Phthaloylazid | 50906-29-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phthaloylazid
• 英文别名: Phthalazid；phthaloyl diazide；phthaloyl azide；symm. Phthalsaeure-diazid；phthahydroazide；1,2-Benzenedicarbonyldiazide；benzene-1,2-dicarbonyl azide
• CAS: 50906-29-1
• 化学式: C₈H₄N₆O₂
• 分子量: 216.159
• InChiKey: SEWSAELRCXMQGI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  62.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Phthaloylazid 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Lindemann; Schultheis, Justus Liebigs Annalen der Chemie, 1928, vol. 464, p. 243,245, 249

  摘要：

  DOI：
• 作为产物：
  描述：

  邻苯二甲酰氯 在 sodium azide 、 丙酮 作用下， 生成 Phthaloylazid
  参考文献：
  名称：

  Lindemann; Schultheis, Justus Liebigs Annalen der Chemie, 1928, vol. 464, p. 243,245, 249

  摘要：

  DOI：

文献信息

• Synthetic Ion Channels
  申请人：Yang Dan

  公开号：US20080146513A1

  公开（公告）日：2008-06-19

  Provided herein are self-assembling compounds that can form ion channels in lipid bilayers or cell membranes and ion-channel-forming compositions comprising the self-assembling compounds. Also provided are methods of making and using the ion channels formed from a plurality of molecules of the self-assembling compounds. Further, provided are methods of treating or preventing conditions and diseases that are related to the dysfunction of ion channels, including chloride channels.

  本文提供了能够在脂质双分子层或细胞膜中形成离子通道的自组装化合物，以及包含这些自组装化合物的离子通道形成组合物。还提供了利用由多种分子自组装化合物形成的离子通道的制备和使用方法。此外，还提供了治疗或预防与离子通道功能失调相关的疾病和情况的方法，包括氯离子通道。
• Synthesis and structure of tetranuclear orthometallated Pd(ii) complexes derived from bis-iminophosphoranes
  作者：Raquel Bielsa、Rafael Navarro、Tatiana Soler、Esteban P. Urriolabeitia

  DOI：10.1039/b718108f

  日期：——

  The reaction of Pd(OAc)2 with bis-iminophosphoranes Ph3PNCH2CH2CH2NPPh3 (1a), [C6H4(C(O)NPPh3)2-1,3] (1b) and [C6H4(C(O)NPPh3)2-1,2] (1c), gives the orthopalladated tetranuclear complexes [Pd(µ-Cl)C6H4(PPh2NCH2-κ-C,N)-2}}2CH2]2 (2a) [Pd(µ-OAc)C6H4(PPh2NC(O)-κ-C,N)-2}}2C6H4-1′,3′]2 (2b) and [Pd(µ-OAc)C6H4(PPh2NC(O)-κ-C,N)-2}}2C6H4-1′,2′]2 (2c). The reaction takes place in CH2Cl2 for 1a, but must be performed in glacial acetic acid for 1b and 1c. The process implies in all cases the activation of a C–H bond on a Ph ring of the phosphonium group, with concomitant formation of endo complexes. This is the expected behaviour for 1a, but for 1b and 1c reverses the exo orientation observed in other ketostabilized iminophosphoranes. The influence of the solvent in the orientation of the reaction is discussed. The dinuclear acetylacetonate complexes [Pd(acac-O,O′)C6H4(PPh2NCH2-κ-C,N)-2}}2CH2] (3a), [Pd(acac-O,O′)C6H4(PPh2NC(O)-κ-C,N)-2}}2C6H4-1′,3′] (3b) and [Pd(acac-O,O′)C6H4(PPh2NC(O)-κ-C,N)-2}}2C6H4–1′,2′] (3c) have been obtained from the halide-bridging tetranuclear derivatives. The X-ray crystal structure of [3c·4CHCl3] is also reported.

