hexadecyl hydrogen fumarate | 1637-11-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: hexadecyl hydrogen fumarate
• 英文别名: Einecs 220-942-8；(E)-4-hexadecoxy-4-oxobut-2-enoic acid
• CAS: 1637-11-2
• 化学式: C₂₀H₃₆O₄
• 分子量: 340.503
• InChiKey: YXIQOXQGELPIFQ-WUKNDPDISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  24
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  十六烷基马来酸氢酯 、 反丁烯二酰氯 以83%的产率得到
  参考文献：
  名称：

  DYMICKY, M.;BUCHANAN, R. L., ORG. PREP. AND PROCED. INT., 1985, 17, N 2, 121-131

  摘要：

  DOI：

文献信息

• Simultaneously chlorinating and grafting a cure site onto polyethylene in an aqueous suspension
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0147718A2

  公开（公告）日：1985-07-10

  A chlorinated polyethylene elastomer is made by mixing polyethylene with water to form an aqeous suspension of the polyethylene and simultaneously chlorinating and grafting a cure site on the polyethylene by mixing and heating the aqueous suspension containing a free radical initiator, gaseous chlorine and about 0.1-1.5 moles per kg of polyethylene of an alkyl or alkylaryl monester of butenedioic acid having the formulas or mixtures thereof, where R1 is an alkyl or alkylaryl group having from about 8-20 carbon atoms and R2 and R3 are hydrogen, chlorine or an alkyl group having from about 1-4 carbon atoms.

  氯化聚乙烯弹性体的制造方法是：将聚乙烯与水混合，形成聚乙烯的水悬浮液，同时将含有自由基引发剂、气态氯和每千克聚乙烯约 0.1-1.5 摩尔的丁二酸烷基或烷基芳基单酯的水悬浮液混合并加热，在聚乙烯上氯化和接枝固化位点，丁二酸烷基或烷基芳基单酯的分子式为 或其混合物，其中 R1 是具有约 8-20 个碳原子的烷基或烷基芳基，R2 和 R3 是氢、氯或具有约 1-4 个碳原子的烷基。
• Use of low temperature flow improvers in distillate oils
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0283293A1

  公开（公告）日：1988-09-21

  As a flow improver in a crude oil or a liquid hydrocarbon fuel are used polymers containing more than one amide group, the amide being an amide of a secondary amine, and either the amide group or an ester group of the polymer containing a hydrogen- and carbon-containing group of at least 10 carbon atoms, provided that if the polymer is derived from the polymerisation of an aliphatic olefin and maleic anhydride, the polymer must have both an amide group and an ester group each of which contains a hydrogen- and carbon-containing group of at least 10 carbon atoms, for example, a diamide of a copolymer of an alkyl fumarate, vinyl acetate and maleic anhydride.

  作为原油或液态烃燃料的流动性改进剂，可使用含有一个以上酰胺基团的聚合物，酰胺是仲胺的酰胺，聚合物的酰胺基团或酯基团含有至少 10 个碳原子的含氢和含碳基团、例如，富马酸烷基酯、醋酸乙烯酯和马来酸酐共聚物的二酰胺。
• Flow improvers and cloud point depressants
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0306290A1

  公开（公告）日：1989-03-08

  Additives suitable for improving the flow and/or depressing the cloud point of crude oils, lubricating oils and especially fuel oils are polymers containing defined alkyl groups of at least 8 carbon atoms chain length. Such polymers are either (a) of a mixture of monomers having only two alkyl groups one being at least 3 carbon atoms longer than the other or (b) of a mixture of monomers having only three alkyl groups each differing by at least 3 carbon atoms and the middle alkyl group being half the combined length of the other two. Alternatively, the polymer may be derived from a monomer having the two defined alkyl groups (a) or the three defined alkyl groups (b).

  适用于改善原油、润滑油，特别是燃料油的流动性和/或降低浊点的添加剂是含有至少 8 个碳原子链长的确定烷基的聚合物。这种聚合物可以是 (a) 单体的混合物，其中只有两个烷基，其中一个比另一个至少长 3 个碳原子；或者 (b) 单体的混合物，其中只有三个烷基，每个烷基至少相差 3 个碳原子，中间的烷基是另外两个烷基总长度的一半。或者，聚合物可以由具有两个定义的烷基（a）或三个定义的烷基（b）的单体衍生而来。
• Fuel oil compositions
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0343981A1

  公开（公告）日：1989-11-29

  A fuel composition comprising a major proportion by weight of a liquid hydrocarbon fuel and a minor proportion by weight of a polymer containing more than one amino group, this amino group being a salt of a primary, secondary or tertiary amine or a quaternary ammonium salt, for example an amine salt of a copolymer of an alkyl fumarate, vinyl acetate and maleic anhydride.

  一种燃料组合物，包括按重量计占主要比例的液态碳氢化合物燃料和按重量计占次要比例的含有一个以上氨基的聚合物，这种氨基是伯胺、仲胺或叔胺的盐或季铵盐，例如富马酸烷基酯、醋酸乙烯酯和马来酸酐共聚物的胺盐。
• LIQUID CRYSTAL LIGHT CONTROL ELEMENT AND PROCESS FOR PRODUCING THE LIQUID CRYSTAL LIGHT CONTROL ELEMENT
  申请人：Nippon Sheet Glass Company Limited

  公开号：EP2224279A1

  公开（公告）日：2010-09-01

  In the production method of the present invention, an emulsion including a copolymer with a glass transition temperature (Tg) of -50 to 20°C is obtained by the emulsion polymerization of a monomer group including a monomer A that is a (meth)acrylic acid alkyl ester (where the alkyl group is an open chain group with 1 to 20 carbon atoms or a cyclic group with 5 to 20 carbon atoms) as the main monomer and a monomer B having a carbon-carbon double bond and a nonionic hydrophilic group such as a polyoxyalkylene group, an amide group, and a hydroxyl group. Liquid crystals are dispersed in this emulsion, which is applied onto a conductive film-coated substrate. Another conductive film-coated substrate is laminated thereto, and thus a liquid crystal light control device is obtained. A monomer C having a carboxyl group and/or an amino group and a carbon-carbon double bond may be used in combination with a crosslinking agent so that a crosslinked structure is introduced into the copolymer. The present invention provides a liquid crystal light control device in which the transparency with a voltage applied and the shielding property with no voltage applied are compatible at high level.

  在本发明的生产方法中一种包括玻璃化转变温度（Tg）为 -50 至 20°C 的共聚物的乳液，是由包括作为主单体的（甲基）丙烯酸烷基酯（其中烷基是具有 1 至 20 个碳原子的开链基团或具有 5 至 20 个碳原子的环状基团）的单体 A 和具有碳碳双键和非离子亲水基团（如聚氧烷基、酰胺基和羟基）的单体 B 的乳液聚合而成。液晶分散在这种乳液中，然后涂在涂有导电薄膜的基底上。将另一种涂有导电薄膜的基底层压在上面，就得到了液晶光控制装置。具有羧基和/或氨基以及碳碳双键的单体 C 可与交联剂结合使用，从而在共聚物中引入交联结构。本发明提供了一种液晶光控制装置，在该装置中，加电压时的透明性和不加电压时的屏蔽性在高水平上兼容。