1-(2,4-Dinitrophenyl)pyrrole | 1190362-53-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 1-(2,4-Dinitrophenyl)pyrrole
• CAS: 1190362-53-8
• 化学式: C₁₀H₇N₃O₄
• 分子量: 233.183
• InChiKey: KBGALDGPBXWCFU-UHFFFAOYSA-N

物化性质

• 沸点：
  394.7±32.0 °C(Predicted)
• 密度：
  1.47±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  96.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,5-二甲氧基四氢呋喃 、 2,4-二硝基苯胺 在 bismuth (III) nitrate pentahydrate 作用下， 反应 0.67h， 以92%的产率得到1-(2,4-Dinitrophenyl)pyrrole
  参考文献：
  名称：

  Facile synthesis of N-substituted pyrroles via microwave-induced bismuth nitrate-catalyzed reaction

  摘要：

  Simple synthesis of N-substituted pyrroles using microwave-induced bismuth nitrate-catalyzed reaction has been accomplished with an excellent yield. A plausible mechanism has been advanced. This reaction also provides a simple method to prepare diverse varieties of N-substituted pyrrole derivatives with less nucleophilic polyaromatic amines. (C) 2009 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2009.06.002

文献信息

• Elektro-release systems, modified electrodes and their use
  申请人：Plant Bioscience Limited

  公开号：EP1438983A1

  公开（公告）日：2004-07-21

  An electro-release system, for example for use in releasing a pharmaceutical compound, has an electrode and a layer structure on said electrode releasably holding an electro-releasable compound. The layer structure comprises at least one functional compound providing a first functional group forming an ionic bond with the electro-releasable compound and a second functional group which, on application of an appropriate voltage bias to the electrode, generates protons which break the ionic bond, thereby controlling release of the electro-releasable compound. Also disclosed are modified electrodes useful in such an electro-release system and having polymer bilayers based on polypyrrole or polythiophene with the two layers carrying different substituents giving different functionality or reactivity.

  电释放系统，例如用于释放药物化合物的电释放系统，具有一个电极和在所述电极上可释放地容纳电释放化合物的层结构。该层结构包括至少一种官能团化合物，其中第一官能团与可电释放化合物形成离子键，第二官能团在对电极施加适当的电压偏压时产生质子，质子破坏离子键，从而控制可电释放化合物的释放。此外，还公开了可用于此类电释放系统的改性电极，这些电极具有基于聚吡咯或聚噻吩的聚合物双层，其中两层带有不同的取代基，具有不同的功能性或反应性。
• ELECTRO-RELEASE SYSTEMS
  申请人：Plant Bioscience Limited

  公开号：EP0959941B1

  公开（公告）日：2004-08-04
• US6132752A
  申请人：——

  公开号：US6132752A

  公开（公告）日：2000-10-17
• Facile synthesis of N-substituted pyrroles via microwave-induced bismuth nitrate-catalyzed reaction
  作者：Sonya Rivera、Debasish Bandyopadhyay、Bimal K. Banik

  DOI：10.1016/j.tetlet.2009.06.002

  日期：2009.9

  Simple synthesis of N-substituted pyrroles using microwave-induced bismuth nitrate-catalyzed reaction has been accomplished with an excellent yield. A plausible mechanism has been advanced. This reaction also provides a simple method to prepare diverse varieties of N-substituted pyrrole derivatives with less nucleophilic polyaromatic amines. (C) 2009 Published by Elsevier Ltd.