formic acid-(β,β'-dichloro-isopropyl ester) | 64030-32-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: formic acid-(β,β'-dichloro-isopropyl ester)
• 英文别名: Ameisensaeure-(β,β'-dichlor-isopropylester)；1,3-Dichloropropan-2-yl formate
• CAS: 64030-32-6
• 化学式: C₄H₆Cl₂O₂
• mdl: MFCD19234414
• 分子量: 156.996
• InChiKey: RNRNWPWHOZCDEY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  formic acid-(β,β'-dichloro-isopropyl ester) 、 alkaline earth salt of/the/ methylsulfuric acid 生成 potassium formate
  参考文献：
  名称：

  Pfungst, Journal fur praktische Chemie (Leipzig 1954), 1886, vol. <2>34, p. 28

  摘要：

  DOI：
• 作为产物：
  描述：

  硝基甲烷 、 1,3-二氯丙醇 生成 formic acid-(β,β'-dichloro-isopropyl ester)
  参考文献：
  名称：

  Pfungst, Journal fur praktische Chemie (Leipzig 1954), 1886, vol. <2>34, p. 28

  摘要：

  DOI：

文献信息

• 3-(4,5-Dihydroisoxaxol-5-yl)benzoylcyclohexenones and the use thereof as herbicides
  申请人：——

  公开号：US20030199699A1

  公开（公告）日：2003-10-23

  The invention relates to 3-(4,5-dihydroisoxazole-5-yl)benzoylcyclohexenones of the general formula (I), wherein the variables have the following meanings: R 1 , R 2 represents hydrogen, nitro, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkysulfonyl or C 1 -C 6 haloalkylsulfonyl; R 3 represents hydrogen, halogen or alkyl; R 4 represents hydrogen or alkyl; R 5 , R 6 represents hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl, benzyl or carbonyl, wherein the 7 last residues can be substituted; R 11 represents optionally substituted cyclohexenone that is linked in the 2 position and that carries a hydroxy residue or derivatives thereof in the 1 position. The invention further relates to the agriculturally useful salts thereof, to methods for producing the 3-(4,5-dihydroisoxazole-5-yl)benzoylcyclohexenones, to agents that contain the inventive compound, and to the use of said derivatives or agents containing them for controlling undesired plants.

  该发明涉及通式（I）的3-(4,5-二氢异噁唑-5-基)苯甲酰环己烯酮，其中变量具有以下含义：R1，R2代表氢、硝基、卤素、氰基、烷基、卤代烷基、烷氧基、卤代烷氧基、烷硫基、卤代烷硫基、烷基磺酰基、卤代烷基磺酰基或C1-C6卤代烷基磺酰基；R3代表氢、卤素或烷基；R4代表氢或烷基；R5，R6代表氢、卤素、氰基、硝基、烷基、烷氧基、烷硫基、二烷基氨基、苯基、苄基或羰基，其中最后7个残基可以被取代；R11代表在2位连接的可选择取代的环己烯酮，在1位携带一个羟基残基或其衍生物。该发明还涉及其农业上有用的盐，生产3-(4,5-二氢异噁唑-5-基)苯甲酰环己烯酮的方法，含有该创新化合物的药剂，以及用于控制不受欢迎植物的衍生物或含有它们的药剂的用途。
• 3-(4,5-dihydroisoxazol-5-yl)benzoylpyrazole
  申请人：——

  公开号：US20030100590A1

  公开（公告）日：2003-05-29

  1 The invention relates to 3-(4,5-dihydroisoxazole-5-yl)benzoylpyrazole of the formula (I), wherein the variables have the following meanings: R 1 , R 1 represent hydrogen, nitro, halogen, cyano, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl or halogenalkylsulfonyl; hydrogen, R 3 represents halogen or alkyl; R 4 represents hydrogen or alkyl; R 5 , R 6 represent hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl R 3 or carbonyl, wherein the latter six groups can be substituted; R 7 represents halogen, cyano, hydroxy, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl, halogenalkylsulfonyl, amino, alkylamino, dialkylamino, dialkoxymethyl, hydroxyiminoalkyl, alkoxyiminoalkyl or optionally substituted carbonyl; R 11 represents optionally substituted pyrazole that is bound in the 4 position and that carries a hydroxy group or a derivative thereof in the 5 position. The invention also relates to the agriculturally useful salts thereof, to methods and to intermediate products for preparing the 3-(4,5-dihydroisoxazole-5-yl)benzoylpyrazole, to agents containing them and to the use of said derivatives or the agents containing them for combatting undesired plants.

