2,6-bis(4-azidobenzylidene)-4-methylcyclohexanone | 5284-79-7

• 物质功能分类: 化学试剂 - 有机试剂 - 叠氮
• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 2,6-bis(4-azidobenzylidene)-4-methylcyclohexanone
• 英文别名: 2,6-bis-[(4-azidophenyl)-methylene]-4-methylcyclohexanone；(2E,6E)-2,6-bis[(4-azidophenyl)methylidene]-4-methylcyclohexan-1-one
• CAS: 5284-79-7
• 化学式: C₂₁H₁₈N₆O
• 分子量: 370.414
• InChiKey: MLIWQXBKMZNZNF-PWDIZTEBSA-N

物化性质

• 熔点：
  124-126 °C(lit.)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  28
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  5

安全信息

• 危险等级：
  4.1
• 危险品标志：
  F
• 安全说明：
  S16,S33
• 危险类别码：
  R11
• WGK Germany：
  3
• 危险品运输编号：
  UN 1325 4.1/PG 2
• 包装等级：
  III
• 危险类别：
  4.1
• 危险标志：
  GHS02
• 危险性描述：
  H228
• 危险性防范说明：
  P210

反应信息

• 作为反应物：
  描述：

  、 2,6-bis(4-azidobenzylidene)-4-methylcyclohexanone 在 tetrakis(actonitrile)copper(I) hexafluorophosphate 作用下， 以 二甲基亚砜 为溶剂， 反应 0.01h， 生成 2,6-Bis-[1-(4-{4-[4-((1R,2R,3S,4R,6S)-4,6-diamino-2,3-dihydroxy-cyclohexyloxy)-butyl]-[1,2,3]triazol-1-yl}-phenyl)-meth-(E)-ylidene]-4-methyl-cyclohexanone
  参考文献：
  名称：

  Size-Specific Ligands for RNA Hairpin Loops

  摘要：

  The targeting of one mRNA in the transcriptome requires small molecules that bind with substantial affinity and specificity. As such, compounds with specificity for individual RNA secondary structural motifs could be useful for targeting RNA. Described herein is the synthesis of a combinatorial library of 105 dimers of deoxystreptamine and the subsequent identification of compounds with specificity for specific RNA hairpin loop sizes, including tetraloops and octaloops. Such compounds will be useful for the perturbation of RNA function in vivo.

  DOI：

  10.1021/ja051685b
• 作为产物：
  描述：

  2,6-bis-[(4-aminophenyl)-methylene]-4-methylcyclohexanone 在 sodium nitrite 作用下， 生成 2,6-bis(4-azidobenzylidene)-4-methylcyclohexanone
  参考文献：
  名称：

  Process for the preparation of azidobenzal compounds

  摘要：

  一种制备式为##STR1##的2,6-双[(4-偶氮苯基)亚甲基]-环己酮的方法，其中R是氢或1-6个碳原子的烷基，包括将式为##STR2##的环己酮（其中R如上定义）与4-氨基苯甲醛缩合，在碱性缩合剂的存在下，4-氨基团可选择性地被保护；当4-氨基团被保护时去除保护基团；重氮化得到式为##STR3##的2,6-双[(4-氨基苯基)亚甲基]-环己酮（其中R如上定义），并将重氮化产物与碱金属偶氮化物反应。

  公开号：

  US04354976A1

文献信息

• Polymerizable composition and formed article using the same
  申请人：Kodemura Junji

  公开号：US20060211809A1

  公开（公告）日：2006-09-21

  A polymerizable composition which comprises a cycloolefin monomer (A), a filler (B), a polymer (C) having a carboxyl group or a carboxylic acid anhydride group and having an acid value of 0.1 to 100 mgKOH/g, and a metathesis polymerization catalyst (D). The polymerizable composition comprises a cycloolefin monomer and a large amount of a filler, and has a low viscosity and is excellent in fluidity, and further can provide a molded product which is excellent in the lowness of dielectric constant, the lowness of dielectric loss tangent, the lowness of linear expansion coefficient, high heat resistance and adhesiveness, and further is free of bubble inclusion.

  一种可聚合的组合物，包括环烯烃单体（A）、填料（B）、具有羧基或羧酸酐基团且酸值为0.1至100 mgKOH/g的聚合物（C），以及一种交换聚合催化剂（D）。该可聚合组合物包括环烯烃单体和大量填料，具有低粘度和优异的流动性，并且能够提供优异的介电常数低、介电损耗正切低、线性膨胀系数低、高耐热性和粘附性的成型产品，且无气泡包含。
• INFRARED-SENSITIVE COLOR DEVELOPING COMPOSITION, LITHOGRAPHIC PRINTING PLATE PRECURSOR, PLATE MAKING METHOD FOR LITHOGRAPHIC PRINTING PLATE, AND INFRARED-SENSITIVE COLOR DEVELOPER
  申请人：FUJIFILM Corporation

  公开号：US20160326372A1

  公开（公告）日：2016-11-10

  Objects are to provide an infrared-sensitive color developing composition which develops colors in a high density by means of infrared exposure and does not significantly discolor when aged, to provide a lithographic printing plate precursor which has extremely excellent plate-inspecting properties and favorable storage stability and is capable of maintaining favorable color-developing properties and a plate making method for a lithographic printing plate in which the lithographic printing plate precursor is used, and to provide a new compound that can be preferably used as an infrared-sensitive color developer. An infrared-sensitive color developing composition of the present invention includes a compound represented by Formula (1) (Component A). In addition, the compound in the present invention is represented by Formula (1).

