2-trifluoromethyl acrylic acid cyclohexyl ester | 769175-07-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-trifluoromethyl acrylic acid cyclohexyl ester
• 英文别名: 2-Propenoic acid, 2-(trifluoromethyl)-, cyclohexyl ester；cyclohexyl 2-(trifluoromethyl)prop-2-enoate
• CAS: 769175-07-7
• 化学式: C₁₀H₁₃F₃O₂
• 分子量: 222.207
• InChiKey: OYKNZRLOFMNYPG-UHFFFAOYSA-N

物化性质

• 沸点：
  236.0±40.0 °C(Predicted)
• 密度：
  1.16±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  1,2-二溴-3,3,3-三氟丙烷 、 一氧化碳 、 环己醇 在 bis-triphenylphosphine-palladium(II) chloride 三乙胺 作用下， 以 甲苯 为溶剂， 120.0 ℃ 、1.0 MPa 条件下， 反应 5.0h， 以73.4%的产率得到2-trifluoromethyl acrylic acid cyclohexyl ester
  参考文献：
  名称：

  EP1637514

  摘要：

  公开号：

文献信息

• Polymerizable monomer polymeric compound resin compositions for photoresist and method for producing semiconductor
  申请人：Koyama Hiroshi

  公开号：US20060058480A1

  公开（公告）日：2006-03-16

  A polymerizable monomer of the present invention is represented by the following formula (1); R 1 , R 2 and R 3 are each a hydrogen atom, a fluorine atom, an alkyl group or a fluoroalkyl group, W is a single bond or a linkage group and n is 0 or 1, where at least one of R 1 , R 2 and R 3 is a fluorine atom or a fluoroalkyl group when n= 1; and the ring in the formula may have a substituent. The polymerizable monomer of the present invention can provide an appropriate hydrophilicity or hydrophilicity and transparency to a photoresist polymer.

  本发明的可聚合单体由以下公式（1）表示；其中，R1、R2和R3分别为氢原子、氟原子、烷基或氟烷基，W为单键或连接基，n为0或1，当n=1时，R1、R2和R3中至少有一个为氟原子或氟烷基；公式中的环可能具有取代基。本发明的可聚合单体能够为光刻胶聚合物提供适当的亲水性或亲疏水性和透明度。
• METHOD FOR PRODUCING FLUORINE-CONTAINING ACRYLATE
  申请人：Tosoh F-Tech, Inc.

  公开号：EP1637514A1

  公开（公告）日：2006-03-22

  A process for producing a fluorine-containing acrylic acid ester represented by CH2=C(Rf) (COOR) characterized in that 1-bromo-1-perfluoroalkylethene represented by CH2=CBr-Rf, or 1,2-dibromo-1-perfluoroalkylethane represented by CH2CBr-CHBr-Rf is allowed to react with an alcohol represented by ROH in the presence of a palladium catalyst, carbon monoxide, and two or more kinds of bases. The fluorine-containing acrylic acid ester is a useful compound having wide applications in materials for pharmaceuticals and functional polymers.

  一种以 CH2=C(Rf) (COOR) 为代表的含氟丙烯酸酯的生产工艺，其特征在于以 CH2=CBr-Rf 为代表的 1-溴-1-全氟烷基乙烯或以 CH2CBr-CHBr-Rf 为代表的 1,2-二溴-1-全氟烷基乙烷在钯催化剂、一氧化碳和两种或两种以上碱的存在下与以 ROH 为代表的醇反应。这种含氟丙烯酸酯是一种有用的化合物，在药物材料和功能聚合物中有着广泛的应用。
• Solid electrolyte composition, solid electrolyte-containing sheet, all-solid state secondary battery, and methods for manufacturing solid electrolyte composition, solid electrolyte-containing sheet, all-solid state secondary battery
  申请人：FUJIFILM Corporation

  公开号：US10833351B2

  公开（公告）日：2020-11-10

  Provided are a solid electrolyte composition containing an inorganic solid electrolyte having a conductivity for ions of metals belonging to Group I or II of the periodic table and a compound having an anionic polymerizable functional group, a solid electrolyte-containing sheet containing an inorganic solid electrolyte having a conductivity for ions of metals belonging to Group I or II of the periodic table and an anionic polymer which bonds to the inorganic solid electrolyte, and an all-solid state secondary battery, and methods for manufacturing the solid electrolyte composition, the solid electrolyte-containing sheet, and the all-solid state secondary battery.

