Perfluoro(pentyl vinyl) ether | 34805-59-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: Perfluoro(pentyl vinyl) ether
• 英文别名: (Perfluor-n-pentylvinyl)ether；1,1,1,2,2,3,3,4,4,5,5-Undecafluoro-5-(1,2,2-trifluoroethenoxy)pentane
• CAS: 34805-59-9
• 化学式: C₇F₁₄O
• 分子量: 366.054
• InChiKey: XXOPBQKMXTVKNS-UHFFFAOYSA-N

物化性质

• 沸点：
  101.3±40.0 °C(Predicted)
• 密度：
  1.662±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  15

反应信息

• 作为产物：
  描述：

  2,2,3,3,4,4,5,5-八氟-1-戊醇 在 溴 、 氯 、 sodium hydride 、 fluorine 、 sodium fluoride 、 锌 作用下， 以 乙醚 、 N,N-二甲基甲酰胺 为溶剂， -10.0~85.0 ℃ 、2.41 MPa 条件下， 反应 27.0h， 生成 Perfluoro(pentyl vinyl) ether
  参考文献：
  名称：

  Synthesis of Perfluorovinyl Ether Monomers

  摘要：

  DOI：

  10.1021/jo00094a058

文献信息

• Fluorelastomers
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0208314A2

  公开（公告）日：1987-01-14

  A base resistant, substantially amorphous fluoroelastomer comprising (1) 10-40 mole percent ethylene units, (2) 32-60 mole percent tetrafluoroethylene units, (3) 20-40 mole percent perfluoro(alkyl vinyl ether) units wheren the alkyl group contains 1-5 carbon atoms and (4) a cure-site monomer. Such fluoroelastomers are resistant to attack by amines, strong bases and hydrogen sulfide and possess a combination of good low temperature and high temperature properties and they are resistant to oil swell. To prevent fluoroelastomers of the type described above, with or without units of ethylene, that contain a bromine-containing olefin as a peroxide cure site from sticking to the mold cavity when cured an N,N,N',N'-tetrasubstituted 1,8-diaminonaphthalene is added to the fluoroelastomer having the formula: wherein R1, R2, R3 and R4 are independently alkyl groups of 1-6 carbon atoms, phenyl or benzyl, R, and R2 and/or R3 and R4 can be joined to form a 5- or 6-membered heterocyclic ring in which a carbon atom can be replaced by an oxygen or a sulfur atom, R, and R3 and/or R2 and R4 can be joined to form a heterocyclic ring of 6-20 carbon atoms in which a carbon atom can be replaced by an oxygen or a sulfur atom, X and Y are independently an alkyl group or an alkoxy group containing 1-4 carbon atoms and n is 0-3.

  一种耐碱、基本无定形的氟弹性体，由以下成分组成：(1) 10-40 摩尔百分数的乙烯单元；(2) 32-60 摩尔百分数的四氟乙烯单元；(3) 20-40 摩尔百分数的全氟（烷基乙烯基醚）单元，其中烷基含有 1-5 个碳原子；(4) 一种固化位单体。这种氟弹性体能抵抗胺、强碱和硫化氢的侵蚀，同时具有良好的低温和高温性能，并能抵抗油膨胀。为了防止上述类型的含或不含乙烯单元的含溴烯烃作为过氧化物固化位点的氟弹性体在固化时粘在模腔上，在具有以下式子的氟弹性体中加入了 N,N,N',N'-四取代的 1,8-二氨基萘： 其中 R1、R2、R3 和 R4 独立地为 1-6 个碳原子的烷基、苯基或苄基，R 和 R2 和/或 R3 和 R4 可以连接形成 5 或 6 元杂环，其中一个碳原子可以被氧原子或硫原子取代，R、和 R3 和/或 R2 和 R4 可连接形成 6-20 个碳原子的杂环，其中一个碳原子可被氧原子或硫原子取代，X 和 Y 独立地为含 1-4 个碳原子的烷基或烷氧基，n 为 0-3。
• POLYTETRAFLUOROETHYLENE POWDER FOR MOLDING
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP0583481A1

  公开（公告）日：1994-02-23

  Polytetrafluoroethylene powder for molding, which contains 0.01-1 wt.% of perfluorovinyl ether units, has a heat of crystallization of 18.0-25.0 J/g, and provides a molded article having a bending life of 7 million cycles or above, a creep resistance (at 200 °C, total deformation) of 20 % or less, and a creep resistance (at 25 °C. total deformation) of 15 % or less. The powder is excellent in both creep resistance and bending fatigue resistance required of a molding material for the parts of a machine subjected to repeated bending, such as a pump.

