cis-{PtCl2(C2H4)(PPh3)} | 38095-87-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-{PtCl2(C2H4)(PPh3)}
• 英文别名: cis-[PtCl2(ethylene)(PPh3)]；cis-PtCl2(PPh3)(ethylene)；dichloroplatinum;ethene;triphenylphosphane
• CAS: 38095-87-3
• 化学式: C₂₀H₁₉Cl₂PPt
• 分子量: 556.331
• InChiKey: CCMORLBEAFQDMY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.62
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  cis-{PtCl2(C2H4)(PPh3)} 在 NEt₃ 作用下， 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Sarhan, Jamil K. K.; Green, Michael; Al-Najjar, Ibrahim M., Journal of the Chemical Society, Dalton Transactions, 1984, p. 771 - 778

  摘要：

  DOI：
• 作为产物：
  描述：

  乙烯 、 三苯基膦 、 platinum(II) chloride 以 N,N-二甲基甲酰胺 为溶剂， 以95%的产率得到cis-{PtCl2(C2H4)(PPh3)}
  参考文献：
  名称：

  Amine Attack on Coordinated Alkenes:  An Interconversion from Anti-Markovnikoff to Markovnikoff Products

  摘要：

  A sequence of alkene complexes of platinum, PtCl2(PPh3)(alkene) (alkene = ethylene, propene, 1-butene, cis-2-butene, 1-hexene, 1-octene, and 1-decene), has been prepared. These complexes are characterized by NMR spectroscopy, including assignment of each proton, and X-ray crystal structures of the 1-propene and 1-hexene complexes. Each complex was reacted with diethylamine. For the 1-hexene, 1-octene, and 1-decene complexes, the amine displaces the alkene. For the smaller alkenes, the diethylamine nucleophilically attacks the coordinated alkene. For propene and 1-butene, the low-temperature addition leads to the anti-Markovnikoff nucleophilic attack, which slowly converts at room temperature to the Markovnikoff product. The transformation from anti-Markovnikoff to Markovnikoff addition occurs without diethylamine dissociation.

  DOI：

  10.1021/ja0469939

文献信息

• Addition reactions on co-ordinated olefinic ligands. Part 8. Platinum(II) complexes of 1,1 -dimethylallene and their reaction with amines. Molecular structure of the zwitterionic derivative dichloro-[1-(NN-diethylammoniomethyl)-2-methylprop-1-enyl](triphenylphosphine) platinum(II)
  作者：Augusto De Renzi、Benedetto Di Blasio、Achille Panunzi、Carlo Pedone、Aldo Vitagliano

  DOI：10.1039/dt9780001392

  日期：——

  Some new platinum(II) complexes of 1,1-dimethylallene (dma) of general formula cis-[PtCl2(dma)L](L = PPh3, AsPh3, H2NC6H4Me-p, or SMe2O) have been prepared. They react with aliphatic and aromatic amines to give zwitterionic alkenyl derivatives of the type cis-[PtCl2(Me2CCCH2NR1R2R3) L], which on treatment with hydrogen chloride afford the ammonium salts [NR1R2R3(CH2CHCMe2)]Cl. The structure of the

  通式为顺式-[PtCl 2（dma）L]（L = PPh 3，AsPh 3，H 2 NC 6 H 4 Me- p或SMe的1,1-二甲基丙二烯（dma）的一些新的铂（II）配合物2 O）已经准备好了。它们与脂肪族和芳香族胺反应，得到顺式-[PtCl 2（Me 2 C CCH 2 NR 1 R 2 R 3）L]型两性离子烯基衍生物，将其在用氯化氢处理后得到铵盐[NR 1 R2 R 3（CH 2 CHCMe 2）] Cl。在标题配合物的情况下，已经通过X射线衍射分析证实了烯基配合物的结构。晶体是三斜晶，空间群P，在尺寸为a = 11.130（3）， b = 18.887（5）， c = 14.370（5）Å，α= 108.8（3），β= 90.1的晶胞中Z = 4（2）， γ＝ 95.1（2）°。该结构已通过Patterson和Fourier方法求解，并通过块对角最小二乘法改进为R对于3,630个观察到的反射=
• Synthesis, structures, stabilities, and reactions of cationic olefin complexes of palladium(II) containing the .eta.5-cyclopentadienyl ligand
  作者：Hideo Kurosawa、Tetsuro Majima、Naonori Asada

