hexanedioic acid isobutyl ester | 20166-56-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: hexanedioic acid isobutyl ester
• 英文别名: adipic acid isobutyl ester；Monoisobutyl adipate；6-(2-methylpropoxy)-6-oxohexanoic acid
• CAS: 20166-56-7
• 化学式: C₁₀H₁₈O₄
• 分子量: 202.251
• InChiKey: DWAXWYZOQYHMPN-UHFFFAOYSA-N

物化性质

• 沸点：
  309.8±15.0 °C(Predicted)
• 密度：
  1.052±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  己二酸 、 异丁醇 在 Candida antarctica lipase immobilized on polyacrylic resin 作用下， 以 1,4-二氧六环 为溶剂， 反应 3.0h， 生成 hexanedioic acid isobutyl ester 、 己二酸二异丁酯
  参考文献：
  名称：

  Synergism of Microwaves and Immobilized Enzyme Catalysis in Synthesis of Adipic Acid Esters in Nonaqueous Media

  摘要：

  Low-energy microwave irradiation leads to enhancement by a factor of up to 2.63 in comparison with conventional heating in immobilized lipase-catalyzed esterification of adipic acid with various alcohols and this effect is due to the greater frequency of collision, without any change in activation energy of the two modes of heating.

  DOI：

  10.1081/scc-200061687

文献信息

• FUNGICIDAL OR BACTERICIDAL COMPOSITION, AND METHOD FOR CONTROLLING DISEASES
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20170188580A1

  公开（公告）日：2017-07-06

  To provide a novel pesticidal composition, particularly a composition for a fungicide. A fungicidal or bactericidal composition comprising one or more compounds selected from oxime-substituted amide compounds represented by the formula (I), or their N-oxides or salts, and one or more compounds selected from known fungicidal or bactericidal compounds: wherein G 1 represents a structure of G 1 -1, G 1 -27, etc., G 2 represents a structure of G 2 -2, etc., W represents an oxygen atom, etc., X 1 represents difluoromethyl, trifluoromethyl, etc., X 2 , X 3 , X 4 and X 5 each independently represents a hydrogen atom, etc., Y 1 represents a halogen atom, etc., Y 2 represents a hydrogen atom, a halogen atom, etc., Y 3 represents a halogen atom, trifluoromethyl, C 2 -C 6 alkynyl, etc., Y 4 represents a hydrogen atom, etc., R 1 represents C 1 -C 6 alkyl, C 1 -C 4 haloalkyl, etc., R 2 and R 3 each independently represents a hydrogen atom, methyl, etc., R 4 represents a hydrogen atom, etc., and R 5 represents methyl, etc.

  提供一种新型杀虫剂组合物，特别是一种用于杀菌剂的组合物。一种杀真菌或杀菌组合物，包括下式所示的氧肟取代酰胺化合物中选择的一个或多个化合物，或其N-氧化物或盐，以及从已知的杀真菌或杀菌化合物中选择的一个或多个化合物： 其中G1代表G1-1、G1-27等的结构，G2代表G2-2等的结构，W代表氧原子等，X1代表二氟甲基、三氟甲基等，X2、X3、X4和X5分别独立地代表氢原子等，Y1代表卤素原子等，Y2代表氢原子、卤素原子等，Y3代表卤素原子、三氟甲基、C2-C6炔基等，Y4代表氢原子等，R1代表C1-C6烷基、C1-C4卤代烷基等，R2和R3分别独立地代表氢原子、甲基等，R4代表氢原子等，R5代表甲基等。
• EXTERNAL PREPARATION FOR SKIN
  申请人：Ishihara Tatsuya

  公开号：US20130309188A1

  公开（公告）日：2013-11-21

  The present invention has an object to provide an external dermal agent with a sustainable anti-wrinkle action, which has both the action of enhancing the proliferation and differentiation of keratinocytes in the skin and the action of enhancing the collagen production in the skin, and which assists the maintenance and the improvement of tissue structures and physiological functions of the epidermis and the dermis, whereby providing a remarkable skin improvement effect. The present invention solves the above abject by providing an external dermal agent containing α-D-glucopyranosyl-(1→3′)-adenosine and/or α-D-glucopyranosyl-(1→5′)-adenosine as an effective ingredient(s).

