2,3-epoxyperfluoro-3-isopropyl-4-methylpentane | 103697-21-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: 2,3-epoxyperfluoro-3-isopropyl-4-methylpentane
• 英文别名: 2-(1,1,1,2,3,3,3-Heptafluoropropan-2-yl)-2-(pentafluoroethyl)-3,3-bis(trifluoromethyl)oxirane；2-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-2-(1,1,2,2,2-pentafluoroethyl)-3,3-bis(trifluoromethyl)oxirane
• CAS: 103697-21-8
• 化学式: C₉F₁₈O
• 分子量: 466.07
• InChiKey: OZQNQQRUDNMYNL-UHFFFAOYSA-N

物化性质

• 沸点：
  120-122 °C
• 密度：
  1.822±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  19

反应信息

• 作为反应物：
  描述：

  2,3-epoxyperfluoro-3-isopropyl-4-methylpentane 、 氟化铯 生成 全氟(2-甲基-2-戊烯)
  参考文献：
  名称：

  ZAPEVALOV, A. YA.;FILYAKOVA, T. I.;PESCHANSKIJ, N. V.;KODESS, M. I.;KOLEN+, ZH. ORGAN. XIMII, 1985, 21, N 10, 2113-2119

  摘要：

  DOI：
• 作为产物：
  描述：

  1,1,1,4,5,5,5-七氟-3-(五氟乙基)-2,4-二(三氟甲基)戊-2-烯 在 sodium hypochlorite 作用下， 以 乙腈 为溶剂， 以91%的产率得到2,3-epoxyperfluoro-3-isopropyl-4-methylpentane
  参考文献：
  名称：

  Zapevalov, A. Ya.; Filyakova, T. I.; Peschanskii, N. V., Journal of Organic Chemistry USSR (English Translation), 1985, vol. 21, p. 1933 - 1938

  摘要：

  DOI：

文献信息

• FLUORINATED OXIRANES AS ORGANIC RANKINE CYCLE WORKING FLUIDS AND METHODS OF USING SAME
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20140311146A1

  公开（公告）日：2014-10-23

  A process and an apparatus for converting thermal energy into mechanical energy in a Rankine cycle is provided. The process and apparatus include a working fluid that comprises a fluorinated oxirane. The fluorinated oxirane can contain substantially no hydrogen atoms bonded to carbon atoms and can have from about 4 to about 9 carbon atoms. The process can drive a turbine and, in some embodiments, generate electricity.

  提供了一种在兰金循环中将热能转化为机械能的过程和装置。该过程和装置包括一种工作流体，其中包括一种含有氟的环氧乙烷。该含氟环氧乙烷可以几乎不包含与碳原子键合的氢原子，并且碳原子数量在约4到约9之间。该过程可以驱动涡轮，并在一些实施例中产生电力。
• Cai, Xingwei; Sha, Min; Pan, Ren Ming, Asian Journal of Chemistry, 2012, vol. 24, # 5, p. 2357 - 2358
  作者：Cai, Xingwei、Sha, Min、Pan, Ren Ming

  DOI：——

  日期：——
• Synthesis and reactions of perfluoro-α-oxides derived from trimers of hexafluoropropene
  作者：A.Ya. Zapevalov、T.I. Filyakova、N.V. Peschansky、M.I. Kodess、I.P. Kolenl

  DOI：10.1016/s0022-1139(00)83420-x

  日期：1985.8
• Novel epoxidation reaction of perfluoroalkenes with trimethylamine N-oxide and iodosylbenzene
  作者：Taizo Ono、Philip Henderson

  DOI：10.1016/s0040-4039(02)01863-4

  日期：2002.10

  Trimethylamine N-oxide and iodosylbenzene were found to be useful reagents for the epoxidation of tri- and tetra-substituted perfluoroalkenes in good to excellent yields. A catalytic epoxidation method was also developed by coupling this reaction with the N-oxidation of trimethylamine by hydrogen peroxide or perbenzoic acid. (C) 2002 Elsevier Science Ltd. All rights reserved.
• Epoxidation reaction of perfluoroalkenes with tert-amine N-oxide
  作者：Xing Wei Cai、Min Sha、Biao Jiang、Ren Ming Pan

  DOI：10.1016/j.cclet.2012.10.005

  日期：2012.11

  Straight-chain aliphatic tert-amine N-oxides were found to be useful oxidizing agent for epoxidation of tri- and tetra-substituted perfluoroalkenes under mild conditions in high yields. The process for epoxidation by employing tri-n-butylamine N-oxide gave the best result in the reagent survey. (C) 2012 Ren Ming Pan. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.