2-dodecyloxyphenol | 169206-40-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-dodecyloxyphenol
• 英文别名: 2-Dodecyloxy-phenol；Dodecyl-(2-hydroxy-phenyl)-aether；O-Dodecyl-brenzcatechin；2-Hydroxy-1-dodecyloxy-benzol；2-dodecoxyphenol
• CAS: 169206-40-0
• 化学式: C₁₈H₃₀O₂
• 分子量: 278.435
• InChiKey: RISYVLILTAVNNP-UHFFFAOYSA-N

物化性质

• 沸点：
  383.9±15.0 °C(Predicted)
• 密度：
  0.948±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  20
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-dodecyloxyphenol 在 溴 、 potassium carbonate 作用下， 以 二氯甲烷 、 丙酮 为溶剂， 反应 48.0h， 生成 1,2-dibromo-4-dodecyloxy-5-(1,4,7,10-tetraoxaundecyl)benzene
  参考文献：
  名称：

  Clarkson, Guy J.; McKeown, Neil B.; Treacher, Kevin E., Journal of the Chemical Society. Perkin transactions I, 1995, # 14, p. 1817 - 1824

  摘要：

  DOI：
• 作为产物：
  描述：

  邻苯二酚 、 溴代十二烷 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以62 %的产率得到2-dodecyloxyphenol
  参考文献：
  名称：

  过渡金属配合物60†的盘状液晶：基于二硫醇镍配合物的新型盘状液晶的合成和π受体能力

  摘要：

  我们合成了 13 种基于具有 π 受体特性的二硫醇镍配合物的新型金属介晶：(o-C12OPhO)4DTNi (1)、(m-C12OPhO)4DTNi (2)、(p-C12OPhO)4DTNi (3)、[o, m-(C12O)2Ph...

  DOI：

  10.1080/15421406.2023.2272393

文献信息

• [EN] A PROCESS FOR THE PREPARATION OF UV ABSORBERS<br/>[FR] PROCÉDÉ DE PRÉPARATION D'ABSORBEURS UV
  申请人：BASF SE

  公开号：WO2020144094A1

  公开（公告）日：2020-07-16

  The presently claimed invention relates to a novel, highly efficient and general process for the preparation of UV absorbers.

  目前所声称的发明涉及一种新颖、高效和通用的紫外线吸收剂制备过程。
• Substituted phthalocyanides with sulfonyl substituted with amino or
  申请人：The Secretary of State for Defence in Her Majesty's Government of the

  公开号：US05792860A1

  公开（公告）日：1998-08-11

  Phthalocyanines of formula (I) are described, wherein M is a metal atom, metal compound or silicon or a compound of silicon or is 2H; R.sub.1 -R.sub.25 may be the same or different, provided that at least one of R.sub.1 -R.sub.25 has the Formula (II), wherein Y groups are independently H, C.sub.1-3 alkyl, halogen or CN; k=0 or 1; l=1-10; m=0 or 1; n=1-10; p=1-10; q=1-20; r=0 or 1; X may be H, Me, etc . . . Compounds of the above formulae are useful in a broad range of applications, including electrooptical devices, and for use in optical recording media. ##STR1##

  本文描述了式(I)的酞菁化合物，其中M是金属原子、金属化合物、硅或硅化合物或2H；R.sub.1-R.sub.25可以相同也可以不同，但至少其中一个R.sub.1-R.sub.25具有式(II)，其中Y基独立地是H、C.sub.1-3烷基、卤素或CN；k=0或1；l=1-10；m=0或1；n=1-10；p=1-10；q=1-20；r=0或1；X可以是H、Me等。上述式的化合物在广泛的应用中有用，包括电光器件和用于光记录媒介。
• AMINOETHYLATION PROCESS HAVING IMPROVED YIELD OF ARYLOXYALKYLENE AMINE COMPOUNDS AND REDUCED UREA BY-PRODUCTS
  申请人：McDougall Patrick J.

  公开号：US20140073814A1

  公开（公告）日：2014-03-13

  Disclosed is a process for preparing an aryloxyalkylene amine compound via an aminoethylation reaction comprising: a) reacting an aromatic hydroxyl compound in the presence of a basic catalyst with a 2-oxazolidinone compound of the formula II to form an intermediate reaction product; wherein R 3 is selected from the group consisting of hydrogen or lower alkyl having 1 to 6 carbon atoms, R 4 is selected from the group consisting of hydrogen, straight or branched chain alkyl having from one to six carbon atoms, phenyl, alkaryl, or arylalkyl; and b) reacting the intermediate product of step a) with a polyalkylene polyamine.