  DOI：10.1021/ja00543a016

  日期：1980.11
• Stoichiometric model reactions in olefin hydroformylation by platinum-tin systems
  作者：Montserrat Gomez、Guillermo Muller、Daniel Sainz、Joaquim Sales、Xavier Solans

  DOI：10.1021/om00058a019

  日期：1991.12

  The three independent steps involved in the hydroformylation process, insertion of the olefin, insertion of carbon monoxide, and hydrogenolysis, have been investigated with use of platinum-tin catalysts and 1-pentene as olefin at low pressure and temperature in CH2Cl2. In the temperature range 198-308 K, the three reactions can be studied consecutively. All the intermediates observed were prepared and characterized separately. The complex trans-[PtH(SnCl3)(PPh3)2] was used as the initial compound for this sequence. The hydrido complex crystallized in the monoclinic space group C2/c, with a = 31.345 (5) angstrom, b = 12.716 (3) angstrom, c = 18.135 (3) angstrom, beta = 96.5 (2)-degrees, Z = 8, and R (R(w)) = 0.056 (0.060) for 3235 independent reflections having I > 2.56-sigma(I). The large Pt-Sn bond (2.601 (1) angstrom) distance correlates satisfactorily with the low 1J(Pt-Sn) value. The Pt-Sn bond is necessary for the insertion of 1-pentene in the hydrido-platinum complex and for the hydrogenolysis of the acyl compounds under these mild conditions. The insertion of 1-pentene was observed at 198 K, giving the cis-alkyl complex; CO insertion took place after isomerization to the trans-alkyl complex. The instability of Pt-Sn and Pt-C bonds in the trans-acyl complex favors easy decarbonylation or loss of SnCl2, so any other platinum complex without tin accepts SnCl2 from the acyl complex. The hydrogenolysis of trans-[Pt(SnCl3)(COC5H11)(PPh3)2] under 1.5 bar of H2-CO (1:1) did not yield n-hexanal quantitatively; only 12% of n-hexanal was formed. Thus, decarbonylation was the main process observed. From the reactions studied, it is possible to propose the following order of Pt-Sn bond stability: trans-[Pt(SnCl3)(COC5H11)(PPh3)2] < [Pt(SnCl3)(C5H11)(PPh3)2] < trans-[PtH-(SnCl3)(PPh3)2] < [PtH(SnCl3)(CO)(PPh3)2] < [Pt(mu-Cl)(SnCl3)(PPh3)]2 < [PtCl(SnCl3)(PPh3)]- < [PtCl2(SnCl3)2]2-. The insertion reactions studied with cis-[PtCl2(olefin)(PR3)] as an olefin carrier and the hydrido-platinum complexes trans-[PtHCl(PPh3)2], trans-[PtH(SnCl3)(PPh3)2], and [PtH(SnCl3)-(CO)(PPh3)2] as hydrogen carriers exclude the participation of intermolecular steps by reaction of two different platinum complexes under the experimental conditions described.
• Formation of an azaplatinacyclobutane compound from a tertiary amine by elimination of an alkene
  作者：Ibrahim M. Al-Najjar

  DOI：10.1016/s0020-1693(00)82507-4

  日期：1984.3
• Neighboring group effects on the stability of azaplatinacyclobutane rings in (2-aminoethyl)platinum(II) compounds
  作者：Michael Green、Jamil K. K. Sarhan、Ibrahim M. Al-Najjar

  DOI：10.1021/om00082a002

  日期：1984.4