  模塑用聚四氟乙烯粉末含有 0.01-1 重量百分比的全氟乙烯基醚单元，其结晶热为 18.0-25.0 焦耳/克，可提供弯曲寿命达 700 万次或以上、抗蠕变性（在 200 °C 时，总变形量）为 20% 或以下、抗蠕变性（在 25 °C 时，总变形量）为 15% 或以下的模塑制品。这种粉末在抗蠕变性和抗弯曲疲劳性方面都非常出色，是泵等需要反复弯曲的机器部件所需的成型材料。
• SEAL RING
  申请人：Daikin Industries, Ltd.

  公开号：EP1273614A1

  公开（公告）日：2003-01-08

  There is provided a seal ring which is excellent since the seal ring has a high durability under sliding at high pressure during a long-term use, and a necessary suitability for fitting. The seal ring can provide an effect of sealing oil stably for a long period of time, and possesses properties suitable particularly for a seal ring of endless type. The seal ring with a sliding surface, which is obtained by molding a molding powder or granulated powder of non-melt-moldable modified polytetrafluoroethylene containing 0.01 to 1 % by weight of a perfluorovinylether unit represented by the formula (I):         -CF2-CF(-O-X)-     (I) wherein X represents a perfluoroalkyl group having 1 to 6 carbon atoms or a perfluoroalkoxyalkyl group having 2 to 9 carbon atoms, said modified polytetrafluoroethylene having a heat of crystallization of 18 to 25 J/g measured by a differential scanning calorimeter.

  本发明提供了一种密封环，该密封环在长期使用过程中的高压滑动下具有很高的耐久性，而且非常适合安装。该密封环可以长期稳定地提供密封油的效果，并具有特别适合无端型密封环的特性。 带有滑动表面的密封环是通过将含有 0.01 至 1%（重量）由式（I）表示的全氟乙烯基醚单 位的非熔模改性聚四氟乙烯的模塑粉末或颗粒粉末进行模塑而获得的： -CF2-CF(-O-X)-(I) 其中 X 代表具有 1 至 6 个碳原子的全氟烷基或具有 2 至 9 个碳原子的全氟烷氧基，用差示扫描量热计测量，所述改性聚四氟乙烯的结晶热为 18 至 25 焦耳/克。
• Ozone-resistant injection-molded articles and injection-molding materials
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP2189492A1

  公开（公告）日：2010-05-26

  The present invention provides ozone-resistant injection-molded articles and relevant injection-molding materials.

  本发明提供了抗臭氧注塑物品和相关注塑材料。
• CONTAINER FOR CELL ADMINISTRATION, STORAGE OR CULTURING
  申请人：Daikin Industries, Ltd.

  公开号：EP3323878A1

  公开（公告）日：2018-05-23

  When mammal cells are administered by using a container whose surface in contact with the mammal cells is formed of a fluororesin material at least partially having a -CF3 terminal group or a container whose surface in contact with the mammal cells is formed of a fluororesin material having a total number of non-fluorinated group terminals and -CF2H group terminals in the fluororesin of 70 or less per 1 × 106 carbon atoms, or mammal cells are stored or cultured in such a container, the cell adhesion on the container inner surface and the cell survival rate reduction can effectively be suppressed. Therefore, by using these containers, a mammal cell-containing liquid having a high concentration and a high proportion of living cells can be administered, stored or prepared, which contributes to regenerative medicine using the mammal cell-containing liquid (suspension liquid).

  当使用一种容器给哺乳动物细胞施药时，该容器与哺乳动物细胞接触的表面是由至少部分具有-CF3末端基团的荧光素材料形成的，或者使用一种容器与哺乳动物细胞接触的表面是由荧光素材料形成的，该荧光素材料中的非氟化基团末端和-CF2H基团末端的总数为每1×106个碳原子中70个或更少、或哺乳动物细胞在这样的容器中储存或培养，可有效抑制细胞在容器内表面的粘附和细胞存活率的降低。因此，通过使用这些容器，可以施用、储存或制备具有高浓度和高比例活细胞的哺乳动物细胞含液，这有助于使用哺乳动物细胞含液（悬浮液）进行再生医学。