  揭示了一种通过氨基乙基化反应制备芳基氧基烷胺化合物的过程，包括：a)在碱性催化剂存在下，将芳香羟基化合物与式II的2-噁唑烷酮化合物反应，形成中间反应产物；其中R3选自氢或1至6个碳原子的较低烷基，R4选自氢、一元或分支链烷基（含1至6个碳原子）、苯基、烷基芳基或芳基烷基；b)将步骤a）中间产物与聚烷基聚胺反应。
• N-Substituted Carbamic Acid Ester Production Method, Isocyanate Production Method Using Such N-Substituted Carbamic Acid Ester, And Composition For Transfer And Storage Of N-Substituted Carbamic Acid Ester Comprising N-Substituted Carbamic Acid Ester and Aromatic Hydroxy Compound
  申请人：Shinohata Masaaki

  公开号：US20110133121A1

  公开（公告）日：2011-06-09

  The present invention is a method for producing an N-substituted carbamic acid ester derived from an organic amine from an organic amine, a carbonic acid derivative and a hydroxy composition containing one or more types of hydroxy compounds, wherein the organic amine, the carbonic acid derivative and the hydroxy composition are reacted using a urethane production reaction vessel provided with a condenser, a gas containing the hydroxy composition, the compound having the carbonyl group derived from the carbonic acid derivative, and an ammonia formed as a by-product in the reaction, is introduced into the condenser provided in the urethane production reaction vessel, and the hydroxy composition and the compound having the carbonyl group derived from the carbonic acid derivative are condensed, and wherein a stoichiometric ratio of a hydroxy compound contained in the condensed hydroxy composition to the condensed compound having the carbonyl group derived from the carbonic acid derivative is 1 or more, and a ratio of number of carbonyl groups (—C(═O)—) contained in the compound having the carbonyl group derived from the carbonic acid derivative and number of ammonia molecules contained in the ammonia recovered as a gas from the condenser is 1 or less.

  本发明涉及一种从有机胺、碳酸衍生物和含有一种或多种羟基化合物中制得的N-取代氨基甲酸酯的制备方法，其中使用一种含有冷凝器的脲类生产反应容器反应有机胺、碳酸衍生物和羟基化合物，将含有羟基化合物的气体、来自碳酸衍生物衍生的含有羰基基团的化合物、以及在反应中形成的氨气体引入到脲类生产反应容器中的冷凝器中，使羟基化合物和含有羰基基团的化合物冷凝，其中在冷凝的羟基化合物中所含有的羟基化合物与冷凝的含有羰基基团的化合物中所含有的羰基基团的化合物的比例为1或更多，而且在从冷凝器中回收的氨气体中所含有的羰基基团（—C(═O)—）数与氨分子数的比例为1或更少。
• N-Substituted Carbamic Acid Ester Production Method, Isocyanate Production Method Using Such N-Substituted Carbamic Acid Ester, and Composition for Transfer and Storage of N-Substituted Carbamic Acid Ester Comprising N-Substituted Carbamic Acid Ester and Aromatic Hydroxy Compound
  申请人：Asahi Kasei Chemicals Corporation

  公开号：US20140194650A1

  公开（公告）日：2014-07-10

  The present invention is a method for producing an N-substituted carbamic acid ester derived from an organic amine from an organic amine, a carbonic acid derivative and a hydroxy composition containing one or more types of hydroxy compounds, wherein the organic amine, the carbonic acid derivative and the hydroxy composition are reacted using a urethane production reaction vessel provided with a condenser, a gas containing the hydroxy composition, the compound having the carbonyl group derived from the carbonic acid derivative, and an ammonia formed as a by-product in the reaction, is introduced into the condenser provided in the urethane production reaction vessel, and the hydroxy composition and the compound having the carbonyl group derived from the carbonic acid derivative are condensed, and wherein a stoichiometric ratio of a hydroxy compound contained in the condensed hydroxy composition to the condensed compound having the carbonyl group derived from the carbonic acid derivative is 1 or more, and a ratio of number of carbonyl groups (—C(═O)—) contained in the compound having the carbonyl group derived from the carbonic acid derivative and number of ammonia molecules contained in the ammonia recovered as a gas from the condenser is 1 or less.

  本发明是一种从有机胺、碳酸酯衍生物和含有一种或多种羟基化合物中制备N-取代的氨基甲酸酯的方法，其中利用一种尿素生产反应容器反应有机胺、碳酸酯衍生物和羟基化合物，该反应容器配有冷凝器，将含有羟基化合物的气体、由碳酸酯衍生物产生的含有羰基基团的化合物以及在反应中生成的氨引入到尿素生产反应容器中的冷凝器中，将羟基化合物和含有羰基基团的碳酸酯衍生物冷凝，其中在冷凝的羟基化合物中所含的羟基化合物的化学计量比与所冷凝的含有羰基基团的化合物的化学计量比为1或更多，而且所含有羰基基团的化合物中所含的羰基基团（-C(═O)-）的数量与从冷凝器中回收的氨分子数量的比率为1或更小。