N~1~,N~2~-Bis[3,4-bis(dodecyloxy)phenyl]ethanebis(thioamide) | 189934-25-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: N~1~,N~2~-Bis[3,4-bis(dodecyloxy)phenyl]ethanebis(thioamide)
• 英文别名: N,N'-bis(3,4-didodecoxyphenyl)ethanedithioamide
• CAS: 189934-25-6
• 化学式: C₆₂H₁₀₈N₂O₄S₂
• 分子量: 1009.68
• InChiKey: KTYLNORAGAXRJD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.8
• 重原子数：
  70
• 可旋转键数：
  50
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  125
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N~1~,N~2~-Bis[3,4-bis(dodecyloxy)phenyl]ethanebis(thioamide) 、 dichlorobis(dimethyl sulfoxide)platinum(II) 以 氯仿 为溶剂， 以99%的产率得到Pt(S2C2N2H(C6H3-3,4-(O(CH2)11CH3)2)2)2
  参考文献：
  名称：

  长链仲二硫代草酰胺作为配体，用于合成铂（II）金属成矿物质

  摘要：

  摘要为寻找具有成矿作用的仲二硫代草酰胺（RNHCS）2（RNHCS）2（称为R 2 H 2 DTO）铂配合物，从顺式[[Pt（Me 2 SO）]合成了数种[Pt（R 2 HDTO）2]。 ）2 Cl 2]。本文主要研究长链二硫代草酰胺的配位化学，在某些情况下，该配位化学相对于在氮原子上带有小取代基的R 2 H 2 DTO表现出不同的行为。相对于二烷基-二硫代草酰胺，观察到的反应性似乎仅部分与二芳基中酰胺氮原子的碱性较低有关，并且配合物的不同填充构象似乎起重要作用。R = 3,4- [CH 3（CH 2）9 O] 2 C 6 H 3和3的[Pt（R 2 HDTO）2]的中间相形成，通过偏振光学显微镜和差示扫描量热法提出了4- [CH 3（CH 2）11 O] 2 C 6 H 3的建议。还描述了类似的双螯合物的合成，但是具有两个不同的二硫代草酰胺配体。

  DOI：

  10.1016/s0020-1693(96)05450-3
• 作为产物：
  描述：

  4-硝基儿茶酚 在 tetraphosphorus decasulfide 、 tin(ll) chloride 作用下， 生成 N~1~,N~2~-Bis[3,4-bis(dodecyloxy)phenyl]ethanebis(thioamide)
  参考文献：
  名称：

  Mesomorphic Dithiooxamide Complexes of Platinum(II)

  摘要：

  Complexation of non-mesomorphic dithiooxamide ligands to Pt(II) leads to square planar complexes which exhibit mesomorphic properties. The synthesis of these complexes was accomplished in three steps: the formation of bisamides, starting from conveniently substituted anilines, their conversion into dithiooxamides and the reaction of these sulfur derivatives with [PtCl2(dmso)(2)]. Four, eight and twelve-chained complexes were obtained and their behaviour as potentially mesomorphic material was studied. The eight-chained complexes 21 (n = 12-16) and the twelve-chained complexes 22 (n = 8,11,13) exhibit columnar mesophases which have been characterised by optical microscopy, X-ray scattering and related miscibility studies.

  DOI：

  10.1080/10587250008024795

文献信息

• Mesomorphic Dithiooxamide Complexes of Platinum(II)
  作者：Maria Chiara Aversa、Paola Bonaccorsi、Duncan W. Bruce、Francesco Caruso、Bertrand Donnio、Placido Giannetto、Daniel Guillon、Santo Lanza、Stefania Morrone

  DOI：10.1080/10587250008024795

  日期：2000.8.1

  Complexation of non-mesomorphic dithiooxamide ligands to Pt(II) leads to square planar complexes which exhibit mesomorphic properties. The synthesis of these complexes was accomplished in three steps: the formation of bisamides, starting from conveniently substituted anilines, their conversion into dithiooxamides and the reaction of these sulfur derivatives with [PtCl2(dmso)(2)]. Four, eight and twelve-chained complexes were obtained and their behaviour as potentially mesomorphic material was studied. The eight-chained complexes 21 (n = 12-16) and the twelve-chained complexes 22 (n = 8,11,13) exhibit columnar mesophases which have been characterised by optical microscopy, X-ray scattering and related miscibility studies.
• Long chain secondary dithiooxamides as ligands for the synthesis of platinum(II) metallomesogens
  作者：Maria Chiara Aversa、Paola Bonaccorsi、Duncan W. Bruce、Francesco Caruso、Placido Giannetto、Santo Lanza、Stefania Morrone

  DOI：10.1016/s0020-1693(96)05450-3

  日期：1997.3

  long chain dithiooxamides which in some cases show a different behaviour with respect to R 2 H 2 DTO bearing small substituents on nitrogen atoms. The observed reactivity appears related only in part to the lower basicity of amide nitrogen atoms in diaryl- with respect to dialkyl-dithiooxamides, and differently populated conformations of the complexes seem to play an important role. Mesophase formation

  摘要为寻找具有成矿作用的仲二硫代草酰胺（RNHCS）2（RNHCS）2（称为R 2 H 2 DTO）铂配合物，从顺式[[Pt（Me 2 SO）]合成了数种[Pt（R 2 HDTO）2]。 ）2 Cl 2]。本文主要研究长链二硫代草酰胺的配位化学，在某些情况下，该配位化学相对于在氮原子上带有小取代基的R 2 H 2 DTO表现出不同的行为。相对于二烷基-二硫代草酰胺，观察到的反应性似乎仅部分与二芳基中酰胺氮原子的碱性较低有关，并且配合物的不同填充构象似乎起重要作用。R = 3,4- [CH 3（CH 2）9 O] 2 C 6 H 3和3的[Pt（R 2 HDTO）2]的中间相形成，通过偏振光学显微镜和差示扫描量热法提出了4- [CH 3（CH 2）11 O] 2 C 6 H 3的建议。还描述了类似的双螯合物的合成，但是具有两个不同的二硫代草酰胺配体。