hexakis(pyrenyloxy)cyclotriphosphazene | 1560916-54-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: hexakis(pyrenyloxy)cyclotriphosphazene
• 英文别名: 2,2,4,4,6,6-Hexa(pyren-1-yloxy)-1,3,5-triaza-2lambda5,4lambda5,6lambda5-triphosphacyclohexa-1,3,5-triene；2,2,4,4,6,6-hexa(pyren-1-yloxy)-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-triene
• CAS: 1560916-54-2
• 化学式: C₉₆H₅₄N₃O₆P₃
• 分子量: 1438.42
• InChiKey: FBXQTQWBGYSLRS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  30.4
• 重原子数：
  108
• 可旋转键数：
  12
• 环数：
  25.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  92.5
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  六氯环三磷腈 、 1-羟基芘 在 caesium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以83%的产率得到hexakis(pyrenyloxy)cyclotriphosphazene
  参考文献：
  名称：

  Intramolecular excimer formation in hexakis(pyrenyloxy)cyclotriphosphazene: photophysical properties, crystal structure, and theoretical investigation

  摘要：

  通过N3P3Cl6和2-羟基芘的反应合成了一个六(吡利酸酯)环三磷氮化物，并研究了其激基发射。

  DOI：

  10.1039/c3dt52957f

文献信息

• Fluorescence properties of fluorenylidene bridged cyclotriphosphazenes bearing aryloxy groups
  作者：Gönül Yenilmez Çiftçi、Elif Şenkuytu、Elif Saadet İncir、Mahmut Durmuş、Fatma Yuksel

  DOI：10.1016/j.poly.2015.10.047

  日期：2015.12

  The synthesis and characterization of the first series of aryloxy full-substituted fluorenylidene open chain and bridged cyclotriphosphazene derivatives (13-18) are reported in this study. The synthetic route utilized includes the reaction of penta-substituted cyclotriphosphazenes (5, 7, 9) with 4,4'-(9-fluorenylidene)diphenol (FDP) (11) and 4,4'-(9-fluorenylidene)dianiline (FDA) (12) to give bridged compounds (13, 15-17) and open chain compounds (14 and 18). The structural investigations of the compounds were verified by elemental analyses, mass spectrometry, UV-Vis, FT-IR, H-1 and P-31 NMR techniques, and X-ray crystallography (for 13 and 18). The fluorescence behavior of the studied cyclotriphosphazene derivatives were also examined in THF solution. Compound 16 showed a high emission among the studied compounds to investigate its metal sensing properties. This compound showed high selectivity for copper (Cu2+) and iron (Fe2+/Fe3+) ions in solution. (C) 2015 Elsevier Ltd. All rights reserved.
• Intramolecular excimer formation in hexakis(pyrenyloxy)cyclotriphosphazene: photophysical properties, crystal structure, and theoretical investigation
  作者：Serkan Yeşilot、Bünyemin Çoşut、Hüsnüye Ardıç Alidağı、Ferda Hacıvelioğlu、Gül Altınbaş Özpınar、Adem Kılıç

  DOI：10.1039/c3dt52957f

  日期：——

  A hexakis(pyrenyloxy)cyclotriphosphazene was synthesized by the reaction of N₃P₃Cl₆ with 2-hydroxypyrene, and its excimer emission has been investigated.

  通过N3P3Cl6和2-羟基芘的反应合成了一个六(吡利酸酯)环三磷氮化物，并研究了其激基发射。