2-methylacrylic acid 2-[3-(3-{2-[2-(3-trifluoromethanesulfonylaminopropoxy)ethoxy]ethoxy}propyl)ureido]ethyl ester | 1110783-62-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: 2-methylacrylic acid 2-[3-(3-{2-[2-(3-trifluoromethanesulfonylaminopropoxy)ethoxy]ethoxy}propyl)ureido]ethyl ester
• 英文别名: 2-[3-[2-[2-[3-(Trifluoromethylsulfonylamino)propoxy]ethoxy]ethoxy]propylcarbamoylamino]ethyl 2-methylprop-2-enoate；2-[3-[2-[2-[3-(trifluoromethylsulfonylamino)propoxy]ethoxy]ethoxy]propylcarbamoylamino]ethyl 2-methylprop-2-enoate
• CAS: 1110783-62-4
• 化学式: C₁₈H₃₂F₃N₃O₈S
• 分子量: 507.529
• InChiKey: KPDIGGOXAOLJOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  33
• 可旋转键数：
  20
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  150
• 氢给体数：
  3
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  2-methylacrylic acid 2-[3-(3-{2-[2-(3-trifluoromethanesulfonylaminopropoxy)ethoxy]ethoxy}propyl)ureido]ethyl ester 、 1-乙基-3-甲基溴化咪唑 在 lithium hydride 、 对苯二酚 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以90%的产率得到
  参考文献：
  名称：

  Synthesis, polymerization and conducting properties of an ionic liquid-type anionic monomer

  摘要：

  The synthesis of a new ionic liquid-type monomer has been performed by association of a methacrylate polymerizable group, a polar tri(ethylene oxide) (TEO) spacer, a trifluoromethane sulfonic (TFSI-) anion and a free imidazolium (EMIm(+)) cation. The ionic liquid monomer (ILM) has demonstrated a good thermal stability and a high ionic conductivity around 2.1 X 10(-3) S cm(-1) at 20 degrees C. The corresponding homopolymer has shown an ionic conductivity closely related to the monomer (6.5 x 10(-4) S cm(-1) at 20 degrees C, which confirms the ILM as a valuable monomer for the formation of polymeric ionic liquid (PIL) materials. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.10.096
• 作为产物：
  描述：

  甲基丙烯酸异氰基乙酯 、 N-(3-{2-[2-(3-aminopropoxy)ethoxy]ethoxy}propyl)-trifluoromethanesulfonamide 在 对苯二酚 作用下， 以 氯仿 为溶剂， 反应 48.5h， 以79%的产率得到2-methylacrylic acid 2-[3-(3-{2-[2-(3-trifluoromethanesulfonylaminopropoxy)ethoxy]ethoxy}propyl)ureido]ethyl ester
  参考文献：
  名称：

  Synthesis, polymerization and conducting properties of an ionic liquid-type anionic monomer

  摘要：

  The synthesis of a new ionic liquid-type monomer has been performed by association of a methacrylate polymerizable group, a polar tri(ethylene oxide) (TEO) spacer, a trifluoromethane sulfonic (TFSI-) anion and a free imidazolium (EMIm(+)) cation. The ionic liquid monomer (ILM) has demonstrated a good thermal stability and a high ionic conductivity around 2.1 X 10(-3) S cm(-1) at 20 degrees C. The corresponding homopolymer has shown an ionic conductivity closely related to the monomer (6.5 x 10(-4) S cm(-1) at 20 degrees C, which confirms the ILM as a valuable monomer for the formation of polymeric ionic liquid (PIL) materials. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.10.096

文献信息

• Synthesis, polymerization and conducting properties of an ionic liquid-type anionic monomer
  作者：Jonathan Juger、Franck Meyer、Frédéric Vidal、Claude Chevrot、Dominique Teyssié

  DOI：10.1016/j.tetlet.2008.10.096

  日期：2009.1

  The synthesis of a new ionic liquid-type monomer has been performed by association of a methacrylate polymerizable group, a polar tri(ethylene oxide) (TEO) spacer, a trifluoromethane sulfonic (TFSI-) anion and a free imidazolium (EMIm(+)) cation. The ionic liquid monomer (ILM) has demonstrated a good thermal stability and a high ionic conductivity around 2.1 X 10(-3) S cm(-1) at 20 degrees C. The corresponding homopolymer has shown an ionic conductivity closely related to the monomer (6.5 x 10(-4) S cm(-1) at 20 degrees C, which confirms the ILM as a valuable monomer for the formation of polymeric ionic liquid (PIL) materials. (C) 2008 Elsevier Ltd. All rights reserved.