tert-butyl-dimethyl-[(E)-2-[(2-methylpropan-2-yl)oxy]-2-phenylethenyl]silane | 196106-76-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tert-butyl-dimethyl-[(E)-2-[(2-methylpropan-2-yl)oxy]-2-phenylethenyl]silane
• CAS: 196106-76-0
• 化学式: C₁₈H₃₀OSi
• 分子量: 290.521
• InChiKey: NAJQUXKGONOBFZ-JQIJEIRASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.89
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  tert-butyl-dimethyl-[(E)-2-[(2-methylpropan-2-yl)oxy]-2-phenylethenyl]silane 在 水 、 氢气 作用下， 生成 2-[tert-Butyl(dimethyl)silyl]-1-phenylethan-1-one
  参考文献：
  名称：

  Stereospecific Access to Trisubstituted Enol Ethers from Vinylsilanes

  摘要：

  The reaction of RCH=CHSiMe3 (R: alkyl or aryl) with IPy2BF4/HBF4 and a set of representative alcohols affords the corresponding addition products as a single regio- and stereoisomers in good yield. Subsequent dehydroiodination with DBU furnishes silyl-substituted enol ethers. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)01547-5
• 作为产物：
  描述：

  tert-butyl-dimethyl-((Z)-styryl)-silane 在 tetrafluoroboric acid 、 Barluenga reagent 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 二氯甲烷 为溶剂， 反应 21.0h， 生成 tert-butyl-dimethyl-[(E)-2-[(2-methylpropan-2-yl)oxy]-2-phenylethenyl]silane
  参考文献：
  名称：

  Stereospecific Access to Trisubstituted Enol Ethers from Vinylsilanes

  摘要：

  The reaction of RCH=CHSiMe3 (R: alkyl or aryl) with IPy2BF4/HBF4 and a set of representative alcohols affords the corresponding addition products as a single regio- and stereoisomers in good yield. Subsequent dehydroiodination with DBU furnishes silyl-substituted enol ethers. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)01547-5

文献信息

• Stereospecific Access to Trisubstituted Enol Ethers from Vinylsilanes
  作者：José Barluenga、Lorenzo J. Alvarez-García、Gustavo P. Romanelli、José M. González

  DOI：10.1016/s0040-4039(97)01547-5

  日期：1997.9

  The reaction of RCH=CHSiMe3 (R: alkyl or aryl) with IPy2BF4/HBF4 and a set of representative alcohols affords the corresponding addition products as a single regio- and stereoisomers in good yield. Subsequent dehydroiodination with DBU furnishes silyl-substituted enol ethers. (C) 1997 Elsevier Science Ltd.