N,N,N',N'-tetra(allyl)ethanediamide | 39097-82-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N,N,N',N'-tetra(allyl)ethanediamide
• 英文别名: N,N,N',N'-tetrakis(prop-2-enyl)oxamide
• CAS: 39097-82-0
• 化学式: C₁₄H₂₀N₂O₂
• 分子量: 248.325
• InChiKey: XAIPBGHZHKLNRK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N,N',N'-tetra(allyl)ethanediamide 在 bis[1,1-di(trifluoromethyl)ethoxy][(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate 作用下， 反应 3.0h， 以39%的产率得到1,2-di(2H-pyrrol-1-(5H)-yl)ethane-1,2-dione
  参考文献：
  名称：

  Room temperature ionic liquids: new solvents for Schrock's catalyst and removal using polydimethylsiloxane membranes

  摘要：

  一种室温离子液体被用作与Schrock催化剂进行的交换反应的溶剂，并报告了一种新方法，以利用聚二甲基硅氧烷拇指进行小分子和离子液体之间的分离。

  DOI：

  10.1039/b618341g
• 作为产物：
  描述：

  草酸氯化物 、 二烯丙基胺 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 N,N,N',N'-tetra(allyl)ethanediamide
  参考文献：
  名称：

  Photosensitive resin composition and uses thereof

  摘要：

  该发明涉及一种具有高显影性、良好硬度和良好溅射抗性的感光树脂组合物。该发明还提供了一种制造彩色滤光片、彩色滤光片和液晶显示装置的方法。该感光树脂组合物包括碱溶性树脂（A）、含有乙烯基不饱和基团的化合物（B）、光引发剂（C）、有机溶剂（D）、颜料（E）和化合物（F）。

  公开号：

  US09568763B2

文献信息

• High activity ruthenium or osmium metal carbene complexes for olefin metathesis reactions and synthesis thereof
  申请人：CALIFORNIA INSTITUTE OF TECHNOLOGY

  公开号：EP1251135A3

  公开（公告）日：2004-01-02

  A method of preparing a catalyst of the formula comprising:reacting a compound of the formula (XX1MLnL1m)p with a phosphorane of the formula wherein:M is Os or Ru;R and R1 are either the same or different and are(a) hydrogen,(b) a group selected from C2-C20 alkenyl, C2-C20 alkynyl, C1-C20 alkyl, aryl, C1-C20 carboxylate, C2-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl, or C1-C20 alkylsulfinyl, or(c) one of the groups listed in (b) substituted with C1-C5 alkyl, halogen, C1-C5 alkoxy, unsubstituted phenyl, halogen substituted phenyl, C1-C5 alkyl substituted phenyl, or C1-C5 alkoxy substituted phenyl;R4, R5, and R6 are either the same or different and are each unsubstituted or substituted hydrocarbon wherein the hydrocarbon is selected from the group consisting of aryl, C1-C6 alkyl, C1-C6 alkoxy, and phenoxy and the hydrocarbon substitution is selected from the group consisting of halogen, C1-C3 alkyl, C1-C3 alkoxy, unsubstituted phenyl, halogen substituted phenyl, C1-C5 alkyl substituted phenyl, and C1-C5 alkoxy substituted phenyl;X and X1 are either the same or different and are any anionic ligand;L is any neutral electron donor;L1 is a trialkylphosphine ligand where at least one of the alkyl groups is a secondary alkyl or a cycloalkyl;n and m are independently 0-4, provided n+m=2, 3 or 4; andp is an integer equal to or greater than 1.

