α-butyl-Ï -hydroxyl-ethylene oxide | 164916-64-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: α-butyl-Ï -hydroxyl-ethylene oxide
• 英文别名: α-butyl-Ï -hydroxy-ethylene oxide；alpha-butyl-omega-hydroxyl-ethylene oxide；alpha-butyl-omega-hydroxy-ethylene oxide；epoxyhexanol；3-butyloxiran-2-ol
• CAS: 164916-64-7
• 化学式: C₆H₁₂O₂
• 分子量: 116.16
• InChiKey: HOFDOCBAQZRCEL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  32.8
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-pentenol 在 bis(2-hydroxy-1-benzylidene)terephthalodihydrazone dimolybdenyl monohydrate 、 双氧水 作用下， 以 乙腈 为溶剂， 反应 3.5h， 以71%的产率得到α-butyl-Ï -hydroxyl-ethylene oxide
  参考文献：
  名称：

  铀和钼的均二氧双金属双di配合物在烯烃均相氧化中的催化潜力

  摘要：

  摘要在各种脂肪族和环状烯烃的均相氧化过程中，研究了二氧钼（VI）和二氧铀（VI）均双金属双-ONO三齿（2-羟基-1-亚苄基）丙二酰，琥珀酰和对苯二di配合物的催化势。使用H 2 O 2水溶液或TBHP（叔丁基过氧化氢）作为末端氧化剂。催化潜力是定量的，并且具有很高的选择性，可提供相应的氧化物产物与Mo VI O 2络合物，比使用H 2 O 2水溶液的U VI O 2络合物高5倍。或TBHP。在含水H 2 O 2的Mo VI O 2配合物催化的1,2-环辛烯的氧化中，研究了各种溶剂和温度的影响，结果发现，最合适的溶剂是乙腈，最适温度为70°C。初步描述和讨论了机理途径。 图形概要

  DOI：

  10.1007/s00706-015-1477-9

文献信息

• Novel imidazole alcohol compound, process for producing the same, and surface-treating agent comprising the same
  申请人：Imori Toru

  公开号：US20060135584A1

  公开（公告）日：2006-06-22

  It is an object of the present invention to provide a novel imidazole alcohol compound that adheres strongly to metal surfaces in metal products, especially copper, aluminum and steel products, and that has a superior rust-preventive effect even in a thin film, and a surface-treating agent using the same. The novel imidazole alcohol compound is expressed by the following general formula (1) show a rust-preventive effect. (In general formula (1), R 1 , R 2 and R 3 are each hydrogen, a vinyl group or an alkyl group with 1 to 20 carbon atoms, an aromatic ring may be formed by R 2 and R 3 , X indicates hydrogen, an alkyl group with 1 to 6 carbon atoms, or a substituent group which may contain N or O, m indicates an integer from 0 to 20, and n and 1 indicate integers from 1 to 3.) The above-mentioned imidazole alcohol compound can be produced by reacting an imidazole compound and an epoxy alcohol compound.

  本发明的目的是提供一种新型咪唑醇化合物，该化合物可以强烈附着于金属制品，特别是铜、铝和钢制品的金属表面，即使在薄膜中也具有优异的防锈效果，并且使用相同的表面处理剂。新型咪唑醇化合物由以下通式（1）表示，显示出防锈效果。（在通式（1）中，R1、R2和R3分别为氢、乙烯基或具有1至20个碳原子的烷基，R2和R3可以形成芳香环，X表示氢、具有1至6个碳原子的烷基或可能含有N或O的取代基，m表示从0到20的整数，n和1表示从1到3的整数。）上述咪唑醇化合物可以通过反应咪唑化合物和环氧醇化合物来制备。
• Low solvent content type-resin composition, coating composition containing such resin composition and process for coating such coating composition
  申请人：MAZDA MOTOR CORPORATION

  公开号：EP0688841A2

  公开（公告）日：1995-12-27

  The present invention is to provide a low solvent content type-coating composition by which the resultant coatings with good scuff resistance or water resistance as well as good chipping resistance are produced, while the content of an organic solvent to be used can be much reduced. The low solvent content type-coating composition comprises a polyester oligomer having a hydroxyl group in an amount of 2.0 to 10.0 moles/Kg-resin, a number average molecular weight (Mn) of 300 to 1500, a weight average molecular weight (Mw) of 300 to 3000, and a ratio of a weight average molecular weight/a number average molecular weight (Mw/Mn) of 1 to 2.0, an amount of a modifying lactone being 31 to 85%, and an aliphatic hydrocarbon group of C4-22 which is not derived from lactones. The present invention is also to provide a process for coating a low solvent content type-coating composition on, for example, a base coating composition by a wet-on-wet coating. The base coating composition comprises a vinyl oligomer having a hydroxyl group and/or a blocked hydroxyl group, a melamine resin containing 50 to 100% of an imino type or methylol type mononucleus melamine and a weak acidic curing catalyst.

  本发明旨在提供一种低溶剂含量型涂料组合物，通过该组合物可生产出具有良好耐磨擦性或耐水性以及良好抗崩角性的涂料，同时可大大减少所用有机溶剂的含量。低溶剂含量型涂料组合物包括具有羟基的聚酯低聚物，其羟基含量为 2.0 至 10.0 摩尔/Kg-树脂，数均分子量（Mn）为 300 至 1500，重量平均分子量（Mw）为 300 至 3000，重量平均分子量/数均分子量之比（Mw/Mn）为 1 至 2.0，改性内酯的含量为 31 至 85%，以及不来自内酯的 C4-22 脂肪族烃基。本发明还提供一种通过湿对湿涂覆法在例如基底涂料组合物上涂覆低溶剂含量型涂料组合物的工艺。基底涂料组合物包括具有羟基和/或封端羟基的乙烯基低聚物、含有 50%至 100%亚氨基型或甲醇型单核三聚氰胺的三聚氰胺树脂和弱酸性固化催化剂。
• Method of surface treatment using imidazole compound
  申请人：Imori Toru

  公开号：US20090068364A1

  公开（公告）日：2009-03-12

  It is an object of the present invention to provide a novel imidazole alcohol compound that adheres strongly to metal surfaces in metal products, especially copper, aluminum and steel products, and that has a superior rust-preventive effect even in a thin film, and a surface-treating agent using the same. The novel imidazole alcohol compound is expressed by the following general formula (1) show a rust-preventive effect. (In general formula (1), R 1 , R 2 and R 3 are each hydrogen, a vinyl group or an alkyl group with 1 to 20 carbon atoms, an aromatic ring may be formed by R 2 and R 3 , X indicates hydrogen, an alkyl group with 1 to 6 carbon atoms, or a substituent group which may contain N or O, m indicates an integer from 0 to 20, and n and l indicate integers from 1 to 3.) The above-mentioned imidazole alcohol compound can be produced by reacting an imidazole compound and an epoxy alcohol compound.
• US4822405A
  申请人：——

  公开号：US4822405A

  公开（公告）日：1989-04-18
• US5721015A
  申请人：——

  公开号：US5721015A

  公开（公告）日：1998-02-24