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di(o-tolyl) sulfate | 67628-61-9

中文名称
——
中文别名
——
英文名称
di(o-tolyl) sulfate
英文别名
Di-m-tolyl-sulfat;Bis(2-methylphenyl) sulfate
di(o-tolyl) sulfate化学式
CAS
67628-61-9
化学式
C14H14O4S
mdl
——
分子量
278.329
InChiKey
FRNXGERZXOCFQR-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 沸点:
    407.4±38.0 °C(Predicted)
  • 密度:
    1.271±0.06 g/cm3(Predicted)

计算性质

  • 辛醇/水分配系数(LogP):
    4.1
  • 重原子数:
    19
  • 可旋转键数:
    4
  • 环数:
    2.0
  • sp3杂化的碳原子比例:
    0.14
  • 拓扑面积:
    61
  • 氢给体数:
    0
  • 氢受体数:
    4

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

  • 作为反应物:
    描述:
    di(o-tolyl) sulfate苯基溴化镁二氯化双(三环己基膦)镍(II)三环己基膦 作用下, 以 乙醚 为溶剂, 反应 2.0h, 以88%的产率得到2-(p-氯苯氧基)-2-甲基丙酸盐二异丙基铵
    参考文献:
    名称:
    Biaryl Construction through Kumada Coupling with Diaryl Sulfates as One-by-One Electrophiles under Mild Conditions
    摘要:
    Diaryl sulfates were successfully applied as one-by-one organo electrophiles in Kumada coupling to construct biaryls with the emission of harmless inorganic salts.
    DOI:
    10.1021/ol9028308
  • 作为产物:
    描述:
    邻甲酚caesium carbonateN,N-硫酰二咪唑 作用下, 以 四氢呋喃 为溶剂, 以95%的产率得到di(o-tolyl) sulfate
    参考文献:
    名称:
    Biaryl Construction through Kumada Coupling with Diaryl Sulfates as One-by-One Electrophiles under Mild Conditions
    摘要:
    Diaryl sulfates were successfully applied as one-by-one organo electrophiles in Kumada coupling to construct biaryls with the emission of harmless inorganic salts.
    DOI:
    10.1021/ol9028308
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文献信息

  • Mass and infrared spectra of diaryl and aryl alkyl sulfate diesters
    作者:G. Paulson、J. Bakke、J. Giddings、M. Simpson
    DOI:10.1002/bms.1200050206
    日期:1978.2
    The synthesis and the infrared and mass spectra of diaryl and aryl alkyl sulfate diesters are described. The mass spectra of these two classes of compounds consistently showed an intense molecular ion and two or three additional intense, diagnostic ions. Their infrared spectra also gave information useful for characterizing and differentiating these two classes of compounds.
    描述了二芳基和芳基烷基硫酸二酯的合成以及红外光谱和质谱图。这两类化合物的质谱图始终显示强分子离子和两个或三个其他强诊断离子。它们的红外光谱还提供了有助于表征和区分这两类化合物的信息。
  • Silicone resins and process for synthesis
    申请人:DOW CORNING CORPORATION
    公开号:EP1059322A2
    公开(公告)日:2000-12-13
    A method for hydrolyzing chlorosilanes having at least three chlorine atoms bonded to each silicon atom to form silicone resins is disclosed. The method comprises adding at least one hydridotrichlorosilane, tetrachlorosilane, or organotrichlorosilane to a two-phase mixture containing a non-polar organic solvent, an aqueous phase containing 0 to 43 weight percent hydrochloric acid and a surface active compound represented by the formula wherein Q is selected from monovalent hydrocarbon radicals, A is selected from the hydrogen atom and alkali metal and n is 0 or 1:
    本发明公开了一种水解每个硅原子上至少键合有三个氯原子的氯硅烷以形成硅树脂的方法。该方法包括将至少一种氢ridotrichlorosilane、tetrachlorosilane 或 organotrichlorosilane 加入到一种两相混合物中,该混合物包含一种非极性有机溶剂、一种含 0 至 43 重量百分比盐酸的水相和一种由式表示的表面活性化合物。 其中 Q 选自一价烃基,A 选自氢原子和碱金属,n 为 0 或 1:
  • US6395825B1
    申请人:——
    公开号:US6395825B1
    公开(公告)日:2002-05-28
  • Biaryl Construction through Kumada Coupling with Diaryl Sulfates as One-by-One Electrophiles under Mild Conditions
    作者:Bing-Tao Guan、Xing-Yu Lu、Yang Zheng、Da-Gang Yu、Tong Wu、Kun-Lin Li、Bi-Jie Li、Zhang-Jie Shi
    DOI:10.1021/ol9028308
    日期:2010.1.15
    Diaryl sulfates were successfully applied as one-by-one organo electrophiles in Kumada coupling to construct biaryls with the emission of harmless inorganic salts.
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