methyl 2-(2-cyano-4-methoxy-2,4-dimethylpentyl)acrylate | 1404110-93-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: methyl 2-(2-cyano-4-methoxy-2,4-dimethylpentyl)acrylate
• 英文别名: Methyl 4-cyano-6-methoxy-4,6-dimethyl-2-methylideneheptanoate；methyl 4-cyano-6-methoxy-4,6-dimethyl-2-methylideneheptanoate
• CAS: 1404110-93-5
• 化学式: C₁₃H₂₁NO₃
• 分子量: 239.315
• InChiKey: GVZMCHWEPKNLKF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  59.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  偶氮二甲氧基异庚腈 、 甲基丙烯酸甲酯 在 4-tert-butyl-2,2,6,6-tetraethyl-3-oxo-piperazin-1-oxyl 作用下， 反应 5.0h， 以7%的产率得到methyl 2-(2-cyano-4-methoxy-2,4-dimethylpentyl)acrylate
  参考文献：
  名称：

  Nitroxide-Mediated Polymerization of Styrene, Butyl Acrylate, or Methyl Methacrylate by Microflow Reactor Technology

  摘要：

  The nitroxide-mediated radical polymerization (NMP) of styrene and butyl acrylate in microflow tubular reactors was examined. In comparison with polymerizations conducted in a batch reactor under otherwise identical conditions, the microflow setup gave higher conversions and produced polymers with lower polydispersity indices. Block copolymers of the two monomers could be synthesized by connecting two microflow tubular reactors through a T-junction. The NMP of methyl methacrylate in a microflow tubular reactor was also investigated.

  DOI：

  10.1055/s-0031-1290780

文献信息

• Nitroxide-Mediated Polymerization of Styrene, Butyl Acrylate, or Methyl Methacrylate by Microflow Reactor Technology
  作者：Ilhyong Ryu、Armido Studer、Takahide Fukuyama、Yoshito Kajihara

  DOI：10.1055/s-0031-1290780

  日期：2012.8

  The nitroxide-mediated radical polymerization (NMP) of styrene and butyl acrylate in microflow tubular reactors was examined. In comparison with polymerizations conducted in a batch reactor under otherwise identical conditions, the microflow setup gave higher conversions and produced polymers with lower polydispersity indices. Block copolymers of the two monomers could be synthesized by connecting two microflow tubular reactors through a T-junction. The NMP of methyl methacrylate in a microflow tubular reactor was also investigated.