  本发明提供了一种固体电解质组合物，该组合物含有对属于元素周期表第 I 组或第 II 组的金属离子具有导电性的无机固体电解质和具有阴离子可聚合官能团的化合物、一种含固体电解质的薄片，其中含有对属于元素周期表第I或第II族的金属离子具有导电性的无机固体电解质和一种与无机固体电解质结合的阴离子聚合物，以及一种全固态二次电池，以及制造该固体电解质组合物、含固体电解质的薄片和全固态二次电池的方法。
• 6-Trifluoromethyl-2 vinyloxy-4-oxatricyclo[4.2.1.03,7]noname-5-one, and polymer compound
  申请人：Koyama Hiroshi

  公开号：US20050245706A1

  公开（公告）日：2005-11-03

  6-trifluoromethyl-2-vinyloxy-4-oxatricyclo[4.2.1.0 3,7 ]nonan-5-one of the present invention is represented by the following formula (1). This compound can be produced by reacting 6-trifluoromethyl-2-hydroxy-4-oxatricyclo[4.2.1.0 3,7 ]nonan-5-one represented by the following formula (2) with a compound represented by the following formula (3a) or (3b), wherein R a and R b are each a hydrogen atom or a hydrocarbon group.

  6-三氟甲基-2-乙烯基氧基-4-氧杂三环[4.2.1.0 3,7 本发明的 6-三氟甲基-2-乙烯氧基-4-氧杂三环[4.2.1.0 3,7 ]壬烷-5-酮由下式 (1) 表示。 该化合物可通过将 6-三氟甲基-2-乙烯基氧基-4-氧杂三环[4.2.1.0 3,7 ]壬-5-酮与下式（2）所代表的化合物反应制得 与下式 (3a) 或 (3b) 所代表的化合物反应、 其中 R a 和 R b 均为氢原子或烃基。
• FLUORINE-ATOM-CONTAINING POLYMERIZABLE UNSATURATED-MONOMER, FLUORINE-ATOM-CONTAINING POLYMERIC COMPOUND AND PHOTORESIST RESIN COMPOSITION
  申请人：Koyama Hiroshi

  公开号：US20050282985A1

  公开（公告）日：2005-12-22

  A fluorine-atom-containing polymerizable unsaturated-monomer of the present invention is represented by the following formula (1a) or (1b): wherein each of a ring Z 1 and a ring Z 2 is an alicyclic carbon ring; when the alicyclic carbon ring is multi-cyclic, a part of atoms constituting the ring may be substituted by an oxygen atom, a sulfur atom or a nitrogen atom; an atom constituting the ring Z 1 and the ring Z 2 may have a substituent; each of R 1 , R 2 and R 3 is an alkyl group or a fluoroalkyl group; R is an specific unsaturated acyl group; provided that at least one of R 1 and R 2 is a fluorine atom or a fluoroalkyl group in the formula (1a), and in the formula (1b) (i) the ring Z 2 is bonded by a fluorine atom or a fluoroalkyl group, or (ii) R 3 is a fluoroalkyl group.

  本发明的含氟原子可聚合不饱和单体由下式(1a)或(1b)表示： 其中每个环 Z 1 和环 Z 2 为脂环碳环；当脂环碳环为多环时，构成环的部分原子可被氧原子、硫原子或氮原子取代；构成环 Z 1 和环 Z 2 中的每个 R 1 , R 2 和 R 3 是烷基或氟烷基； R 是特定的不饱和酰基；条件是 R 1 和 R 2 在式(1a)中至少有一个是氟原子或氟烷基，在式(1b)中 (i) 环 Z 2 由氟原子或氟烷基键合，或 (ii) R 3 是氟烷基。