1-(3,4-dioctoxyphenyl)-N-(4-octoxyphenyl)methanimine | 1321194-80-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-(3,4-dioctoxyphenyl)-N-(4-octoxyphenyl)methanimine
• CAS: 1321194-80-2
• 化学式: C₃₇H₅₉NO₃
• 分子量: 565.88
• InChiKey: QODCWRFEWBCQJD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.4
• 重原子数：
  41
• 可旋转键数：
  26
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  40
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-辛氧基苯胺 、 3,4-(二辛基氧)苯甲醛 在 溶剂黄146 作用下， 以 乙醇 为溶剂， 以55%的产率得到1-(3,4-dioctoxyphenyl)-N-(4-octoxyphenyl)methanimine
  参考文献：
  名称：

  Dinuclear ortho-Metallated Palladium(II) Complexes with Acetato and Chloro Bridges as Liquid Crystals

  摘要：

  In this article we present the preparation and the investigation of the liquid crystal properties of a series of dinuclear acetato- and chloro-bridged ortho-metallated Pd(II) complexes bearing six alkoxy peripheral chains in the molecule. Their structures were assigned based on elemental analysis, Infrared (IR), and 1H and 13C nuclear magnetic resonance (NMR) spectroscopy, whereas the thermal behavior was investigated by polarizing optical microscopy and differential scanning calorimetry. All these complexes show mesomorphic behavior with smectic A phases being displayed. The acetato complexes exhibit a monotropic smectic A phase with transition temperatures from the isotropic state depending on the alkyl chain lengths, whereas the chloro complexes decompose on melting from the crystalline state to an SmA phase.

  DOI：

  10.1080/15421406.2011.536473

文献信息

• Dinuclear <i>ortho</i>-Metallated Palladium(II) Complexes with Acetato and Chloro Bridges as Liquid Crystals
  作者：Viorel Cîrcu、Florea Dumitraşcu

  DOI：10.1080/15421406.2011.536473

  日期：2011.1.13

  In this article we present the preparation and the investigation of the liquid crystal properties of a series of dinuclear acetato- and chloro-bridged ortho-metallated Pd(II) complexes bearing six alkoxy peripheral chains in the molecule. Their structures were assigned based on elemental analysis, Infrared (IR), and 1H and 13C nuclear magnetic resonance (NMR) spectroscopy, whereas the thermal behavior was investigated by polarizing optical microscopy and differential scanning calorimetry. All these complexes show mesomorphic behavior with smectic A phases being displayed. The acetato complexes exhibit a monotropic smectic A phase with transition temperatures from the isotropic state depending on the alkyl chain lengths, whereas the chloro complexes decompose on melting from the crystalline state to an SmA phase.