9-(benzyloxy)-10-methylanthracene | 98612-71-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9-(benzyloxy)-10-methylanthracene
• 英文别名: 9-Methyl-10-phenylmethoxyanthracene
• CAS: 98612-71-6
• 化学式: C₂₂H₁₈O
• 分子量: 298.384
• InChiKey: VUMLWMKPSJPGLQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9-(benzyloxy)-10-methylanthracene 在 臭氧 作用下， 以 甲醇 为溶剂， 反应 0.25h， 以62%的产率得到1-methyl-8-phenylmethoxy-15,16,17-trioxatetracyclo[6.6.3.02,7.09,14]heptadeca-2,4,6,9,11,13-hexaene
  参考文献：
  名称：

  Transannular ozonides of 9-alkoxyanthracenes

  摘要：

  DOI：

  10.1021/jo00223a012
• 作为产物：
  描述：

  10-甲基-10H-蒽-9-酮 、 氯化苄 在 sodium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以66%的产率得到9-(benzyloxy)-10-methylanthracene
  参考文献：
  名称：

  Transannular ozonides of 9-alkoxyanthracenes

  摘要：

  DOI：

  10.1021/jo00223a012

文献信息

• SULFONIUM SALT, HEAT- OR PHOTO-ACID GENERATOR, HEAT- OR PHOTO-CURABLE COMPOSITION, AND CURED PRODUCT THEREOF
  申请人：SAN APRO LTD.

  公开号：US20190284134A1

  公开（公告）日：2019-09-19

  The sulfonium salt does not contain a toxic metal and exhibits higher cationic polymerization performance and crosslinking performance than a tetrakis(pentafluorophenyl)borate salt. The heat- or photo-acid generator contains the sulfonium salt. The sulfonium salt is formed of a sulfonium cation selected from a group represented by general formulas (1), (9), (10) and (11) described below and a gallate anion represented by formula (a). The heat- or photo-acid generator contains the sulfonium salt. The heat- or energy ray-curable composition contains the acid generator and a cationically polymerizable compound. A cured product can be obtained by curing the same.

  硫铵盐不含有毒金属，表现出比四(五氟苯基)硼酸盐更高的阳离子聚合性能和交联性能。热或光酸发生剂含有硫铵盐。硫铵盐由下面描述的通用公式(1)、(9)、(10)和(11)所代表的一组硫铵阳离子和由公式(a)代表的镓酸根阴离子形成。热或光酸发生剂含有硫铵盐。热或能量射线固化组合物含有酸发生剂和阳离子聚合性化合物。通过固化可以获得固化产品。
• SULFONIUM SALT, PHOTOACID GENERATOR, PHOTOCURABLE COMPOSITION, AND CURED PRODUCT THEREOF
  申请人：SAN-APRO LTD.

  公开号：US20190300476A1

  公开（公告）日：2019-10-03

  A sulfonium salt is formed of a sulfonium cation selected from a group indicated by general formulas (1), (2), and (3) and a gallate anion represented by formula (a). A photoacid generator is characterized in that said sulfonium salt is contained therein. An energy-ray curable composition contains the acid generator and a cationic polymerizable compound. A cured product is formed by curing these substances.

  一种磺胺盐由通式（1）、（2）和（3）所示的一组磺胺阳离子以及由式（a）表示的没食子酸根阴离子组成。一种光酸发生剂的特征在于其中含有该磺胺盐。一种能量射线固化组合物包含该酸发生剂和一个阳离子可聚合化合物。通过固化这些物质形成一个固化产物。
• SULFONIUM SALT, PHOTOACID GENERATOR, AND PHOTOSENSITIVE COMPOSITION
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20170305848A1

  公开（公告）日：2017-10-26

  A novel sulfonium salt having high sensitivity with respect to active energy rays, a photoacid generator including the sulfonium salt, and a photosensitive composition containing the photoacid generator. The sulfonium salt is represented by formula (a1). In the formula, R 1 and R 2 each independently represent the group that is represented by formula (a2) or an alkyl group that may be substituted by a halogen atom, R 1 and R 2 are bonded to each other and may form a ring with the sulfur atom within the formula, R 3 is the group represented by formula (a3) or the group represented by formula (a4), A 1 represents S or the like, X − represents a monovalent anion, and R 1 and R 2 are not both an alkyl group which may be substituted with a halogen atom. In formulas (a2) to (a4), the ring Z 1 represents an aromatic hydrocarbon ring, R 4 , R 6 , R 9 , and R 10 each represents a specific monovalent group, R 5 , R 7 , and R 8 each represents a specific divalent group, A 2 and A 3 each represents S or the like, m1 represents an integer of 0 or more, and n1 and n2 each represent 0 or more.

