cis-Tridec-11-enyl-1-acetat | 33951-95-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: cis-Tridec-11-enyl-1-acetat
• 英文别名: (Z)-11-Tridecenyl-acetat；(Z)-11-tridecenyl acetate；cis-11-Tridecen-1-ol acetate；[(Z)-tridec-11-enyl] acetate
• CAS: 33951-95-0
• 化学式: C₁₅H₂₈O₂
• 分子量: 240.386
• InChiKey: MNOWBWZEFOISCB-ARJAWSKDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  -11-octadecenyl acetate 生成 cis-Tridec-11-enyl-1-acetat
  参考文献：
  名称：

  XIII信息素：合成von 1-substituierten（Z）-11-Alkenen

  摘要：

  Es werden zwei allgemeine Methoden zur Darstellung von 1-substituierten（Z）-11-Alkenen durchstereoselektive Wittig -Reaktion beschrieben。世卫组织制毒药和系统性药典。

  DOI：

  10.1002/cber.19781110123

文献信息

• PRODUCTION OF FATTY OLEFIN DERIVATIVES VIA OLEFIN METATHESIS
  申请人：PROVIVI, INC.

  公开号：US20170137365A1

  公开（公告）日：2017-05-18

  In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R 1 is independently selected from H, C 1-18 alkyl, and C 2-18 alkenyl; R 2b is C 1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.

  在一个方面，该发明提供了一种合成脂肪烯衍生物的方法。该方法包括：a）在存在一种烯烃催化剂的条件下，将符合式I的烯烃与符合式IIb的交换反应伙伴接触，以形成符合式IIIb的交换产物；并b）将交换产物转化为脂肪烯衍生物。每个R1独立地选择自H、C1-18烷基和C2-18烯基；R2为C1-8烷基；下标y为0至17之间的整数；下标z为0至17之间的整数。在某些实施方式中，交换催化剂为钨催化剂或钼催化剂。在各种实施方式中，脂肪烯衍生物为信息素。还描述了信息素组合物及其使用方法。
• AGRICULTURAL PHEROMONE COMPOSITIONS COMPRISING POSITIONAL ISOMERS
  申请人：PROVIVI, INC.

  公开号：US20170135343A1

  公开（公告）日：2017-05-18

  The present disclosure provides pheromone compositions. In some aspects, the compositions taught herein comprise a pheromone chemically corresponding to the pheromone naturally produced by a given insect, along with at least one positional isomer of said pheromone. In various aspects, pheromone compositions of the present disclosure are able to modulate the response of the insect based on the ratio of natural pheromone to its positional isomer.

  本公开提供信息素组合物。在某些方面，本文所教授的组合物包括一种与某种昆虫自然产生的信息素在化学上相对应的信息素，以及至少一种该信息素的位置异构体。在各个方面，本公开的信息素组合物能够通过自然信息素与其位置异构体的比例来调节昆虫的反应。
• Novel bisexual attractants, aggregants and arrestants for adults and larvae of codling moth and other species of lepidoptera
  申请人：——

  公开号：US20020061324A1

  公开（公告）日：2002-05-23

  Novel bisexual attractants for lepidopterous insect pests isolated from pears or apples. A method for monitoring and control of codling moth and other species of Lepidoptera comprising a lure and kill, mating disruption or mass trapping strategy. A method of using a formulation containing the bisexual attractants with or without an insecticide and/or pheromone for control of the insect pests.

  从梨或苹果中分离出的新型双性吸引剂，用于吸引鳞翅目害虫。一种监测和控制苹果蠹和其他鳞翅目物种的方法，包括诱杀、交配干扰或大规模捕捉策略。一种使用含有双性吸引剂的配方（带或不带杀虫剂和/或信息素）来控制害虫的方法。
• A composite body for sustainedly releasing vapor of a vaporizable active substance and a method for the preparation thereof
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0160151A2

  公开（公告）日：1985-11-06

  The invention provides a vapor dispenser for the emission of a vaporizable substance exhibiting an activity in the atmosphere in a trace concentration, such as an insectan sex pheromone used in pest control, at a controlled uniform rate, a large number of which can be distributed in the field with minimum labor, for example, by tying to and hanging on the twigs of tea plants in a tea garden. The inventive vapor dispenser comprises a plastic-made tubular body having a specific cross sectional area of the pore and a specific outer circumferential length filled with the vaporizable substance and a coated or uncoated metal wire bonded to the tubular body side-by-side, said metal having a Brinell hardness of 65 or smaller, to facilitate tying works and stability of the dispenser tied and hung on the twigs by virtue of the moderate deformability and shape-retainability of the wire.

  本发明提供了一种可在大气中以痕量浓度释放具有活性的可汽化物质（如害虫防治中使用的昆虫性信息素）的蒸汽分配器，其释放量可控且均匀，可在田间以最少的劳动量进行大量分配，例如，将其绑在茶园中茶树的枝条上并悬挂起来。本发明的蒸汽分配器包括一个塑料制成的管状体，该管状体具有特定的孔截面积和特定的外圆周长度，管状体中填充有可蒸发物质，管状体上并排粘接有涂层或无涂层的金属丝，所述金属的布氏硬度为 65 或更小，以方便绑扎工作，并凭借金属丝的适度变形性和形状保持性，使分配器稳定地绑扎和悬挂在树枝上。
• Attractant composition containing ethyl 3-methylbutanoate and (E,E)-8-,10-dodecadien-1-ol
  申请人：BASF SE

  公开号：EP2735230A1

  公开（公告）日：2014-05-28

  The present invention relates to a composition for controlling undesired insect infestation comprising (E,E)-8,10-dodecadien-1-ol and ethyl 3-methylbutanoate. The invention further relates to a process for the preparation of said composition and a method for controlling undesired insect infestation with said composition.

  本发明涉及一种用于控制虫害的组合物，该组合物由(E,E)-8,10-十二碳二烯-1-醇和 3-甲基丁酸乙酯组成。本发明还涉及一种制备所述组合物的工艺和一种用所述组合物控制虫害的方法。