5-[(氯乙酰氧基)甲基]-2-降冰片烯 | 28693-00-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 5-[(氯乙酰氧基)甲基]-2-降冰片烯
• 英文名称: (bicyclo[2.2.1]hept-5-enyl)methyl monochloroacetate
• 英文别名: chloro-acetic acid norborn-5-en-2-ylmethyl ester；Chlor-essigsaeure-norborn-5-en-2-ylmethylester；bicyclo[2.2.1]hept-5-en-2-ylmethyl chloroacetate；2-Chloracetoxymethyl-bicyclo<2.2.1>-hepten-(5)；Acetic acid, chloro-, bicyclo(2.2.1)hept-5-en-2-ylmethyl ester；2-bicyclo[2.2.1]hept-5-enylmethyl 2-chloroacetate
• CAS: 28693-00-7
• 化学式: C₁₀H₁₃ClO₂
• 分子量: 200.665
• InChiKey: YEQPPBCBKNMCKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2915400090

反应信息

• 作为产物：
  描述：

  氯乙酸丙烯酯 、 环戊二烯 生成 5-[(氯乙酰氧基)甲基]-2-降冰片烯
  参考文献：
  名称：

  Kukalenko; Melnikow, Zhurnal Obshchei Khimii, 1958, vol. 28, p. 154,156

  摘要：

  DOI：

文献信息

• Modified monoolefin copolymer elastomer with improved heat and oil resistance
  申请人：UNIROYAL, INC.

  公开号：EP0015627A1

  公开（公告）日：1980-09-17

  An EPM or EPDM type of elastomer is modified by graft copolymerization with acrylic ester type of monomeric material whose homopolymer has a glass transition temperature of not greater than 6° C, in an amount sufficient to provide an ester group (-COO-) content of from 25 to 40% by weight, to yield a mixed copolymerizate vulcanizable to a heat and oil resistant elastomeric state.

  通过与丙烯酸酯类单体材料接枝共聚改性 EPM 或 EPDM 弹性体，其均聚物的玻璃化转变温度不高于 6 摄氏度，其用量足以使酯基（-COO-）含量达到 25% 至 40% （按重量计），从而得到可硫化成耐热耐油弹性体状态的混合共聚物。
• A mult-component copolymer rubber, a process for producing the same, and a rubber composition containing the multi-component copolymer rubber
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0160399A2

  公开（公告）日：1985-11-06

  A multi-component copolymer rubber consisting essentially of (A) 20 to 69.5% by weight of a cyanosubstituted alkyl (meth)acrylate, (B) 30 to 79.5% by weight of an alkyl acrylate, (C) 0.5 to 10% by weight of a crosslinkable monomer and (D) 0 to 10% by weight of other ethylenically unsaturated monomer copolymerizable with (A), (B) and (C), excels in heat resistance, ozone resistance, sour gasoline resistance and sour gasohol resistance. These properties of said multi-component copolymer rubber can further be improved by incorporating into the copolymer rubber a crosslinking agent, a metal salt, a vinylidene fluoride polymer, a vinyl chloride resin or other multi-component copolymer rubber.

  一种多组分共聚橡胶主要由以下物质组成：(A) 20 至 69.5%（按重量计）氰基取代的烷基（甲基）丙烯酸酯；(B) 30 至 79.5%（按重量计）丙烯酸烷基酯；(C) 0.5 至 10%（按重量计）可交联单体；(D) 0 至 10%（按重量计）可与(A)、(B)和(C)共聚的其他乙烯基不饱和单体，该橡胶具有优异的耐热性、耐臭氧性、耐酸汽油性和耐酸汽油醇性。通过在共聚橡胶中加入交联剂、金属盐、偏氟乙烯聚合物、氯乙烯树脂或其他多组分共聚橡胶，可进一步改善所述多组分共聚橡胶的上述性能。
• Vulcanizable rubber compositions and applications thereof
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0194030A2

  公开（公告）日：1986-09-10

  A vulcanizable rubber composition comprises (1) 100 parts by weight of a polymer composition comprising (I) a vinylidene fluoride resin, (II) at least one acrylic rubber, a,p-unsaturated nitrile-conjugated diene copolymer rubber or hydride of an a,p-unsaturated nitrile-conjugated diene copolymer rubber, (III) another blendable polymer, wherein the weight ratio of (I)/[(II) + (III)] is from 5/95 to 60/ 40 and the weight ratio of (II)/(III) is from 100/0 to 50/50, and (2) from 0 to 40 by weight of a plasticizer. Said rubber composition excels not only in heat resistance, gasoline resistance and sour gasoline resistance but also in gasohol resistance and sour gasohol resistance and further has good tensile strength, elongation and balance between gasoline resistance and low-temperature resistance. Therefore, it can be used in the fluid-contacting surface of a diaphragm or as an inner tube of a fuel hose.