  本发明的目的是提供一种具有持续抗皱作用的外用皮肤制剂，该制剂具有促进皮肤角质细胞增殖和分化以及促进皮肤胶原蛋白产生的作用，有助于维持和改善表皮和真皮组织结构和生理功能，从而提供显著的皮肤改善效果。本发明通过提供含有α-D-葡萄糖吡喃糖基-(1→3′)-腺苷和/或α-D-葡萄糖吡喃糖基-(1→5′)-腺苷作为有效成分的外用皮肤制剂来解决上述问题。
• Antifouling coating
  申请人：Nippon Paint Co., Ltd.

  公开号：EP1138725A1

  公开（公告）日：2001-10-04

  An antifouling coating    which comprises a varnish comprised of a metal-containing acrylic resin having, in a side chain thereof, at least one group represented by the following formula (1) : wherein X represents a group of the formula: n represents 0 or 1; Y represents a hydrocarbon group; M represents a metal; m represents an integer equal to [(the valence number of metal M)-1]; A represents an organic acid residue derived from a monobasic acid,    said varnish having a nonvolatile fraction of not less than 40 weight % and a viscosity at 25 °C of not more than 18 poises    and said antifouling coating having a volatile organic compound (VOC) content of not more than 400 g/L.

  一种防污涂料 包括一种清漆，该清漆由含金属的丙烯酸树脂组成，其侧链中至少有一个由下式（1）代表的基团： 其中 X 代表式中的一个基团： n 代表 0 或 1； Y 代表烃基； M 代表金属； m 代表等于[（金属 M 的价数）-1]的整数； A 代表源自单碱基酸的有机酸残基、 所述清漆的不挥发分不小于 40 重量％，25 °C 时的粘度不大于 18 泊斯 所述防污涂层的挥发性有机化合物 (VOC) 含量不超过 400 克/升。
• Solid pesticidal formulation
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1166630A1

  公开（公告）日：2002-01-02

  A solid pesticidal formulation which comprises (a) 0.1 to 75% by weight of a pesticidal active ingredient, (b) 0.3 to 40% by weight of a dispersant, (c) 0.3 to 20% by weight of a wetting agent, (d) 0.1 to 30% by weight of a boron compound selected from boron oxides, borin acids and borates, (e) 0.1 to 95% by weight of a water-soluble carrier and (f) 0.1 to 30% by weight of a smectite that is excellent in preservation stability and can prevent aggregation of formulation, reducing of fluidity, and reducing dispersibility when dilution with water is applied.

  一种固体农药制剂，它包括(a)0.1-75%（按重量计）的农药活性成分，(b)0.3-40%（按重量计）的分散剂，(c)0.3-20%（按重量计）的润湿剂，(d)0.1-30%（按重量计）的选自硼氧化物、硼酸和硼酸盐的硼化合物，(e)0.(f) 0.1 至 30%（按重量计）的具有优良保存稳定性并能防止制剂聚集、降低流动性和在用水稀释时降低分散性的直闪石。
• Acrylic resin and antifouling coating
  申请人：Nippon Paint Co., Ltd.

  公开号：EP1323745A2

  公开（公告）日：2003-07-02

  The present invention has for its object to provide an antifouling coating improved in such a manner that the coating film formed therefrom may retain a steady polishing rate over a long time period and be not ready to develop cracks and other defects, thus exhibiting a excellent long-term antifouling performance. An acrylic resin having at least one group represented by the following general formula (1): (wherein R1, R2 and R3 may be the same or different and each represents a hydrocarbon residue of 1 to 20 carbon atoms) in its side chain and additionally at least one group represented by the following general formula (2): (wherein X is a group represented by the formula: n is equal to 0 or 1; Y represents a hydrocarbon; M represents a divalent metal; and A represents a monobasic organic acid residue)in its side chain.

  本发明的目的是提供一种防污涂层，其改进方式是使由此形成的涂膜可以在很长一段时间内保持稳定的抛光率，并且不会出现裂纹和其他缺陷，从而表现出优异的长期防污性能。 一种丙烯酸树脂，至少具有一个由以下通式（1）代表的基团： (其中 R1、R2 和 R3 可以相同或不同，且各自代表 1 至 20 个碳原子的烃残基）的丙烯酸树脂，另外还具有至少一个由下式通式（2）代表的基团： (其中 X 是由式表示的基团： n等于0或1；Y代表烃；M代表二价金属；A代表单碱基有机酸残基）的侧链。