bis(2-ethylhexyl)phosphine oxide | 195195-90-5

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: bis(2-ethylhexyl)phosphine oxide
• 英文别名: di(2-ethylhexyl)phosphine oxide；3-(2-ethylhexylphosphonoylmethyl)heptane
• CAS: 195195-90-5
• 化学式: C₁₆H₃₅OP
• 分子量: 274.427
• InChiKey: YAIGSFCHRKDZJA-UHFFFAOYSA-N

物化性质

• 沸点：
  134 °C(Press: 0.5 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  5.98
• 重原子数：
  18.0
• 可旋转键数：
  12.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  bis(2-ethylhexyl)phosphine oxide 在 双氧水 作用下， 以 水 为溶剂， 以93.2%的产率得到双(2-乙基己基)次磷酸
  参考文献：
  名称：

  Ruthenium(II) Complexes Bearing a Naphthalimide Fragment: A Modular Dye Platform for the Dye-Sensitized Solar Cell

  摘要：

  Cycloruthenated complexes of the type [Ru-II(N boolean AND N)(2)(C boolean AND N)](+) (N boolean AND N = substituted 2,2 '-bipyridine; C boolean AND N = substituted 3-(2 '-pyridyl)-1,8-naphthalimide ligand) are shown to generate high power conversion efficiencies (PCEs) in the dye-sensitized solar cell (DSSC). It is shown that substitution of the pyridine ring of the C boolean AND N ligand with conjugated groups can enhance molar absorption extinction coefficients, while the electron density imparted on the metal center is alleviated by the 1,8-naphthalimide fragment. This latter feature maintains a Ru(III)/Ru(II) redox couple more positive than 0.8 V versus NHE, thereby accommodating regeneration of the oxidized dye by an iodide-based redox mediator. This dye platform can consequently be modulated at various sites to enhance light absorption and suppress recombination between the redox mediator and the TiO2 surface without compromising dye regeneration, thereby maintaining device PCEs as high as 7%. We also introduce a new phosphine-based coadsorbent, bis(2-ethylhexyl)phosphinic acid (BEPA), which is significantly easier to synthesize than the widely used bis(3,3-dimethylbutyl)phosphinic acid (DINHOP) while also facilitating high dye loading.

  DOI：

  10.1021/ic3024524
• 作为产物：
  描述：

  亚磷酸二丁酯 、 2-ethylhexylmagnesium bromide 以 乙醚 为溶剂， 反应 0.08h， 以44%的产率得到bis(2-ethylhexyl)phosphine oxide
  参考文献：
  名称：

  Ruthenium(II) Complexes Bearing a Naphthalimide Fragment: A Modular Dye Platform for the Dye-Sensitized Solar Cell

  摘要：

  Cycloruthenated complexes of the type [Ru-II(N boolean AND N)(2)(C boolean AND N)](+) (N boolean AND N = substituted 2,2 '-bipyridine; C boolean AND N = substituted 3-(2 '-pyridyl)-1,8-naphthalimide ligand) are shown to generate high power conversion efficiencies (PCEs) in the dye-sensitized solar cell (DSSC). It is shown that substitution of the pyridine ring of the C boolean AND N ligand with conjugated groups can enhance molar absorption extinction coefficients, while the electron density imparted on the metal center is alleviated by the 1,8-naphthalimide fragment. This latter feature maintains a Ru(III)/Ru(II) redox couple more positive than 0.8 V versus NHE, thereby accommodating regeneration of the oxidized dye by an iodide-based redox mediator. This dye platform can consequently be modulated at various sites to enhance light absorption and suppress recombination between the redox mediator and the TiO2 surface without compromising dye regeneration, thereby maintaining device PCEs as high as 7%. We also introduce a new phosphine-based coadsorbent, bis(2-ethylhexyl)phosphinic acid (BEPA), which is significantly easier to synthesize than the widely used bis(3,3-dimethylbutyl)phosphinic acid (DINHOP) while also facilitating high dye loading.

  DOI：

  10.1021/ic3024524

文献信息

• COMPOUNDS WITH PHOSPHINE OXIDE AND AMINE FUNCTIONS, USEFUL AS URANIUM (VI) LIGANDS, AND USES THEREOF, IN PARTICULAR FOR EXTRACTING URANIUM(VI) FROM AQUEOUS SOLUTIONS OF SULPHURIC ACID
  申请人：COMMISSARIAT À L'ÉNERGIE ATOMIQUE ET AUX ÉNERGIES ALTERNATIVES

  公开号：US20180094009A1

  公开（公告）日：2018-04-05

  The invention relates to compounds which correspond to the general formula (I) below: in which: R 1 and R 2 represent, independently of one another, a C 4 to C 12 acyclic hydrocarbon group; R 3 represents H; a C 1 to C 12 acyclic hydrocarbon group with optionally one or more heteroatoms; a C 5 or C 6 cyclic hydrocarbon group; or a 5- or 6-membered heterocyclic group; R 4 represents H or a C 1 to C 12 acyclic hydrocarbon group with optionally one or more heteroatoms; R 5 and R 6 represent, independently of one another, H; a C 1 to C 12 acyclic hydrocarbon group with optionally one or more heteroatoms; a C 5 or C 6 cyclic hydrocarbon group; or a 5- or 6-membered heterocyclic group; on the condition however that R 5 and R 6 do not each represent H.

  该发明涉及与下面的一般式（I）对应的化合物：其中：R1和R2分别独立地代表C4到C12的无环烃基；R3代表H；一个具有一个或多个杂原子的C1到C12的无环烃基；一个C5或C6的环烃基；或一个5-或6-成员杂环基；R4代表H或一个具有一个或多个杂原子的C1到C12的无环烃基；R5和R6分别独立地代表H；一个具有一个或多个杂原子的C1到C12的无环烃基；一个C5或C6的环烃基；或一个5-或6-成员杂环基；但条件是R5和R6不同时代表H。
• Process for extracting metal values
  申请人：ZENECA LIMITED

  公开号：EP0573182A1

  公开（公告）日：1993-12-08

  A process for extracting metal values especially zinc values from aqueous solutions of metal salts which comprises contacting the aqueous solution with an organic phase comprising a compound of the formula: wherein each of R¹, R², R³ and R⁴, independently, represents an optionally substituted hydrocarbyl or hydrocarbyloxy group or R¹ and R² together with the attached phosphorus atom and/or R³ and R⁴ together with the attached phosphorus atom form a 5- to 8-membered heterocyclic ring.

  一种从金属盐水溶液中提取金属值，特别是锌值的工艺，包括将水溶液与含有式化合物的有机相接触： 其中 R¹、R²、R³ 和 R⁴ 各自独立地代表任选取代的烃基或烃氧基，或 R¹ 和 R² 与所连接的磷原子和/或 R³ 和 R⁴ 与所连接的磷原子一起形成 5 至 8 元杂环。
• US5393431A
  申请人：——

  公开号：US5393431A

  公开（公告）日：1995-02-28
• US5502250A
  申请人：——

  公开号：US5502250A

  公开（公告）日：1996-03-26
• US5557003A
  申请人：——

  公开号：US5557003A

  公开（公告）日：1996-09-17