  Pd(OAc)2 与双亚氨基磷烷 Ph3PNCH2CH2CH2NPPh3 (1a)、[C6H4(C(O)NPPh3)2-1,3] (1b) 和 [C6H4(C(O)NPPh3)2-1,2] (1c)反应，得到正钯化四核配合物 [Pd(µ-Cl)C6H4(PPh2NCH2-κ-C、N)-2}}2CH2]2 (2a) [Pd(µ-OAc)C6H4(PPh2NC(O)-κ-C,N)-2}}2C6H4-1′,3′]2 (2b) 和 [Pd(µ-OAc)C6H4(PPh2NC(O)-κ-C,N)-2}}2C6H4-1′,2′]2 (2c)。1a 的反应在 CH2Cl2 中进行，但 1b 和 1c 的反应必须在冰醋酸中进行。在所有情况下，反应过程都意味着膦基 Ph 环上的 C-H 键被活化，同时形成内络合物。这是 1a 的预期行为，但对于 1b 和 1c，在其他酮稳定亚氨基磷烷中观察到的外向性发生了逆转。本文讨论了溶剂对反应取向的影响。二核乙酰丙酮配合物 [Pd(acac-O,O′)C6H4(PPh2NCH2-κ-C,N)-2}}2CH2] (3a)、[Pd(acac-O,O′)C6H4(PPh2NC(O)-κ-C,N)-2}}2C6H4-1′、3′]（3b）和[Pd(acac-O,O′)C6H4(PPh2NC(O)-κ-C,N)-2}2C6H4-1′,2′]（3c）是从卤桥四核衍生物中得到的。同时还报告了 [3c-4CHCl3] 的 X 射线晶体结构。
• Electroconductive polymer film and method for producing the same
  申请人：MITSUI MINING COMPANY, LIMITED

  公开号：EP0279407A2

  公开（公告）日：1988-08-24

  An electroconductive polyaniline-based resin containing a dopant is cast without using a binder by a film casting method into an electroconductive polymer film having a high strength and an adequate flexibility; in particular, one which has a film thickness of 15 to 100 µm or is formed into a porous film having a large surface area is advantageously used in a secondary cell with a substantial increase in unit capacity of the cell.

  将含有掺杂剂的导电性聚苯胺基树脂不使用粘合剂，通过铸膜方法铸成具有高强度和足够柔韧性的导电性聚合物薄膜；特别是将薄膜厚度为 15 至 100 微米或形成具有较大表面积的多孔薄膜用于二次电池，可显著提高电池的单位容量。
• Method for inhibition of scale and scale inhibiting composition
  申请人：MOBIL OIL CORPORATION

  公开号：EP0459171A1

  公开（公告）日：1991-12-04

  A method for the inhibition of scale deposition on thesurfaces of a well coproducing oil and scale forming brines comprising injecting into the well reservoir an acidic (aqueous) solution at a first pH containing dissolved therein a scale inhibitor, multivalent metal ions, and a heat sensitive pH increasing substance which decomposes at elevated temperatures liberating an alkaline compound such that the solution is inherently heated by the higher ambient reservoir temperature to a temperature at which the alkaline compound is liberated from the heat sensitive substance thus raising the pH of the solution to a point at which a sparingly soluble multivalent metal salt of the scale inhibitor is phase separated from the solution on the porous surfaces of the reservoir rock formation, providing for a slow release of inhibitor into the produced brines when the well is in its production phase.

  一种抑制油井表面水垢沉积的方法，这种油井同时生产石油和形成水垢的盐水，该方法包括向油井储层注入第一pH值的酸性（水）溶液，该溶液中溶解有阻垢剂、多价金属离子、和一种对 pH 值有热敏性的物质，这种物质在高温下分解，释放出一种碱性化合物，从而使溶液被较高的储层环境温度固有地加热到一定温度，在该温度下，碱性化合物从热敏性物质中释放出来，从而使溶液的 pH 值升高到一定程度，在该程度上，阻垢剂的稀溶性多价金属盐与储层岩层多孔表面上的溶液相分离，从而使阻垢剂在油井处于生产阶段时缓慢释放到所生产的盐水中。
• Fahmy,A.F.M.; Elkomy,M.A., Indian Journal of Chemistry, 1975, vol. 13, p. 652 - 654
  作者：Fahmy,A.F.M.、Elkomy,M.A.

  DOI：——

  日期：——