  制备配方催化剂的方法包括：将具有以下配方的化合物（XX1MLnL1m）与具有以下配方的磷烷反应：其中：M为Os或Ru；R和R1要么相同要么不同，且为(a) 氢，(b) 从C2-C20烯烃、C2-C20炔烃、C1-C20烷基、芳基、C1-C20羧酸酯、C2-C20烷氧基、C2-C20烯氧基、C2-C20炔氧基、芳氧基、C2-C20烷氧羰基、C1-C20烷硫基、C1-C20烷基磺酰基或C1-C20烷基亚磺酰基中选择的基团，或(c) 在(b)中列出的基团之一，其被C1-C5烷基、卤素、C1-C5烷氧基、未取代的苯基、卤素取代的苯基、C1-C5烷基取代的苯基或C1-C5烷氧基取代的苯基所取代；R4、R5和R6要么相同要么不同，且每个都是未取代或取代的碳氢化合物，其中碳氢化合物选自芳基、C1-C6烷基、C1-C6烷氧基和苯氧基组成的群，碳氢化合物取代选自卤素、C1-C3烷基、C1-C3烷氧基、未取代的苯基、卤素取代的苯基、C1-C5烷基取代的苯基和C1-C5烷氧基取代的苯基；X和X1要么相同要么不同，且为任何阴离子配体；L为任何中性电子给体；L1为三烷基膦配体，其中至少一个烷基是次烷基或环烷基；n和m独立地为0-4，条件是n+m=2、3或4；p为大于或等于1的整数。
• METHODS OF TREATING TEXTILE FIBRES
  申请人：Allen Warrick James David

  公开号：US20140315022A1

  公开（公告）日：2014-10-23

  According to the invention there is provided a method of treating textile fibres including the steps of: providing a polymeric precursor which includes a group of sub-formula (I) where R 2 and R 3 are independently selected from (CR 7 R 8 ) n , or a group CR 9 R 10 , CR 7 R 8 CR 9 R 10 or CR 9 R 10 CR 7 R 8 where n is 0, 1 or 2, R 7 and R 8 are independently selected from hydrogen, halo or hydrocarbyl, and either one of R 9 or R 10 is hydrogen and the other is an electron withdrawing group, or R 9 and R 10 together form an electron withdrawing group, and R 4 and R 5 are independently selected from CH or CR 11 where R 11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X 1 is a group CX 2 X 3 where the dotted line bond to which it is attached is absent and a group CX 2 where the dotted line bond to which it is attached is present, Y 1 is a group CY 2 Y 3 where the dotted line bond to which it is attached is absent and a group CY 2 where the dotted line bond to which it is attached is present, and X 2 , X 3 , Y 2 and Y 3 are independently selected from hydrogen, fluorine or other substituents, R 1 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or —R 3 -R 5 ≡Y 1 , and R 13 is C(O) or S(0) 2 ; coating the textile fibres with the polymeric precursor; and polymerising the polymeric precursor so as to produce a polymeric coating on the textile fibres.

  根据本发明，提供了一种处理纺织纤维的方法，包括以下步骤：提供一种聚合物前体，其中包括一个亚式(I)的基团，其中R2和R3独立地选择自(CR7R8)n，或者选择自CR9R10、CR7R8CR9R10或CR9R10CR7R8的基团，其中n为0、1或2，R7和R8独立地选择自氢、卤素或烃基，而R9和R10中的任意一个是氢，另一个是电子提取基团，或者R9和R10一起形成电子提取基团，而R4和R5独立地选择自CH或CR11，其中R11是电子提取基团，点线表示键的存在或不存在，X1是一个CX2X3基团，其中它附着的点线键不存在，以及一个CX2基团，其中它附着的点线键存在，Y1是一个CY2Y3基团，其中它附着的点线键不存在，以及一个CY2基团，其中它附着的点线键存在，而X2、X3、Y2和Y3独立地选择自氢、氟或其他取代基，R1选择自氢、卤素、硝基、烃基、可选地带有功能基团或者-R3-R5≡Y1，而R13是C(O)或S(0)2；用聚合物前体涂覆纺织纤维；并聚合聚合物前体，使其在纺织纤维上形成聚合物涂层。
• METHODS OF COATING A LOW SURFACE ENERGY SUBSTRATE
  申请人：Allen Warrick James David