  一种可硫化橡胶组合物包括 (1) 100 重量份的聚合物组合物，其中包括 (I) 亚乙烯基氟化树脂、 (II) 至少一种丙烯酸橡胶、a,p-不饱和腈-共轭二烯共聚物橡胶或 a,p-不饱和腈-共轭二烯共聚物橡胶的氢化物、 (III) 另一种可混合聚合物、 其中(I)/[(II)+(III)]的重量比为 5/95 至 60/40，(II)/(III)的重量比为 100/0 至 50/50，以及 (2) 增塑剂的重量比为 0 至 40。上述橡胶组合物不仅在耐热性、耐汽油性和耐酸汽油性方面表现出色，而且在耐煤气醇性和耐酸煤气醇性方面也表现出色，并具有良好的拉伸强度、伸长率以及耐汽油性和耐低温性之间的平衡。因此，它可用于隔膜的流体接触面或作为燃油软管的内管。
• Vinylidene fluoride-acrylic acid ester copolymer, process for producing the same and composition containing the same
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0276957A2

  公开（公告）日：1988-08-03

  A substantially random, linear vinylidene fluoride-acrylic acid ester copolymer comprising: (A) 5-85% by weight of a vinylidene fluoride unit, (B) 15-950/0 by weight of at least one unit selected from the group consisting of an alkyl acrylate unit and an alkoxy-substituted alkyl acrylate unit, and (C) optionally 10% by weight or less, based on the total weight of (A), (B) and (C), of a crosslinking monomer unit, and having an intrinsic viscosity of 0.01-10 dl/g as measured at 30° C in N,N-dimethylformamide. Said copolymer has not only excellent heat resistance, ozone resistance and sour gasoline resistance but also excellent resistance to gasoline permeation.

  一种基本无规的线型偏氟乙烯-丙烯酸酯共聚物，包括：(A) 5-85%（按重量计）的偏氟乙烯单元，(B) 15-950/0（按重量计）的至少一种单元，这些单元选自由丙烯酸烷基酯单元和烷氧基取代的丙烯酸烷基酯单元组成的组，以及(C) 可选 10%（按重量计）或更少（以(A)、(B)和(C)的总重量为基准）的交联单体单元，在 30°C 的 N,N-二甲基甲酰胺中测得的固有粘度为 0.01-10 dl/g。 上述共聚物不仅具有优异的耐热性、耐臭氧性和耐酸汽油性，而且还具有优异的耐汽油渗透性。
• No-post-cure method of curing polyacrylate polymers
  申请人：Zeon Chemicals USA, Inc.

  公开号：EP0309794A2

  公开（公告）日：1989-04-05

  A no-post-cure method of curing polyacrylates having dual cure sites is accomplished with a two-part curing system or a combined one-part curing system. The two-part curing system consists of one or more metallic acid salts and an ammonium and/or phosphonium quaternary salt. The one-part curing system consists of an ammonium or phosphonium quaternary acid salt. The polyacrylate rubber must have both a halogen and a carboxyl cure site. The method consists of blending the curative with the polyacrylate rubber and heating the resultant com­position until the composition cures. Because the mixed composition is shelf stable, it is not necessary to immediately heat the composition to cure it. The method may optionally include the step of storing the mixed composition until it is desired to cure it.

  使用双组分固化体系或组合式单组分固化体系，可实现具有双重固化位点的聚丙烯酸酯的免后固化方法。双组分固化体系由一种或多种金属酸盐和一种铵和/或鏻季盐组成。单组分固化体系由铵或鏻季酸盐组成。聚丙烯酸酯橡胶必须同时具有卤素和羧基固化位点。该方法包括将固化剂与聚丙烯酸酯橡胶混合，然后加热所得组合物，直至组合物固化。由于混合后的组合物具有货架稳定性，因此无需立即加热组合物使其固化。该方法可选择包括储存混合组合物的步骤，直到需要固化为止。