hydroxy-n-propyl methacrylate | 93751-47-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: hydroxy-n-propyl methacrylate
• 英文别名: 1-hydroxypropyl methacrylate；1HPMA；hydroxypropyl methacrylate；1-Hydroxypropyl 2-methylprop-2-enoate
• CAS: 93751-47-4
• 化学式: C₇H₁₂O₃
• 分子量: 144.17
• InChiKey: NUIPOEWADWHGSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  甲基丙烯酸 、 methyloxirane 在 阻聚剂701 、 iron(III) methacrylate 作用下， 反应 3.5h， 以67%的产率得到2-羟丙基异丁烯酸酯
  参考文献：
  名称：

  METHOD FOR PRODUCING IRON CARBONATE

  摘要：

  公开号：

  EP2889284B1

文献信息

• [EN] HALOGENATED HETEROALKENYL- AND HETEROALKYL-FUNCTIONALIZED ORGANIC COMPOUNDS AND METHODS FOR PREPARING SUCH COMPOUNDS<br/>[FR] COMPOSÉS ORGANIQUES HALOGÉNÉS À FONCTION HÉTÉROALCÉNYLE ET HÉTÉROALKYLE ET LEURS PROCÉDÉS DE PRÉPARATION
  申请人：ARKEMA INC

  公开号：WO2019067394A1

  公开（公告）日：2019-04-04

  A method for synthesizing halogenated organic compounds, such as halogenated alkenyl group-containing and halogenated alkyl group-containing compounds having a heteroatom (e.g., O,N.S) coupled to a carbon atom of a halogenated alkenyl or halogenated alkyl group, involves reacting a halogenated olefin such as a chloro-substituted trifluoropropenyl compound with an active hydrogen-containing organic compound such as an alcohol (e.g., an aliphatic monoalcohol, aliphatic polyalcohol, or a phenolic compound), a primary amine, a secondary amine or a thiol.

  合成卤代有机化合物的方法，例如含卤代烯基基团和含卤代烷基基团的化合物，其中含有一个杂原子（例如，O，N，S）与卤代烯基或卤代烷基基团的碳原子偶联，涉及将卤代烯烃（例如氯代三氟丙烯基化合物）与含有活性氢的有机化合物（例如醇（例如脂肪族单醇，脂肪族多醇或酚类化合物），一级胺，二级胺或硫醇）反应。
• METHODS FOR PRODUCING BIOCOMPATIBLE MATERIALS
  申请人：Driver Michael

  公开号：US20130059926A1

  公开（公告）日：2013-03-07

  A method for producing polymerisable solution which comprises dissolving an ethylenically unsaturated zwitterionic monomer in a co-monomer system comprising a functionalised ethylenically unsaturated monomer in which the zwitterionic monomer is soluble, a siloxane group-containing monomer or macromer, and a crosslinking agent is disclosed. The polymerisable solution is biocompatible and can be used to produce polymers and articles such as contact lenses.

  一种生产可聚合溶液的方法，该方法包括将一种乙烯基不饱和的两性离子单体溶解在共单体系统中，该共单体系统包括一种功能性乙烯基不饱和单体，在该单体中两性离子单体是可溶的，一种含有硅氧烷基团的单体或大单体，以及一种交联剂。所述的可聚合溶液具有生物相容性，可用于生产聚合物和制品，如隐形眼镜。
• COMPOSITIONS AND METHODS FOR FORMING ARTICLES HAVING SILVER METAL
  申请人：Eastman Kodak Company

  公开号：US20180362547A1

  公开（公告）日：2018-12-20

  Electrically-conductive silver metal can be provided in a thin film or pattern on a substrate from a silver complex having reducing silver ions and represented by: (Ag + ) a (L) b (P) c (I) wherein L represents an α-oxy carboxylate; P represents a 5- or 6-membered N-heteroaromatic compound; a is 1 or 2; b is 1 or 2; and c is 1, 2, 3, or 4, provided that when a is 1, b is 1, and when a is 2, b is 2. The silver complex is mixed in a hydroxy-free, nitrile-containing aprotic solvent with a polymer that is either (i) a hydroxy-containing cellulosic polymer or (ii) a non-cellulosic acrylic polymer having a halo- or hydroxy-containing side chain. The reducible silver ions in the a thermally sensitive thin film or pattern can be thermally converted to electrically-conductive metallic silver under suitable heating conditions to provide a product article that can be used in various devices.