  公开号：US20140370279A1

  公开（公告）日：2014-12-18

  According to the invention there is provided a method of coating a low surface energy substrate including the steps of: a) providing a polymeric precursor which includes a group of sub-formula (I) where R 1 is i) CR a , where R a is hydrogen or alkyl, ii) a group S(0) p R 13 , or SiR 14 where R 13 and R 14 are independently selected from hydrogen or hydrocarbyl, p is 0, 1 or 2 and q is 1 or 2, iii) C(0)N, S(0) 2 N, C(0)ON, CH 2 ON, or CH═CHR C N where R c is an electron withdrawing group, or iv) OC(0)CH, C(0)OCH or S(0)2CH; in which R 12 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or formula (II) R 2 and R 3 are independently selected from (CR 7 R 8 )n, or a group CR 9 R 10 , CR 7 R 8 CR 9 R 10 or CR 9 R 10 CR 7 R 8 where n is 0, 1 or 2, R 7 and R 8 are independently selected from hydrogen or alkyl, and either one of R 9 or R 10 is hydrogen and the other is an electron withdrawing group, or R 9 and R 10 together form an electron withdrawing group; R 4 and R 5 are independently selected from CH or CR 11 where CR 11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X 1 is a group CX 2 X 3 where the dotted line bond to which it is attached is absent and a group CX 2 where the dotted line to which it is attached is present, Y 1 is a group CY 2 Y 3 where the dotted line to which it is attached is absent and a group CY 2 where the dotted line to which it is attached is present, and X 2, X 3 , Y 2 and Y 3 are independently selected from hydrogen, fluorine or other substituents; and b) either (i) coating the low surface energy substrate with the polymeric precursor and polymerising the polymeric precursor to form a polymeric coating, or (ii) polymerising the polymeric precursor and contacting the polymerised polymeric precursor with a low surface energy substrate to form a polymeric coating on the low surface energy substrate.

  根据本发明提供了一种涂覆低表面能基材料的方法，包括以下步骤：a）提供一个聚合物前体，其中包括一个亚公式（I）的基团，其中R1是i）CRa，其中Ra是氢或烷基，ii）一个S（0）pR13基团，或SiR14，其中R13和R14独立选择自氢或烃基，p为0、1或2，q为1或2，iii）C（0）N，S（0）2N，C（0）ON，CH2ON或CH═CHRCN，其中Rc是一个电子提取基团，或iv）OC（0）CH，C（0）OCH或S（0）2CH；其中R12选择自氢、卤素、硝基、烃基（可选择性地取代或插入功能基团）或公式（II）R2和R3独立选择自（CR7R8）n，或一个CR9R10基团，CR7R8CR9R10或CR9R10CR7R8基团，其中n为0、1或2，R7和R8独立选择自氢或烷基，R9或R10之一为氢，另一个为电子提取基团，或R9和R10一起形成电子提取基团；R4和R5独立选择自CH或CR11，其中CR11是电子提取基团，虚线表示有或无化学键，X1是一个CX2X3基团，其中它所附着的虚线键不存在，以及一个CX2基团，其中它所附着的虚线存在，Y1是一个CY2Y3基团，其中它所附着的虚线键不存在，以及一个CY2基团，其中它所附着的虚线存在，X2、X3、Y2和Y3独立选择自氢、氟或其他取代基团；和b）或者（i）用聚合物前体涂覆低表面能基材料并聚合聚合物前体形成聚合物涂层，或者（ii）聚合聚合物前体并将聚合后的聚合物前体与低表面能基材料接触以形成低表面能基材料上的聚合物涂层。
• COMPOSITE ARTICLES AND METHODS OF PRODUCING SAME
  申请人：Allen Warrick James David

