tert-Butyl-peroxycaprinat | 16474-36-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: tert-Butyl-peroxycaprinat
• 英文别名: Decaneperoxoic acid tert-butyl ester；tert-butyl decaneperoxoate
• CAS: 16474-36-5
• 化学式: C₁₄H₂₈O₃
• 分子量: 244.375
• InChiKey: WKEWCYHGACEYTR-UHFFFAOYSA-N

物化性质

• 沸点：
  290.1±23.0 °C(Predicted)
• 密度：
  0.906±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  叔丁基过氧化氢 、 癸酰氯 在 吡啶 、 Petroleum ether 作用下， 生成 tert-Butyl-peroxycaprinat
  参考文献：
  名称：

  Peroxides. VI.² Preparation of t-Butyl Peresters and Diacyl Peroxides of Aliphatic Monobasic Acids³

  摘要：

  DOI：

  10.1021/ja01519a023

文献信息

• Oxygen permeable hard and semi-hard contact lens compositions, processes for their preparation, contact lenses and their manufacture from such compositions
  申请人：SYNTEX (U.S.A.) INC.

  公开号：EP0067254A1

  公开（公告）日：1982-12-22

  The invention relates to novel monomers of polysiloxanyl alkyl esters of acrylic and methacrylic acids and its complymerization with alkyl esters of acrylic, methacrylic acids and/or itaconate esters to produce highly oxygen permeable contact lens material. The copolymer preferably. includes a cross-linking agent and hydrophilic monomer. Contact lenses manufactured from the material are easily machined and polished into hard or semi-hard contact lenses having excellent dimensional stability.

  本发明涉及新型丙烯酸和甲基丙烯酸聚硅氧烷烷基酯单体及其与丙烯酸、甲基丙烯酸和/或它康酸烷基酯的共聚物，用于生产高透氧性隐形眼镜材料。 共聚物最好包括交联剂和亲水性单体。 用该材料生产的隐形眼镜易于加工和抛光，可制成具有良好尺寸稳定性的硬性或半硬性隐形眼镜。
• Polymers primarily for contact lenses, and contact lenses made from them
  申请人：Tsuetaki, George F.

  公开号：EP0080539A1

  公开（公告）日：1983-06-08

  The invention relates to new monomers of polysiloxanyl alkyl esters of acrylic and methacrylic acids and their copolymerization with alkyl esters of acrylic or methacrylic acids and/or itaconate esters to produce highly oxygen- permeable material primarily for contact lenses. The copolymer will include 10% to 60% of the silicon-containing monomer or monomers; preferred such monomers are tris(non amethyltetrasiloxanyl) methacryloxypropylsilane) or bis(decamethylpentasiloxanyl)di(methacryloxypropyl- methylsilane). The copolymer preferably includes a cross-linking agent and hydrophilic monomer. Contact lenses manufactured from the material are machined and polished into hard or semi-hard contact lenses having dimensional stability.

  本发明涉及丙烯酸和甲基丙烯酸的聚硅氧烷烷基酯的新单体及其与丙烯酸或甲基丙烯酸的烷基酯和/或它康酸酯的共聚物，以生产主要用于隐形眼镜的高透氧性材料。共聚物将包括 10%至 60%的含硅单体；优选的此类单体是三(非甲基四硅氧烷基)甲基丙烯酰氧基丙基硅烷或双(十甲基五硅氧烷基)二(甲基丙烯酰氧基丙基甲基硅烷)。共聚物最好包括交联剂和亲水性单体。用这种材料制成的隐形眼镜经加工和抛光后，可成为具有尺寸稳定性的硬性或半硬性隐形眼镜。
• Fuel compositions with enhanced combustion characteristics
  申请人：ETHYL PETROLEUM ADDITIVES, INC.

  公开号：EP0467628A1

  公开（公告）日：1992-01-22

  Reduction of the amount of atmospheric pollutants (NOx, CO, and/or hydrocarbons) formed on combustion of middle distillate fuels in engines or burner apparatus can be achieved, without concomitant increases in emissions ofparticulates, by fuels containing less than 500 ppm of sulfur and at least one peroxy ester combustion improver.

  通过含硫量低于 500 ppm 的燃料和至少一种过氧酯燃烧改进剂，可以减少发动机或燃烧器装置燃烧中间馏分燃料时形成的大气污染物（氮氧化物、一氧化碳和/或碳氢化合物）的数量，而不会同时增加微粒的排放量。
• Fuel compositions
  申请人：ETHYL PETROLEUM ADDITIVES, INC.

  公开号：EP0537931A1

  公开（公告）日：1993-04-21

  Fuels, methods of producing fuels, and methods of using fuels to reduce the amount of atmospheric pollutants (NOx, CO, and/or hydrocarbons) formed on combustion of middle distillate fuels in engines or burner apparatus. These results can be achieved without an undesirable increase in emissions of particulates. The fuels contain less than 500 ppm of sulfur and at least one organic nitrate combustion improver and at least one tertiary alkyl peroxy ester alkanoate or peroxy benzoate.

  燃料、生产燃料的方法和使用燃料的方法，可减少中间馏分燃料在发动机或燃烧器设备中燃烧时形成的大气污染物（氮氧化物、一氧化碳和/或碳氢化合物）的数量。这些结果可以在不增加微粒排放量的情况下实现。这些燃料含硫量低于 500 ppm，并含有至少一种有机硝酸盐燃烧改进剂和至少一种叔烷基过氧酯烷酸酯或过氧苯甲酸酯。
• Ferroelectric aerogel composites for voltage-variable dielectric tuning, and method for making the same
  申请人：Hughes Aircraft Company

  公开号：EP0667324A1

  公开（公告）日：1995-08-16

  Ferroelectric composites are prepared by sol-gel derived procedures. The present invention utilizes a sol-gel process to form a gel in a mold of the desired size and shape ([1]-[4]), to dry the gel using a supercritical fluid extraction ([5]-[7]), to sinter the dried gel to a crystalline ceramic ([8]), and finally to impregnate the pores with a low loss polymer ([9]). The aerogel composition may be a barium titanate-based composition such as barium strontium titanate (BST). Making a ferroelectric aerogel composite provides a unique and novel means of fully exploiting the voltage- and/or frequency-tunable properties of certain compositions by maximizing their desirable properties and minimizing their undesirable characteristics such as loss at operational frequencies (Fig. 2).

  铁电复合材料是通过溶胶-凝胶衍生工艺制备的。本发明利用溶胶-凝胶法在所需尺寸和形状的模具中形成凝胶（[1]-[4]），使用超临界流体萃取法干燥凝胶（[5]-[7]），将干燥的凝胶烧结成结晶陶瓷（[8]），最后用低损耗聚合物浸渍孔隙（[9]）。气凝胶成分可以是钛酸钡基成分，如钛酸锶钡（BST）。制作铁电气凝胶复合材料为充分利用某些成分的电压和/或频率可调特性提供了一种独特而新颖的方法，即最大限度地提高其理想特性，同时最大限度地降低其不良特性，如工作频率下的损耗（图 2）。