2-methylacrylic acid 3-(2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)benzyl ester | 1160001-17-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-methylacrylic acid 3-(2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)benzyl ester
• 英文别名: [3-[(2,2-Dimethyl-1,3-dioxolan-4-yl)methoxy]phenyl]methyl 2-methylprop-2-enoate；[3-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]phenyl]methyl 2-methylprop-2-enoate
• CAS: 1160001-17-1
• 化学式: C₁₇H₂₂O₅
• 分子量: 306.359
• InChiKey: UOVQLDZHVKZHBU-UHFFFAOYSA-N

物化性质

• 沸点：
  401.5±30.0 °C(predicted)
• 密度：
  1.096±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2,2-二甲基-1,3-二氧环戊基-4-甲醇对甲基苯磺酸酯 在 18-冠醚-6 、 sodium cyanoborohydride 、 potassium carbonate 、 溶剂黄146 、 三乙胺 作用下， 以 四氢呋喃 、 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 145.0h， 生成 2-methylacrylic acid 3-(2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)benzyl ester
  参考文献：
  名称：

  Synthesis and self-assembly of polyhydroxylated and electropolymerizable block copolymers

  摘要：

  A facile synthetic strategy for preparing hydroxylated polymethacrylate amphiphilic block copolymers (PCzMMA-b-PBMMA, PFlMMA-b-PBMMA) incorporated with primary and secondary hydroxyl groups and electroactive moieties along the polymer backbone is reported. Full characterization, structure-property relationship and self-assembly of these polymers are discussed. Due to interplay of hydrophobic/hydrophilic interactions, PCzMMA-b-PBMMA formed a layered lattice and PFlMMA-b-PBMMA showed a vesicular morphology. Electropolymerization of the electroactive units led to the formation of cross-conjugated polymer network in solution and in thin films. The network structure was characterized with a range of spectroscopic techniques. Such highly processable polymers may be of interest to applications in which a conducting amphiphilic films with strong adhesion to various substrates are required. (C) 2014 Wiley Periodicals, Inc.

  DOI：

  10.1002/pola.27234

文献信息

• Synthesis and self-assembly of polyhydroxylated and electropolymerizable block copolymers
  作者：Satyananda Barik、Suresh Valiyaveettil

  DOI：10.1002/pola.27234

  日期：2014.8.1

  A facile synthetic strategy for preparing hydroxylated polymethacrylate amphiphilic block copolymers (PCzMMA-b-PBMMA, PFlMMA-b-PBMMA) incorporated with primary and secondary hydroxyl groups and electroactive moieties along the polymer backbone is reported. Full characterization, structure-property relationship and self-assembly of these polymers are discussed. Due to interplay of hydrophobic/hydrophilic interactions, PCzMMA-b-PBMMA formed a layered lattice and PFlMMA-b-PBMMA showed a vesicular morphology. Electropolymerization of the electroactive units led to the formation of cross-conjugated polymer network in solution and in thin films. The network structure was characterized with a range of spectroscopic techniques. Such highly processable polymers may be of interest to applications in which a conducting amphiphilic films with strong adhesion to various substrates are required. (C) 2014 Wiley Periodicals, Inc.