Pt(η2-C60) | 177651-98-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: Pt(η2-C60)
• CAS: 177651-98-8；1176127-22-2
• 化学式: C₆₀Pt
• 分子量: 915.74
• InChiKey: TZYNSMCKIMMEJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.14
• 重原子数：
  61.0
• 可旋转键数：
  0.0
• 环数：
  33.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Pt(η2-C60) 、 1,3-双(二苯基膦)丙烷 以 四氢呋喃 为溶剂， 以68%的产率得到
  参考文献：
  名称：

  Van Wijnkoop, Maarten; Meidine, Mohamed F.; Avent, Anthony G., Journal of the Chemical Society, Dalton Transactions, 1997, # 4, p. 675 - 677

  摘要：

  DOI：
• 作为产物：
  描述：

  bis(cycloocta-1,5-diene)platinum(0) 、 足球烯 以 甲苯 为溶剂， 以99%的产率得到Pt(η2-C60)
  参考文献：
  名称：

  Van Wijnkoop, Maarten; Meidine, Mohamed F.; Avent, Anthony G., Journal of the Chemical Society, Dalton Transactions, 1997, # 4, p. 675 - 677

  摘要：

  DOI：

文献信息

• Formation of various types of metallofullerenes by laser ablation of externally doped fullerenes C[sub 60]M[sub x] (M=Sm, Pt, Ni, La, Y, and Rh)
  作者：Qingyu Kong、Yifeng Shen、Li Zhao、Jun Zhuang、Shixiong Qian、Yufen Li、Yanghui Lin、Ruifang Cai

  DOI：10.1063/1.1424313

  日期：——

  fullerides C60Mx (M=Sm, Pt, Ni, La, Y, and Rh) by excimer laser ablation-TOF mass spectrometry shows that many kinds of metallofullerenes have been observed in both the positive and negative ionic modes. For C60Mx (M=Sm, Pt, and Ni), the metal atom is incorporated into the network of the fullerene cage to replace one carbon atom of the cage forming substitutional metallofullerene. While in the case

  通过准分子激光烧蚀-TOF质谱法对金属富勒烯C60Mx（M=Sm、Pt、Ni、La、Y和Rh）的光碎裂研究表明，在正离子模式和负离子模式下都观察到了多种金属富勒烯。对于 C60Mx（M=Sm、Pt 和 Ni），金属原子结合到富勒烯笼的网络中以取代笼中的一个碳原子，从而形成取代金属富勒烯。而在金属富勒烯 C60Mx (M=La, Y) 的情况下，已经观察到 La 和 Y 原子封装在富勒烯笼中形成内嵌富勒烯的证据。与上述两种情况不同的是，激光烧蚀铑富勒烯C60Rhx(x≈1)会产生两个序列的含铑富勒烯簇C2nRh和C2n+1Rh(2n=50-62)。在我们对负离子通道中所有金属富勒烯化物的激光烧蚀研究中，观察到富勒烯体系中的奇数全碳簇。总原子数为偶数和奇数的金属富勒烯C2n+1M和C2nM的结构...
• Dehydrogenation of compounds with weakened C-H bonds in the presence of platinum and palladium fullerides
  作者：G. N. Boiko、Yu. M. Shul’ga、O. S. Roshchupkina、A. S. Lobach、N. F. Gol’dshleger

  DOI：10.1134/s1070363207040214

  日期：2007.4

  Coordinated fullerene acts as a hydrogen acceptor in reactions with compounds having weakened C-H bonds (1,4-dihydropyridine and 9,10-dihydroanthracene). Metal fullerides are the dehydrogenation catalysts. They activate the C-H bonds of dihydroanthracene and diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate in positions 9,10 and 1,4, respectively. No activation of norbornane carbon-hydrogen bonds with metal fullerides was observed under mild conditions.
• ——
  作者：N. F. Gol'dshleger、Yu. M. Shul'ga、O. S. Roshchupkina、A. A. Perov、A. V. Okotrub

  DOI：10.1023/a:1012397926736

  日期：——

  9,10-Dihydroanthracene (C14H12) reacts with platinum fulleride Cr,()Pt at 513-623 K under anaerobic conditions to form anthracene and hydrofullerenes identified by IR and mass spectroscopy. The Pt 4f(7/2) binding energy of platinum in the initial fulleride (72.4 eV) indicates partial charge transfer form Pt to C-60, which agrees with the results of X-ray fluorescence spectroscopic study of C60Pt.
• Measurement of third-order optical nonlinearity of C60M2 (M=Pd, Pt, and Sm) organometallic compounds by the femtosecond optically heterodyned optical Kerr effect
  作者：Wei Qian、Li Lin、Zongju Xia、Yinghua Zou、Shixiong Qian、Guohong Ma、Yanghui Lin、Ruifang Cai、Yu Chen、Zu-En Huang

  DOI：10.1016/s0009-2614(00)00074-9

  日期：2000.3

  We have measured the real components of the third-order optical nonlinearity of organometallic compound films of C60M2 (M = Pd, Pt, and Sm) by using the femtosecond optically heterodyned optical Kerr effect at 647.0 nm. The results show that there is an enhancement of the real components of the third-order optical nonlinearity of C60M2 films compared to that of pristine C-60 film. We attribute the origin of this enhancement to the charge transfer from the metal atoms to the C-60 molecules. (C) 2000 Elsevier Science B.V. All rights reserved.