  本发明旨在提供一种红外敏感的彩色显影组成物，通过红外曝光高密度地显色而在老化时不会显著变色，提供一种具有极好的版检查性能和良好的储存稳定性的平版印刷版前体，能够保持良好的显色性能和一种平版印刷版制版方法，其中使用了该平版印刷版前体，并提供一种新的化合物，可作为红外敏感的彩色显影剂优选使用。 本发明的红外敏感的彩色显影组成物包括由式（1）表示的化合物（组分A）。此外，本发明中的化合物由式（1）表示。
• NITROXIDE CONTAINING ELECTRODE MATERIALS FOR SECONDARY BATTERIES
  申请人：Nesvadba Peter

  公开号：US20100181527A1

  公开（公告）日：2010-07-22

  This invention relates to a stable secondary battery utilizing as active principle the oxidation and reduction cycle of a sterically hindered nitroxide radical, a sterically hindered oxoammonium cation, a sterically hindered hydroxylamine or a sterically hindered aminoxide anion containing a piperazin-2,6-dione, a piperazin-2-one or morpholin-2-one structural unit. Further aspects of the invention are a method for providing such a secondary battery, the use of the respective compounds as active elements in secondary batteries and selected novel compounds.

  本发明涉及一种稳定的二次电池，利用空间位阻的亚硝基自由基、空间位阻的氧代铵阳离子、空间位阻的羟胺或空间位阻的氨氧阴离子，其中包含哌嗪-2,6-二酮、哌嗪-2-酮或吗啉-2-酮结构单元的氧化还原循环作为活性原理。发明的其他方面包括提供这种二次电池的方法，使用相应化合物作为二次电池中的活性元素以及选择的新化合物。
• DIVERSITY-ORIENTED POLYMERS OF INTRINSIC MICROPOROSITY AND USES THEREOF
  申请人：The Regents of the University of California

  公开号：US20210309802A1

  公开（公告）日：2021-10-07

  The present disclosure is directed to raicroporous ladder polymers containing amine-functionalized monomer segments, amidoxime-functionalized monomer segments, or a combination thereof. Monomer compounds for preparation of the polymers are also described, as well as membranes and electrochemical cells containing the polymers.

  本公开涉及含有胺基化单体段、酰胺肟化单体段或两者组合的多孔梯形聚合物。还描述了用于制备聚合物的单体化合物，以及包含聚合物的膜和电化学电池。
• (Meth) acrylate derivative, polymer and photoresist composition having lactone structure, and method for forming pattern by using it
  申请人：——

  公开号：US20010026901A1

  公开（公告）日：2001-10-04

  There are here disclosed a photoresist material for lithography using a light of 220 nm or less which comprises at least a polymer represented by the following formula (2) and a photo-acid generator for generating an acid by exposure: 1 wherein R 1 , R 2 , R 3 and R 5 are each a hydrogen atom or a methyl group; R 4 is an acid-labile group, an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has an acid labile group, an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has a carboxyl group, or a hydrocarbon group having 3 to 13 carbon atoms, which has an epoxy group; R 6 is a hydrogen atom, a hydrocarbon group having 1 to 12 carbon atoms, or an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has a carboxyl group; x, y and z are optional values which meet x+y+z=1, 0

  本发明公开了一种用于使用220纳米或更短波长的光进行光刻的光阻材料，其包括至少一种由以下式（2）表示的聚合物和用于通过曝光产���酸的光酸发生剂： 其中，R1、R2、R3和R5分别为氢原子或甲基基团；R4为酸可裂解基团、具有7至13个碳原子的脂环烃基团，其具有酸可裂解基团、具有7至13个碳原子的脂环烃基团，其具有羧基，或具有3至13个碳原子的烃基团，其具有环氧基团；R6为氢原子、具有1至12个碳原子的烃基团，或具有7至13个碳原子的脂环烃基团，其具有羧基；x、y和z是可选的值，满足x+y+z=1，0≤x≤1，0≤y<1和0≤z<1；聚合物的重均分子量在2000至200000范围内，以及具有由式（3）表示的脂环内酯结构的（甲）丙烯酸酯单元的树脂： 其中，R8为氢原子或甲基基团，R9为具有脂环内酯结构的7至16个碳原子的烃基团。

表征谱图