10-(p-formylphenyloxy)decyltrimethylammonium bromide | 73000-51-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 10-(p-formylphenyloxy)decyltrimethylammonium bromide
• 英文别名: 10-(p-Formylphenoxy)-decyltrimethylammonium；1-Decanaminium, 10-(4-formylphenoxy)-N,N,N-trimethyl-, bromide；10-(4-formylphenoxy)decyl-trimethylazanium;bromide
• CAS: 73000-51-8
• 化学式: Br*C₂₀H₃₄NO₂
• 分子量: 400.399
• InChiKey: LZULCLDFEHHQGE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.71
• 重原子数：
  24
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  10-(p-formylphenyloxy)decyltrimethylammonium bromide 、 联苯胺 在 溶剂黄146 作用下， 生成
  参考文献：
  名称：

  Formation of stable monolayer membranes and related structures in dilute aqueous solution from two-headed ammonium amphiphiles

  摘要：

  DOI：

  10.1021/ja00512a020
• 作为产物：
  描述：

  1,10-二溴癸烷 在 sodium ethanolate 作用下， 以 乙醇 、 水 为溶剂， 反应 42.0h， 生成 10-(p-formylphenyloxy)decyltrimethylammonium bromide
  参考文献：
  名称：

  Formation of the stable bilayer assemblies in dilute aqueous solution from ammonium amphiphiles with the diphenylazomethine segment

  摘要：

  DOI：

  10.1021/ja00522a019

文献信息

• Reaction of the Azomethine Moiety Buried in Bilayer Membranes
  作者：Yoshio Okahata、Reiko Ando、Toyoki Kunitake

  DOI：10.1246/bcsj.56.802

  日期：1983.3

  water and amines of the azomethine moiety that is part of single-chain ammonium amphiphiles was examined. These amphiphiles form stable bilayer aggregates when they have the alkyl tail of C7 or C12. The reaction with water of the bilayer-forming amphiphiles ceases at the hydration stage and are 10–2000 times slower than those of the amphiphiles which do not form bilayers and undergo hydrolytic cleavage

  检查了作为单链铵两亲物的一部分的偶氮甲碱部分与水和胺的反应。当这些两亲物具有 C7 或 C12 的烷基尾时，它们会形成稳定的双层聚集体。形成双层的两亲物与水的反应在水合阶段停止，比不形成双层并进行水解裂解的两亲物慢 10-2000 倍。双层中偶氮甲碱部分的反应性随着与膜表面距离的增加而降低。双层形成两亲物的阿伦尼乌斯图显示在对应于相应双层相变 (Tc) 的温度下的不连续性。表观活化能在低于 Tc 的温度下大于在高于 Tc 的温度下。这表明在流体双层中促进了水渗透。与胺的反应受它们在双层基质中的溶解度的影响，当偶氮...
• Formation of stable bilayer assemblies in water from single-chain amphiphiles. Relationship between the amphiphile structure and the aggregate morphology
  作者：Toyoki Kunitake、Yoshio Okahata、Masatsugu Shimomura、Shoichiro Yasunami、Kunihide Takarabe

  DOI：10.1021/ja00408a021

  日期：1981.9
• A Novel System of Self-Reproducing Giant Vesicles
  作者：Katsuto Takakura、Taro Toyota、Tadashi Sugawara

  DOI：10.1021/ja029379a

  日期：2003.7.1

  Novel self-reproducing giant vesicles, consisting of a vesicular amphiphile with an imine group in its hydrophobic chain, were constructed. This vesicular amphiphile, the product of a dehydrocondensation reaction between amphiphilic aldehyde and a lipophilic aniline derivative, could be prepared within the giant vesicles. When a protected form of the aldehyde precursor was added to a suspension of giant vesicles containing the lipophilic aniline precursor and a catalyst, dehydrocondensation between the two precursors took place inside the vesicles and produced the same amphiphile as the one which constitutes the original vesicle. The newly formed amphiphiles self-assembled in the inner water pool to form small vesicles, which were eventually extruded through the outer layer of the original vesicle to the bulk water. Accordingly, this kinetic system can be designated as a self-reproducing system of giant vesicles.
• Formation of the stable bilayer assemblies in dilute aqueous solution from ammonium amphiphiles with the diphenylazomethine segment
  作者：Toyoki Kunitake、Yoshio Okahata

  DOI：10.1021/ja00522a019

  日期：1980.1
• Formation of stable monolayer membranes and related structures in dilute aqueous solution from two-headed ammonium amphiphiles
  作者：Yoshio Okahata、Toyoki Kunitake

  DOI：10.1021/ja00512a020

  日期：1979.8