  公开号：US20150283784A1

  公开（公告）日：2015-10-08

  According to the invention there is provided a composite article including: a textile layer having a first and a second face, each of the first and second faces having a polymeric coating thereon; a first polymeric layer adhered to the polymeric coating on the first face of the textile layer; and a second polymeric layer adhered to the polymeric coating on the second face of the textile layer; in which the polymeric coatings on the first and second faces of the textile layer are each formed by polymerising a polymeric precursor which includes a group of sub-formula (I) where R 2 and R 3 are independently selected from (CR 7 R 8 )n, or a group CR 9 R 10 , CR 7 R 8 CR 9 R 10 or CR 9 R 10 CR 7 R 8 where n is 0, 1 or 2, R 7 and R 8 are independently selected from hydrogen, halo or hydrocarbyl, and either One of R 9 or R 10 is hydrogen and the other is an electron withdrawing group, or R 9 and R 10 together form an electron withdrawing group, and R 4 and R 5 are independently selected from CH or CR 11 where R 11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X 1 is a group CX 2 X 3 where the dotted line bond to which it is attached is absent and a group CX 2 where the dotted line bond to which it is attached is present, Y 1 is a group CY 2 Y 3 where the dotted line bond to which it is attached is absent and a group CY 2 where the dotted line bond to which it is attached is present, and X 2 , X 3 , Y 2 and Y 3 are independently selected from hydrogen, fluorine or other substituents, R 1 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or formula (II), and R 13 is C(0) or S(0) 2 .

  本发明提供了一种复合制品，包括：一层纺织品，具有第一面和第二面，第一面和第二面上分别有聚合物涂层；第一聚合物层粘附在纺织品层的第一面上的聚合物涂层上；第二聚合物层粘附在纺织品层的第二面上的聚合物涂层上；其中，纺织品层的第一面和第二面上的聚合物涂层均由聚合聚合物前体形成，该聚合聚合物前体包括亚式(I)的一个基团，其中R2和R3分别选自(CR7R8)n或CR9R10、CR7R8CR9R10或CR9R10CR7R8的一个基团，n为0、1或2，R7和R8分别选自氢、卤素或烃基，R9和R10中的一个是氢，另一个是电子吸引基团，或R9和R10一起形成电子吸引基团，R4和R5分别选自CH或CR11，其中R11是电子吸引基团，虚线表示键的存在或不存在，X1是一个CX2X3基团，其中它所连接的虚线键不存在，并且是一个CX2基团，Y1是一个CY2Y3基团，其中它所连接的虚线键不存在，并且是一个CY2基团，X2、X3、Y2和Y3分别选自氢、氟或其他取代基，R1选自氢、卤素、硝基、烃基、可选择的取代基或插入功能基团，或式(II)，R13是C(0)或S(0)2。
• Ashless dispersant compounds, their preparation, and their use in providing dispersancy in lubricating oils or liquid fuels
  申请人：EDWIN COOPER INC.

  公开号：EP0087234A1

  公开（公告）日：1983-08-31

  Novel ashless dispersants are provided by oil-soluble compounds each defined as an olefin polymer having an average molecular weight of 500-500,000 to which is grafted an N-allyl amide having the structure wherein R, is hydrogen or a hydrocarbon group containing from 1 to 30 carbon atoms or R, may be absent, R2 is hydrogen, an alkyl group containing from 1-30 carbon atoms, a cycloalkyl group containing from 6-10 carbon atoms, an aryl group containing from 6-10 carbon atoms or, allyl, and n is 1 or 2; provided that when R1 is hydrogen n is 1, when R, is a hydrocarbon group containing from 1 to 30 carbon atoms n is either 1 or 2, and when R, is absent n is 2. Such products may be made by reacting the N-alkyl amide and olefin polymer in the presence of a free radical-generating catalyst. Lubricating oil dispersancy is improved by adding to the oil such a product.

  新型无灰分散剂由油溶性化合物提供，每种化合物都定义为平均分子量为 500-500,000 的烯烃聚合物，其中接枝了具有以下结构的 N-烯丙基酰胺 其中 R 为氢或含 1-30 个碳原子的烃基或 R 可以不存在，R2 为氢、含 1-30 个碳原子的烷基、含 6-10 个碳原子的环烷基、含 6-10 个碳原子的芳基或烯丙基，n 为 1 或 2；但当 R1 为氢时，n 为 1；当 R 为含 1-30 个碳原子的烃基时，n 为 1 或 2；当 R 不存在时，n 为 2。此类产品可通过在产生自由基的催化剂存在下使 N-烷基酰胺和烯烃聚合物发生反应而制成。在润滑油中加入此类产品，可改善润滑油的分散性。