  本发明涉及式（I）的3-（4,5-二氢异噁唑-5-基）苯甲酰吡唑，其中变量具有以下含义：R1，R1代表氢，硝基，卤素，氰基，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，卤代烷硫基，烷基亚磺酰基，卤代烷基亚磺酰基，烷基磺酰基或卤代烷基磺酰基; 氢，R3代表卤素或烷基; R4代表氢或烷基; R5，R6代表氢，卤素，氰基，硝基，烷基，烷氧基，烷硫基，二烷基氨基，苯基R3或羰基，其中后六个基团可以被取代; R7代表卤素，氰基，羟基，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，卤代烷硫基，烷基亚磺酰基，卤代烷基亚磺酰基，烷基磺酰基，卤代烷基磺酰基，氨基，烷基氨基，二烷基氨基，二烷氧甲基，羟基亚氨基烷基，烷氧基亚氨基烷基或可选取代的羰基; R11代表在4位上结合的可选取代的吡唑，并在5位上携带羟基或其衍生物的吡唑。本发明还涉及其在农业上有用的盐，制备3-（4,5-二氢异噁唑-5-基）苯甲酰吡唑的方法和中间体，含有它们的制剂以及使用该衍生物或含有它们的制剂来对抗不良植物的用途。
• 3-heterocycly1 - substituted benzoyl derivatives
  申请人：——

  公开号：US20020025910A1

  公开（公告）日：2002-02-28

  Benzoyl derivatives of the formula I 1 where the variables have the following meanings: R 1 , R 2 are hydrogen, nitro, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl or C 1 -C 6 -haloalkylsulfonyl; R 3 is hydrogen, halogen or alkyl; R 4 , R 5 are hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl or carbonyl, it being possible for the 6 last-mentioned radicals to be substituted; X is O, S, NR 9 , CO or CR 10 R 11 ; Y is O, S, NR 12 , CO or CR 13 R 14 ; R 15 is pyrazole which is unsubstituted or substituted, linked in the 4-position and has attached to it in the 5-position a hydroxyl or sulfonyloxy radical; and the agriculturally useful salts thereof; processes and intermediates for the preparation of the 3-heterocyclyl-substituted benzoyl derivatives, compositions comprising them; and the use of these derivatives or compositions comprising them for controlling undesirable plants.

  化合物I1的苯甲酰衍生物，其中变量具有以下含义：R1，R2为氢，硝基，卤素，氰基，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，卤代烷硫基，烷基磺酰基，卤代烷基磺酰基，烷基磺酸基或C1-C6-卤代烷基磺酸基；R3为氢，卤素或烷基；R4，R5为氢，卤素，氰基，硝基，烷基，烷氧基，烷硫基，二烷基氨基，苯基或羰基，其中可能有6个最后提到的基团被取代；X为O，S，NR9，CO或CR10R11；Y为O，S，NR12，CO或CR13R14；R15为吡唑，其未取代或取代，连接在4位，并在5位上附有羟基或磺酰氧基基团；以及其农业上有用的盐；制备3-杂环基取代的苯甲酰衍生物的方法和中间体，包含它们的组合物；以及使用这些衍生物或包含它们的组合物来控制不良植物。
• 5[(pyrazol-4-yl)carbonyl]benzazolone as herbicide
  申请人：——

  公开号：US20040033899A1

  公开（公告）日：2004-02-19

  Pyrazolylbenzazolones of the formula I 1 where the variables R 1 , R 2 , R 3 , A and Pz are as defined in claim 1 , and their salts, and their use for controlling harmful plants, are described.

  本文描述了式I1中变量R1，R2，R3，A和Pz如权利要求1所定义的吡唑基苯并咪唑酮及其盐的使用，用于控制有害植物。
• Benzazolonylcarbonylcyclohexenones and their use ss herbicides
  申请人：——

  公开号：US20040063584A1

  公开（公告）日：2004-04-01

  Cyclohexenone derivatives of benzazolones of the formula I 1 where the variables R 1 , R 2 , R 3 , A and Hex are as defined in claim 1, and their salts, and their use for controlling harmful plants, are described.

  本发明涉及苯并咪唑酮的环己烯酮衍生物，其化学式为I1，其中变量R1，R2，R3，A和Hex如权利要求1所定义，以及它们的盐，以及它们用于控制有害植物的用途。