propanedioic acid ethyl 2-methyl-2-propenyl diester | 123489-11-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: propanedioic acid ethyl 2-methyl-2-propenyl diester
• 英文别名: ethyl (2-methylallyl) malonate；monoethyl monomethallyl malonate；1-O-ethyl 3-O-(2-methylprop-2-enyl) propanedioate
• CAS: 123489-11-2
• 化学式: C₉H₁₄O₄
• 分子量: 186.208
• InChiKey: MIUSBWABFVSYRF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  propanedioic acid ethyl 2-methyl-2-propenyl diester 以7%的产率得到
  参考文献：
  名称：

  OUMAR-MAHAMAT, H.;MOUSTROU, C.;SURZUR, J. -M.;BERTRAND, M. P., J. ORG. CHEM., 54,(1989) N4, C. 5684-5688

  摘要：

  DOI：
• 作为产物：
  描述：

  ethyl potassium malonate 、 3-氯-2-甲基丙烯 以 N,N-二甲基甲酰胺 为溶剂， 反应 4.0h， 以40%的产率得到propanedioic acid ethyl 2-methyl-2-propenyl diester
  参考文献：
  名称：

  Diarylbutadiene-substituted diorganopolysiloxanes and photoprotective compositions comprised thereof

  摘要：

  新型4,4-二芳基丁二烯取代的二有机聚硅氧烷，其结构式为(1)或(2)：其中A是下式(3)的基团：对于抵御UV辐射对人体皮肤的损害，特别是UV-A辐射，这些化合物是有用的防晒剂。

  公开号：

  US20050129636A1

文献信息

• Lewis Acid-Catalyzed Tandem Reaction Strategy for the Synthesis of Dihydrophenalene-Fused Lactones
  作者：Mingjing OuYang、Jiewen OuYang、Yibin Dong、Jinwei Li、Wen Yang

  DOI：10.1021/acs.joc.4c00314

  日期：2024.5.3

  A Lewis acid-catalyzed tandem reaction strategy for the construction of a dihydrophenalene–lactone tetracyclic skeleton has been disclosed. Starting with 2-naphthol-tethered ketones and active methylene esters, the tandem reaction catalyzed by Sc(OTf)3 proceeded well to afford an array of dihydrophenalene-fused lactones with moderate to high efficiency and diastereoselectivity. Moreover, the synthetic

  已经公开了用于构建二氢苯那烯-内酯四环骨架的路易斯酸催化串联反应策略。从2-萘酚系酮和活性亚甲基酯开始，Sc(OTf) 3催化的串联反应进展顺利，得到一系列具有中等到高效率和非对映选择性的二氢苯那稠合内酯。此外，该方案的合成实用性通过简单的克级制备和多样化的产品转化得到了证明。
• Lactone synthesis by manganese(III)-mediated oxidative cyclization of allylic .beta.-diesters
  作者：H. Oumar-Mahamat、C. Moustrou、J. M. Surzur、M. P. Bertrand

  DOI：10.1021/jo00285a014

  日期：1989.11
• US7229610B2
  申请人：——

  公开号：US7229610B2

  公开（公告）日：2007-06-12
• US7439380B2
  申请人：——

  公开号：US7439380B2

  公开（公告）日：2008-10-21
• [EN] DYEING PROCESS USING A COMPOSITION COMPRISING A GLYCOSYL IRIDOID COMPOUND AND A NUCLEOPHILE OR AN AMINO OR THIO POLYMER, COMPOSITION AND DEVICES THEREFOR<br/>[FR] PROCÉDÉ DE COLORATION UTILISANT UNE COMPOSITION COMPRENANT UN COMPOSÉ IRIDOÏDE GLYCOSYLIQUE ET UN NUCLÉOPHILE OU UN POLYMÈRE AMINÉ OU THIOLÉ ET COMPOSITION ET DISPOSITIFS S'Y RAPPORTANT
  申请人：OREAL

  公开号：WO2013045701A2

  公开（公告）日：2013-04-04

  The present invention relates to a process of dyeing human keratin fibres by applying a composition, comprising, in a cosmetically acceptable medium: * a compound of the iridoid family of formula (I) below, or a plant extract comprising the same: formula (I) in which hydrogen, methyl, hydroxymethyl, aldehyde; -CO2R4 in which R4: hydrogen, C1-C2 alkyl; sugar; R2: a hydrogen atom, a hydroxyl radical, sugar radical; R3: hydrogen, hydroxyl, alkyloxy; R: sugar radical (aldose or derivative); integer ranging from 1 to 5; the compound(s) of formula (I) having undergone prior to or simultaneously with the dyeing process, a step consisting in replacing the radical R with a hydrogen atom; ** at least one particular nucleophilic compound or at least one amino or thio polymer, in an amino or thio polymer(s)/compound(s) of formulae (I) and/or (II) weight ratio of at least 0.01. The invention also relates to multi-compartment devices.