2,3-dimethylsuccinaldehyde | 130227-07-5

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: 2,3-dimethylsuccinaldehyde
• 英文别名: 2,3-Dimethylbutanedial
• CAS: 130227-07-5
• 化学式: C₆H₁₀O₂
• 分子量: 114.144
• InChiKey: BNCSCBPQSPQFAW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,3-dimethylsuccinaldehyde 在 双氧水 作用下， 生成 2,3-二甲基丁二酸
  参考文献：
  名称：

  Reversible coupling of a substituted allylic radical with molecular oxygen in a toco reaction of 5-methylhepta-1,3,6-triene

  摘要：

  DOI：

  10.1016/s0040-4039(00)81337-4
• 作为产物：
  描述：

  (5E)-3-methyl-7-(4-methylphenyl)sulfanylhepta-1,5-dien-4-ol 在 臭氧 作用下， 生成 2,3-dimethylsuccinaldehyde
  参考文献：
  名称：

  Reversible coupling of a substituted allylic radical with molecular oxygen in a toco reaction of 5-methylhepta-1,3,6-triene

  摘要：

  DOI：

  10.1016/s0040-4039(00)81337-4

文献信息

• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• Process for producing epsilon caprolactones and/or hydrates and/or esters thereof
  申请人：UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

  公开号：EP0872482A2

  公开（公告）日：1998-10-21

  This invention relates in part to processes for producing one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof which comprise subjecting one or more substituted or unsubstituted penten-1-ols to carbonylation in the presence of a carbonylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce said one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof. The substituted and unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactam. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof as principal product(s) of reaction.

  本发明部分涉及生产一种或多种取代或未取代的epsilon己内酯和/或其水合物和/或酯的工艺，该工艺包括在羰基化催化剂（如金属-有机磷配位体络合物催化剂）存在下，将一种或多种取代或未取代的戊烯-1-醇进行羰基化，以生产所述一种或多种取代或未取代的epsilon己内酯和/或其水合物和/或酯。通过本发明工艺生产的取代和未取代的epsilon己内酯和/或其水合物和/或酯类可通过进一步反应得到所需的衍生物，如epsilon己内酰胺。本发明还部分涉及含有一种或多种取代或未取代的epsilon己内酯和/或其水合物和/或酯作为主要反应产物的反应混合物。
• Process for producing epsilon caprolactones from penten-1-ols
  申请人：UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

  公开号：EP0872483A1

  公开（公告）日：1998-10-21

  This invention relates in part to processes for producing one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof which comprise subjecting one or more substituted or unsubstituted penten-1-ols to carbonylation in the presence of a carbonylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce said one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof. The substituted and unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactam. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof as principal product(s) of reaction.

  本发明部分涉及生产一种或多种取代或未取代的epsilon己内酯和/或其水合物和/或酯的工艺，该工艺包括在羰基化催化剂（如金属-有机磷配位体络合物催化剂）存在下，将一种或多种取代或未取代的戊烯-1-醇进行羰基化，以生产所述一种或多种取代或未取代的epsilon己内酯和/或其水合物和/或酯。通过本发明工艺生产的取代和未取代的epsilon己内酯和/或其水合物和/或酯类可通过进一步反应得到所需的衍生物，如epsilon己内酰胺。本发明还部分涉及含有一种或多种取代或未取代的epsilon己内酯和/或其水合物和/或酯作为主要反应产物的反应混合物。
• Phosphinyl amidine compounds, metal complexes, catalyst systems, and their use to oligomerize or polymerize olefins
  申请人：Chevron Phillips Chemical Company LP

  公开号：US10144752B2

  公开（公告）日：2018-12-04

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物。还公开了制造 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物的方法。还公开了利用 N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物的催化剂体系，以及 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物在烯烃的低聚和/或聚合中的用途。
• Processes for producing epsilon caprolactones and/or hydrates and/or esters thereof
  申请人：——

  公开号：US20010053858A1

  公开（公告）日：2001-12-20

  This invention relates in part to processes for producing one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof which comprise subjecting one or more substituted or unsubstituted penten-1-ols to carbonylation in the presence of a carbonylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce said one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof. The substituted and unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactam. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof as principal product(s) of reaction.

  本发明部分涉及生产一种或多种取代或未取代的epsilon己内酯和/或其水合物和/或酯的工艺，该工艺包括在羰基化催化剂（如金属-有机磷配位体络合物催化剂）存在下，将一种或多种取代或未取代的戊烯-1-醇进行羰基化，以生产所述一种或多种取代或未取代的epsilon己内酯和/或其水合物和/或酯。通过本发明工艺生产的取代和未取代的epsilon己内酯和/或其水合物和/或酯类可通过进一步反应得到所需的衍生物，如epsilon己内酰胺。本发明还部分涉及含有一种或多种取代或未取代的epsilon己内酯和/或其水合物和/或酯作为主要反应产物的反应混合物。