一种将两个固体暂时牢固地相互固定的方法以及用于该方法的组合物，该方法是一种暂时固定的方法，包括用液晶化合物或包含液晶化合物的组合物将两个固体暂时相互固定。该方法用于临时固定化学机械抛光垫的方法，例如，用于抛光固定在底板表面上的半导体器件晶片，其中一个固体是用于半导体器件晶片化学机械抛光的垫，另一个固体是用于固定垫的底板。