  电导银金属可由含还原银离子的银配合物以薄膜或图案的形式提供在基底上，其由下式表示： (Ag + ) a (L) b (P) c (I) 其中L代表α-氧基羧酸盐；P代表5或6成员的N-杂环化合物；a为1或2；b为1或2；c为1、2、3或4，条件是当a为1时，b为1，当a为2时，b为2。将银配合物与不含羟基、含腈的无质子溶剂中的聚合物混合，该聚合物为(i)含羟基的纤维素聚合物或(ii)具有卤素或含羟基侧链的非纤维素丙烯酸聚合物。在热敏感薄膜或图案中的可还原银离子可以在适当的加热条件下热转换为电导银金属，以提供可用作各种设备的产品物品。
• PREPARATION OF FUNCTIONALIZED ALKOXYAMINE INITIATOR AND ITS USE
  申请人：——

  公开号：US20030236368A1

  公开（公告）日：2003-12-25

  A one-pot process for the preparation of functional alkoxyamines of the general formula (I), 1 is disclosed. The process entails (1) reacting an oxidizing agent with a sterically hindered secondary amine to produce an aqueous phase and a nitroxyl radical (2) removing the aqueous phase and adding to the nitroxyl radical one or more vinyl monomer(s) conforming to a formula and a system which produces free radicals. Also disclosed is a process of polymerizing monomers using the functional alkoxyamine.

  披露了一种用于制备具有一般公式（I）的功能性烷氧基胺的一锅法工艺。该工艺包括：（1）使用氧化剂与空间位阻较大的二级胺反应，产生水相和硝基氧自由基；（2）移除水相，并向硝基氧自由基中加入一种或多种符合公式的乙烯基单体以及能够产生自由基的体系。还披露了一种使用功能性烷氧基胺聚合单体的工艺。
• Copolymers Based on N-Vinylpyrrolidone and Branched Aliphatic Carbonxylic Acids, and Their Use as Solubilizers
  申请人：Angel Maximilian

  公开号：US20080200564A1

  公开（公告）日：2008-08-21

  Copolymers comprising: (a) 60 to 99% by weight of at least one monomer selected from the group consisting of N-vinyllactams, N-vinylamides, and mixtures thereof; (1) 1 to 40% by weight of at least one monomer selected from the group consisting of vinyl esters of aliphatic branched C 8 -C 30 -carboxylic acids; (c) 0 to 30% by weight of vinyl acetate; and (d) 0 to 39% by weight of at least one additional free-radically copolymnerizable monomer; wherein the % by weight content of components (a), (b), (c) and (d) totals 100%, and with the proviso that the total amount of component (b) and component (c) combined is 1 to 40% by weight based on the copolymer, are described along with methods of using such copolymers to solubilize substances which are insoluble in water, substances which are only sparingly soluble in water, and combinations thereof.

  共聚物包含：（a）60至99重量百分比的至少一种单体，选自N-乙烯基内酰胺、N-乙烯酰胺和它们的混合物；（b）1至40重量百分比的至少一种单体，选自支链的C8-C30脂肪族羧酸的乙烯酯；（c）0至30重量百分比的乙酸乙烯酯；和（d）0至39重量百分比的至少一种额外的自由基共聚单体；其中，组分（a）、（b）、（c）和（d）的重量百分比总和为100%，并且有条件规定组分（b）和组分（c）的总和基于共聚物为1至40重量百分比。还描述了使用这样的共聚物来增溶水不溶性物质、水微溶性物质以及它们的组合的方法。