5-hydroxytetratriacontanal | 957126-14-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 5-hydroxytetratriacontanal
• CAS: 957126-14-6
• 化学式: C₃₄H₆₈O₂
• 分子量: 508.913
• InChiKey: CAQGJEHTMLMINH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.66
• 重原子数：
  36.0
• 可旋转键数：
  32.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.97
• 拓扑面积：
  37.3
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  5-hydroxytetratriacontanal 、 2,2,2-三氟-N,N-二(三甲硅基)乙酰胺 以 吡啶 为溶剂， 反应 0.5h， 生成
  参考文献：
  名称：

  Very-long-chain hydroxyaldehydes from the cuticular wax of Taxus baccata needles

  摘要：

  In the cuticular wax of Taxus baccata needles, homologous series of very-long-chain 1,5-alkanediols and 5-hydroxyaldehydes were identified by various chemical transformations with product assignment using GC-MS. The 1,5-alkanediols had chain lengths ranging from C-28 to C-38, with strong predominance of even carbon numbers and a maximum at C-32 (29%). The series of 5-hydroxyaldehydes comprised chain lengths C-24 and C-26-C-36, and showed a pronounced prevalence of even-numbered homologues. 5-Hydroxyoctacosanal was the most abundant compound of the series (42%). The 5-hydroxyaldehydes together amounted to 0.4 mu g/cm(2), corresponding to 1.2% of total wax of the needles. A polyketide-like biosynthetic pathway is proposed based on the (similar) chain length distributions and functional group patterns for both compound classes. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.phytochem.2007.05.029

文献信息

• Very-long-chain hydroxyaldehydes from the cuticular wax of Taxus baccata needles
  作者：Miao Wen、Reinhard Jetter

  DOI：10.1016/j.phytochem.2007.05.029

  日期：2007.10

  In the cuticular wax of Taxus baccata needles, homologous series of very-long-chain 1,5-alkanediols and 5-hydroxyaldehydes were identified by various chemical transformations with product assignment using GC-MS. The 1,5-alkanediols had chain lengths ranging from C-28 to C-38, with strong predominance of even carbon numbers and a maximum at C-32 (29%). The series of 5-hydroxyaldehydes comprised chain lengths C-24 and C-26-C-36, and showed a pronounced prevalence of even-numbered homologues. 5-Hydroxyoctacosanal was the most abundant compound of the series (42%). The 5-hydroxyaldehydes together amounted to 0.4 mu g/cm(2), corresponding to 1.2% of total wax of the needles. A polyketide-like biosynthetic pathway is proposed based on the (similar) chain length distributions and functional group patterns for both compound classes. (C) 2007 Elsevier Ltd. All rights reserved.