1-methyltridecyl formate | 113366-26-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1-methyltridecyl formate
• 英文别名: Tetradecan-2-yl formate
• CAS: 113366-26-0
• 化学式: C₁₅H₃₀O₂
• 分子量: 242.402
• InChiKey: FRJDJRAUUGOHEN-UHFFFAOYSA-N

物化性质

• 沸点：
  309.6±11.0 °C(Predicted)
• 密度：
  0.865±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  17
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  phenyl tetradecan-2-yl telluride 、 N,N-二甲基甲酰胺 在 间氯过氧苯甲酸 作用下， 反应 2.0h， 以65%的产率得到1-methyltridecyl formate
  参考文献：
  名称：

  Hirai, Yasuyuki; Ohe, Kouichi; Toshimitsu, Akio, Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 67, # 1-4, p. 173 - 176

  摘要：

  DOI：

文献信息

• Novel polymer and method for determining cholesterol using the same
  申请人：Wako Pure Chemical Industries, Ltd.

  公开号：EP2239281A2

  公开（公告）日：2010-10-13

  It is an object of the present invention to provide the method for determining cholesterol in lipoprotein and reagent for determining cholesterol comprising the polymer, and the present invention relates to the reagent for determining cholesterol in lipoproteins such as high-density lipoprotein (HDL), low-density lipoprotein(LDL) and very low-density lipoprotein(VLDL) and the determination method using the polymer comprising the following units as constituents: (iv) a polyethylene glycol segment represented by the general formula [1]:         -(CH2CH2O)k-     [1] (wherein, k represents an integer of 10 to 250); (v) a monomer unit represented by the general formula [2]: (wherein R1 represents a hydrogen atom or C1-C3 alkyl group); and (vi) a monomer unit represented by the general formula [3]: [wherein, R2 represents a hydrogen atom or C1-C3 alkyl group, and R3 represents a group represented by the general formula [4]:         -COOR4     [4] (wherein, R4 represents an alkyl group, a haloalkyl group or a bornyl group), an alkyl group, an alkoxy group, an aralkyl group or an alkylcarbamoyl group; particularly, in the direct measurement of cholesterols such as HDL, LDL and VLDL contained in the sample, the reagent for determining cholesterol in the presence of said polymer, and the method for determining the concentration of cholesterol in a specific lipoprotein using said reagent for determining cholesterol, and a novel polymer.

  本发明的目的是提供测定脂蛋白中胆固醇的方法和由聚合物组成的测定胆固醇的试剂，本发明涉及测定高密度脂蛋白(HDL)、低密度脂蛋白(LDL)和极低密度脂蛋白(VLDL)等脂蛋白中胆固醇的试剂和使用由下列单元组成的聚合物作为成分的测定方法： (iv) 由通式[1]表示的聚乙二醇段： -(CH2CH2O)k-[1]。 (其中，k 代表 10 至 250 的整数）； (v) 由通式[2]表示的单体单元： (其中 R1 代表氢原子或 C1-C3 烷基）；以及 (vi) 由通式[3]代表的单体单元： [其中，R2 代表氢原子或 C1-C3 烷基，R3 代表通式[4]所代表的基团： -COOR4[4]代表的基团 (其中，R4 代表烷基、卤代烷基或伯烷基）、烷基、烷氧基、芳烷基或烷基氨基甲酰基；特别是，在直接测定样品中所含胆固醇如高密度脂蛋白、低密度脂蛋白和超低密度脂蛋白时，在所述聚合物存在下测定胆固醇的试剂，以及使用所述测定胆固醇的试剂测定特定脂蛋白中胆固醇浓度的方法，以及一种新型聚合物。
• NOVEL POLYMER AND METHOD OF MEASURING CHOLESTEROL THEREWITH
  申请人：Wako Pure Chemical Industries, Ltd.

  公开号：EP1903069B1

  公开（公告）日：2015-08-12
• Novel Polymer and Method of Measuring Cholesterol Therewith
  申请人：Itai Tomokazu

  公开号：US20090215097A1

  公开（公告）日：2009-08-27

  It is an object of the present invention to provide the method for determining cholesterol in lipoprotein and reagent for determining cholesterol comprising the polymer, and the present invention relates to the reagent for determining cholesterol in lipoproteins such as high-density lipoprotein (HDL), low-density lipoprotein (LDL) and very low-density lipoprotein (VLDL) and the determination method using the polymer comprising the following units as constituents: (iv) a polyethylene glycol segment represented by the general formula [1]: —(CH 2 CH 2 O) k— [1] (wherein, k represents an integer of 10 to 250); (v) a monomer unit represented by the general formula [2]: (wherein R 1 represents a hydrogen atom or C 1 -C 3 alkyl group); and (vi) a monomer unit represented by the general formula [3]: [wherein, R 2 represents a hydrogen atom or C 1 -C 3 alkyl group, and R 3 represents a group represented by the general formula [4]: —COOR 4 [4] (wherein, R 4 represents an alkyl group, a haloalkyl group or a bornyl group), an alkyl group, an alkoxy group, an aralkyl group or an alkylcarbamoyl group; particularly, in the direct measurement of cholesterols such as HDL, LDL and VLDL contained in the sample, the reagent for determining cholesterol in the presence of said polymer, and the method for determining the concentration of cholesterol in a specific lipoprotein using said reagent for determining cholesterol, and a novel polymer.
• US8158375B2
  申请人：——

  公开号：US8158375B2

  公开（公告）日：2012-04-17
• Hirai, Yasuyuki; Ohe, Kouichi; Toshimitsu, Akio, Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 67, # 1-4, p. 173 - 176
  作者：Hirai, Yasuyuki、Ohe, Kouichi、Toshimitsu, Akio、Uemura, Sakae

  DOI：——

  日期：——