1,2-epoxy-3-(2,3-dichloropropoxy)propane | 59778-09-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: 1,2-epoxy-3-(2,3-dichloropropoxy)propane
• 英文别名: 2-(2,3-dichloropropoxymethyl)oxirane
• CAS: 59778-09-5
• 化学式: C₆H₁₀Cl₂O₂
• 分子量: 185.05
• InChiKey: VIDQCFGKSNWICH-UHFFFAOYSA-N

物化性质

• 沸点：
  263.6±25.0 °C(Predicted)
• 密度：
  1.281±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-epoxy-3-(2,3-dichloropropoxy)propane 在 potassium sulfamate 作用下， 以 乙醇 、 水 为溶剂， 反应 30.0h， 以85%的产率得到
  参考文献：
  名称：

  Synthesis ofN-3-chloroalkoxy-2-nitroxypropyl-N-alkylnitramines and their subsequent azidation

  摘要：

  Nitration of N-3-chloroalkoxy-2-hydroxypropyl-N-alkylsulfamates gave the corresponding N-3-chloroalkoxy-2-nitroxypropyl-N-alkylnitramines Azidation of the latter resulted in N-azido-3-azidoalkoxypropyl-N-alkylnitramines.

  DOI：

  10.1007/bf02495971
• 作为产物：
  描述：

  1-chloro-3-(2,3-dichloropropoxy)-2-propanol 在 sodium hydroxide 作用下， 以 乙醚 为溶剂， 生成 1,2-epoxy-3-(2,3-dichloropropoxy)propane
  参考文献：
  名称：

  1-氯-2,3-环氧丙烷与烯丙醇的离子端聚反应及其产物的性质

  摘要：

  研究了在三氟化硼醚化物的存在下，用烯丙醇对1-氯-2,3-环氧丙烷进行的离子端聚反应，作为卤代环氧低聚醚的途径。进行中间低聚（氯醇）的选择性氯化或溴化，然后用NaOH将中间低聚卤代醇脱氯化氢（环氧化）。合成的产物可有效用作基于ED-20树脂的化合物的活性稀释剂。

  DOI：

  10.1134/s1070427213090084

文献信息

• MAMEDOV M. A.; GUSEJNOV M. M.; MAMEDOV N. N.; AGAEV M. T., V SB. ZHPOKSID. MONOMERY I EHPOKSID. SMOLY. ZHAKU, ZHLM, 1975, 70-73
  作者：MAMEDOV M. A.、 GUSEJNOV M. M.、 MAMEDOV N. N.、 AGAEV M. T.

  DOI：——

  日期：——
• PROCESS AND APPARATUS FOR PURIFICATION OF INDUSTRIAL BRINE
  申请人：Hook Bruce

  公开号：US20100193732A1

  公开（公告）日：2010-08-05

  Processes and apparatus for purifying brine are provided including (1) providing an aqueous brine solution comprising one or more inorganic salts and one or more organic compounds and (2) conducting at least one unit operation for removing organic compounds from the brine solution to obtain a purified brine solution.
• BRINE PURIFICATION
  申请人：Hook Bruce

  公开号：US20100219372A1

  公开（公告）日：2010-09-02

  Process and apparatus for reducing organic content of brine comprising subjecting a brine solution to at least two purification treatments selected from electrochemical treatment, chlorinolysis, or other chemical oxidation treatment, carbon adsorption, extraction, biological treatment and chrystallizing treatment; wherein the organic content of purified brine is sufficiently low to enable sense of the purified brine in an industrial process.
• PROCESS, ADAPTED MICROBES, COMPOSITION AND APPARATUS FOR PURIFICATION OF INDUSTRIAL BRINE
  申请人：Pereira Celio Lume

  公开号：US20100261255A1

  公开（公告）日：2010-10-14

  Process for purifying brine including providing an aqueous brine solution comprising one or more inorganic salts, one or more organic compounds, and optionally one or more microbial nutrients other than microbial nutrients comprised in the one or more inorganic salts and the one or more organic compounds and conducting at least one unit operation for removing organic compounds from the aqueous brine solution provided in step (1) to obtain a first purified brine solution, wherein the at least one unit operation comprises contacting the aqueous brine solution with living microbes capable of oxidizing the organic compounds in the presence of oxygen.
• Ionic telomerization of 1-chloro-2,3-epoxypropane with allyl alcohol and properties of products obtained
  作者：A. Kh. Kerimov、A. T. Orudzheva、Kh. A. Mamedova、U. A. Alieva

  DOI：10.1134/s1070427213090084

  日期：2013.9

  Ionic telomerization of 1-chloro-2,3-epoxypropane with allyl alcohol in the presence of boron trifluoride etherate as a route to halogenated epoxy oligoethers was studied. Selective chlorination or bromination of the intermediate oligo(chlorohydrin), followed by dehydrochlorination (epoxidation) of the intermediate oligohalohydrins with NaOH, was performed. The synthesized products are effi cient as

  研究了在三氟化硼醚化物的存在下，用烯丙醇对1-氯-2,3-环氧丙烷进行的离子端聚反应，作为卤代环氧低聚醚的途径。进行中间低聚（氯醇）的选择性氯化或溴化，然后用NaOH将中间低聚卤代醇脱氯化氢（环氧化）。合成的产物可有效用作基于ED-20树脂的化合物的活性稀释剂。