1-vinyloxy-3-methylpropyl methacrylate | 443753-98-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1-vinyloxy-3-methylpropyl methacrylate
• 英文别名: 4-Ethenoxybutan-2-yl 2-methylprop-2-enoate
• CAS: 443753-98-8
• 化学式: C₁₀H₁₆O₃
• 分子量: 184.235
• InChiKey: MNEVOJKXGFTNDQ-UHFFFAOYSA-N

物化性质

• 沸点：
  245.3±23.0 °C(Predicted)
• 密度：
  0.950±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  叔丁醇 、 1-vinyloxy-3-methylpropyl methacrylate 在 三氟乙酸 作用下， 以66%的产率得到
  参考文献：
  名称：

  摘要：

  Alcohols of various structures, in particular, ethylene, acetylene, fluorocontaining alcohols, add regio- and chemoselectively to the vinyloxy group of vinyloxyalkyl methacrylates at 20-40degreesC in the presence of catalytic quantities of trifluoroacetic acid affording functional acetalmethacrylates in high yield.

  DOI：

  10.1023/a:1013905514252
• 作为产物：
  描述：

  4-vinyloxybutan-2-ol 、 甲基丙烯酸甲酯 在 sodium 、 对苯二酚 作用下， 以60%的产率得到1-vinyloxy-3-methylpropyl methacrylate
  参考文献：
  名称：

  摘要：

  Alcohols of various structures, in particular, ethylene, acetylene, fluorocontaining alcohols, add regio- and chemoselectively to the vinyloxy group of vinyloxyalkyl methacrylates at 20-40degreesC in the presence of catalytic quantities of trifluoroacetic acid affording functional acetalmethacrylates in high yield.

  DOI：

  10.1023/a:1013905514252

文献信息

• PATTERN FORMING METHOD
  申请人：HANEDA Yuya

  公开号：US20120249664A1

  公开（公告）日：2012-10-04

  A pattern forming method includes: performing a first droplet ejection step by ejecting droplets containing 0.1%-2% polysiloxane by mass onto a substrate; performing a first layer forming step by solidifying the droplets ejected onto the substrate so that a first layer is formed; performing a second droplet ejection step by ejecting more droplets over the first layer; and performing a second layer forming step by solidifying the droplets ejected onto the first layer so that a second layer is formed.

  一种形成图案的方法包括：通过将含有0.1％-2％聚硅氧烷的液滴喷射到基板上执行第一液滴喷射步骤；通过固化喷射到基板上的液滴以形成第一层执行第一层形成步骤；通过在第一层上喷射更多的液滴执行第二液滴喷射步骤；通过固化喷射到第一层上的液滴以形成第二层执行第二层形成步骤。
• RADIATION CURABLE INK JET COMPOSITION AND INK JET METHOD
  申请人：Seiko Epson Corporation

  公开号：EP3885413A1

  公开（公告）日：2021-09-29

  A radiation curable ink jet composition includes polymerizable compounds; and a photopolymerization initiator, the polymerizable compounds include a vinyl ether group-containing (meth)acrylate represented by the following general formula (I), a content of the vinyl ether group-containing (meth)acrylate with respect to a total mass of the radiation curable inkjet composition is 15 percent by mass or more, and the photopolymerization initiator includes ethyl (2,4,6-trimethylbenzoyl)phenylphosphinate.          H2C=CR1-CO-OR2-O-CH=CH-R3     (I) In the above formula, R1 represents a hydrogen atom or a methyl group, R2 represents a divalent organic residue having 2 to 20 carbon atoms, and R3 represents a hydrogen atom or a monovalent organic residue having 1 to 11 carbon atoms.

  一种可辐射固化的喷墨组合物包括可聚合化合物；以及光聚合引发剂，可聚合化合物包括由以下通式（I）表示的含乙烯基醚基（甲基）丙烯酸酯，含乙烯基醚基（甲基）丙烯酸酯的含量占可辐射固化的喷墨组合物总质量的 15% 或以上，光聚合引发剂包括（2,4,6-三甲基苯甲酰基）苯基膦酸乙酯。 h2c=cr1-co-or2-o-ch=ch-r3 (i) 在上式中，R1 代表氢原子或甲基，R2 代表具有 2 至 20 个碳原子的二价有机残基，R3 代表氢原子或具有 1 至 11 个碳原子的一价有机残基。
• Radiation curable ink jet composition and ink jet recording method
  申请人：Seiko Epson Corporation

  公开号：US10308824B2

  公开（公告）日：2019-06-04

  There is provided a radiation curable ink jet composition including: a monomer A that has one of a (meth)acryloyloxy group and a (meth)acryloyl group and has a cyclic structure containing one or more nitrogen atoms and one or more oxygen atoms in addition to the (meth)acryloyloxy group and the (meth)acryloyl group; and a monofunctional monomer B other than the monomer A; in which the content of the monomer A is equal to or less than 25% by mass with respect to the total mass of the composition, and in which mol average Tg of the monomer A and the monofunctional monomer B is equal to or greater than 45° C.

  提供了一种可辐射固化的喷墨组合物，包括单体 A，它具有(甲基)丙烯酰氧基和(甲基)丙烯酰基中的一个，并具有环状结构，除(甲基)丙烯酰氧基和(甲基)丙烯酰基外，还含有一个或多个氮原子和一个或多个氧原子；和除单体 A 之外的单官能团单体 B；其中单体 A 的含量等于或小于组合物总质量的 25%（以质量计），且单体 A 和单官能团单体 B 的摩尔平均 Tg 等于或大于 45℃。
• ——
  作者：O. V. Vysotskaya、L. A. Oparina、L. N. Parshina、B. V. Timokhin、N. K. Gusarova、B. A. Trofimov

  DOI：10.1023/a:1026024305090

  日期：——

  Reactions of vinyloxyalkyl methacrylates with triazoles (1,2,4-triazole, 1,2,3-benzotriazole, 5-methyl-1,2,3-benzotriazole) under electrophilic conditions (50degreesC, 1-2 h, 1 wt% CF3COOH) occur chemoselectively and afford in quantitative yield polyfunctional methacrylates with triazole and benzotriazole yields.
• ULTRAVIOLET CURABLE TYPE INK-JET INK COMPOSITION, RECORDING METHOD AND RECORDING APPARATUS USISNG SAME
  申请人：KAGOSE Taketoshi

  公开号：US20120113201A1

  公开（公告）日：2012-05-10

  Provided is a UV curable type ink-jet ink composition containing a monomer A which is expressed by the following general formula (I): CH 2 ═CR 1 —COOR 2 —O—CH═CH—R 3 (I) (in the formula, R 1 is a hydrogen atom or methyl radical, R 2 is a bivalent organic residue radical having a carbon number in a range of 2 to 20, and R 3 is a hydrogen atom or a univalent organic residue radical having a carbon number in a range of 1 to 11), a compound B containing five or more (meth)acryloyl radicals per molecule, and a monofunctional (meth)acrylate C having an aromatic ring skeleton, wherein the monofunctional (meth)acrylate C which is in a range of 5 to 35 wt % with respect to the total weight of the ink composition is contained.