  一种对活性能量射线具有高敏感度的新型磺鎓盐，包括该磺鎓盐的光酸发生剂以及含有该光酸发生剂的光敏组合物。该磺鎓盐由公式（a1）表示。在该公式中，R1和R2分别表示由公式（a2）表示的基团或可能被卤素原子取代的烷基基团，R1和R2彼此相连并且可以与公式中的硫原子形成环，R3表示由公式（a3）表示的基团或由公式（a4）表示的基团，A1表示S或类似物，X-表示一价阴离子，且R1和R2不同时为可能被卤素原子取代的烷基基团。在公式（a2）到（a4）中，环Z1表示芳香族碳氢环，R4、R6、R9和R10各自表示特定的一价基团，R5、R7和R8各自表示特定的二价基团，A2和A3各自表示S或类似物，m1表示0或更多的整数，n1和n2各自表示0或更多。
• Novel Fluorinated Alkyl Fluorophosphoric Acid Salts of Onium and Ttransition Metal Complex
  申请人：Kimura Hideki

  公开号：US20070225458A1

  公开（公告）日：2007-09-27

  To obtain a polymerization initiator (acid generating agent) having excellent power for initiation of cationic polymerization without containing arsenic or antimony. [Means for solution] Provided is a specific onium salt or transition metal complex salt of a fluorinated alkyl fluorophosphoric acid.

  获取一种聚合引发剂（酸发生剂），具有优异的阳离子聚合引发能力，不含砷或锑。[解决方案的手段] 提供了一种特定的氟化烷基氟磷酸的烷基铵盐或过渡金属配合物盐。
• SULFONIUM SALT, PHOTOACID GENERATOR, AND PHOTOCURABLE COMPOSITION AND CURED BODY THEREOF
  申请人：Suzuki Issei

  公开号：US20110039205A1

  公开（公告）日：2011-02-17

  An object of the present invention is to provide a sulfonium salt that has sufficient photosensitivity by active energy rays, such as visible light, ultraviolet rays, electron beams, and X-rays. The present invention is a sulfonium salt represented by formula (1). It is noted that R 1 is a group represented by formula (2); R 2 and R 3 each represent an aryl group having 6 to 30 carbon atoms, a heterocyclic hydrocarbon group having 4 to 30 carbon atoms, an alkyl group having 1 to 30 carbon atoms, an alkenyl group having 2 to 30 carbon atoms, or an alkynyl group having 2 to 30 carbon atoms; X − represents a monovalent polyatomic anion; R 4 to R 6 each represent an alkyl group, or the like; k represents an integer of 0 to 4; m represents an integer of 0 to 3; n represents an integer of 0 to 4; and A represents a group represented by —S—, —O—, —SO—, —SO 2 —, or —CO—.

  本发明的目的是提供一种具有足够光敏度的烷基硫鎓盐，能够通过活性能量射线，如可见光、紫外线、电子束和X射线来激发。本发明是一种由式（1）表示的烷基硫鎓盐。其中，R1是由式（2）表示的基团；R2和R3分别表示具有6至30个碳原子的芳基基团、具有4至30个碳原子的杂环烃基团、具有1至30个碳原子的烷基基团、具有2至30个碳原子的烯基基团或具有2至30个碳原子的炔基基团；X-表示单价多原子阴离子；R4至R6分别表示烷基基团或类似物；k表示0至4的整数；m表示0至3的整数；n表示0至4的整数；A表示由—S—、—O—、—SO—、—SO2—或—CO—表示的基团。