5,6-Difluoro-5,6-bis(trifluoromethyl)-7-oxabicyclo[2.2.1]hept-2-ene | 116341-94-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧唑烯
• 英文名称: 5,6-Difluoro-5,6-bis(trifluoromethyl)-7-oxabicyclo[2.2.1]hept-2-ene
• CAS: 116341-94-7
• 化学式: C₈H₄F₈O
• 分子量: 268.106
• InChiKey: KGWCPMLZTYVDQI-UHFFFAOYSA-N

物化性质

• 沸点：
  33 °C(Press: 4 Torr)
• 密度：
  1.5853 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  一氧化碳 、 5,6-Difluoro-5,6-bis(trifluoromethyl)-7-oxabicyclo[2.2.1]hept-2-ene 在 acetylacetonatodicarbonylrhodium(l) 、 氢气 、 三苯基膦 作用下， 以 苯 为溶剂， 59.85 ℃ 、2.0 MPa 条件下， 反应 1.0h， 生成 (1S,2S,4R)-5,6-Difluoro-5,6-bis-trifluoromethyl-7-oxa-bicyclo[2.2.1]heptane-2-carbaldehyde
  参考文献：
  名称：

  Kerov; Yashkir; Korneeva, Petroleum Chemistry, 1998, vol. 38, # 3, p. 156 - 163

  摘要：

  DOI：
• 作为产物：
  描述：

  呋喃 、 全氟2-丁烯 以 乙醚 为溶剂， 反应 10.0h， 以49%的产率得到5,6-Difluoro-5,6-bis(trifluoromethyl)-7-oxabicyclo[2.2.1]hept-2-ene
  参考文献：
  名称：

  [2+4]-Cycloaddition of fluoroolefins and fluoroazomethines with furan

  摘要：

  DOI：

  10.1007/bf01455502

文献信息

• Optical film
  申请人：Mitsui Chemicals, Inc.

  公开号：US10035889B2

  公开（公告）日：2018-07-31

  Disclosed is an optical film having low wavelength dispersibility which is obtained by stretching a film formed of a fluorine-containing cyclic olefin polymer including at least one selected from a repeating structural unit represented by the formula described below, wherein a phase difference at a wavelength of 550 nm is greater than or equal to 50 nm, wavelength dispersibility represented by a ratio Re (400 nm)/Re (550 nm) of a phase difference Re (400 nm) at a wavelength of 400 nm to a phase difference Re (550 nm) at a wavelength of 550 nm is 1.00 to 1.05, wavelength dispersibility represented by a ratio Re (400 nm)/Re (800 nm) of a phase difference Re (400 nm) at a wavelength of 400 nm to a phase difference Re (800 nm) at a wavelength of 800 nm is 1.00 to 1.05, and total light transmittance is greater than or equal to 92%.

  本发明公开了一种具有低波长色散性的光学薄膜，该光学薄膜是通过拉伸由含氟环状烯烃聚合物形成的薄膜而获得的，该聚合物包括至少一种选自下式所代表的重复结构单元、其中，波长 550 nm 处的相位差大于或等于 50 nm，波长色散性由波长 400 nm 处的相位差 Re (400 nm)/Re (550 nm)与波长 550 nm 处的相位差 Re (550 nm)之比 Re (400 nm)/Re (550 nm)1.00 至 1.05，波长色散性由波长为 400 纳米时的相位差 Re (400 纳米)与波长为 800 纳米时的相位差 Re (800 纳米)之比 Re (400 纳米)/Re (800 纳米)表示，为 1.00 至 1.05，总透光率大于或等于 92%。
• ALBEKOV, V. A.;BENDA, A. F.;GONTAR, A. F.;SOKOLSKIJ, G. A.;KNUNYANTS, I.L+, IZV. AN CCCP. CEP. XIM.,(1988) N 4, 897-900
  作者：ALBEKOV, V. A.、BENDA, A. F.、GONTAR, A. F.、SOKOLSKIJ, G. A.、KNUNYANTS, I.L+

  DOI：——

  日期：——
• OPTICAL MATERIAL AND MOLDED PRODUCT THEREOF
  申请人：Sunaga Tadahiro

  公开号：US20130030136A1

  公开（公告）日：2013-01-31

  Disclosed is an optical material including a cyclic olefin copolymer containing at least a repeating structural unit [A] represented by the general formula (1) and a repeating structural unit [B] represented by the general formula (2) and having a molar ratio [A]/[B] of from 95/5 to 1/99, wherein the absolute value of the ratio ΔOB/ΔF is from 0.001 to 0.250 in which ΔOB represents the amount of a change in the absolute value of the orientation birefringence calculated from the phase difference (nm) at a wavelength of 633 nm/film thickness (μm) in a stretched film obtained from the optical material, and ΔF represents the amount of a change in the absolute value of the orientation coefficient determined from the dichroic ratio of parallel light intensity I ∥ to perpendicular light intensity I ⊥ , each relative to the orientation direction according to Raman spectroscopy.
• Optical Film
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20160032063A1

  公开（公告）日：2016-02-04

  Disclosed is an optical film having low wavelength dispersibility which is obtained by stretching a film formed of a fluorine-containing cyclic olefin polymer including at least one selected from a repeating structural unit represented by the formula described below, wherein a phase difference at a wavelength of 550 nm is greater than or equal to 50 nm, wavelength dispersibility represented by a ratio Re (400 nm)/Re (550 nm) of a phase difference Re (400 nm) at a wavelength of 400 nm to a phase difference Re (550 nm) at a wavelength of 550 nm is 1.00 to 1.05, wavelength dispersibility represented by a ratio Re (400 nm)/Re (800 nm) of a phase difference Re (400 nm) at a wavelength of 400 nm to a phase difference Re (800 nm) at a wavelength of 800 nm is 1.00 to 1.05, and total light transmittance is greater than or equal to 92%.
• US9128238B2
  申请人：——

  公开号：US9128238B2

  公开（公告）日：2015-09-08