1,3-bis(4-vinylbenzyloxy)benzene | 253882-65-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,3-bis(4-vinylbenzyloxy)benzene
• 英文别名: O,O'-di(4-vinylbenzyl)resorcinol；1,3-Bis[(4-ethenylphenyl)methoxy]benzene；1,3-bis[(4-ethenylphenyl)methoxy]benzene
• CAS: 253882-65-4
• 化学式: C₂₄H₂₂O₂
• 分子量: 342.437
• InChiKey: ROUKPFNNUJNCCC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-氯甲基苯乙烯 、 间苯二酚 在 18-冠醚-6 、 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 12.0h， 以52%的产率得到1,3-bis(4-vinylbenzyloxy)benzene
  参考文献：
  名称：

  Polymerisation vs. grafting in the preparation of polymer-supported aluminium catalysts for the Diels-Alder reaction: The role of the polymeric backbone

  摘要：

  Several polymers containing Al Lewis acids anchored to chiral prolinol moieties have been prepared and studied as catalyst for the Diels-Alder reaction of cyclopentadiene and methacrolein. The chiral fragment has been introduced by grafting and by polymerisation procedures using different crosslinking agents and ratios. All supported catalysts prepared show a good activity, but the polymeric network seems to play it very important role in the determining the selectivity observed. Best results, in terms of enantioselectivity. are obtained when the chiral fragment is introduced through polymerisation of the appropriate chiral monomer, but only when a high crosslinking degree (90% DVB) is used. It is shown that the presence of coordinating atoms in the polymeric backbone is clearly detrimental for the selectivity observed. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00763-2