2,7'-di-3,4-diazafluorenone-9,9'-spirobifluorene | 1231916-64-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 2,7'-di-3,4-diazafluorenone-9,9'-spirobifluorene
• 英文别名: 3-[2'-(5-Oxoindeno[1,2-c]pyridazin-3-yl)-9,9'-spirobi[fluorene]-2-yl]indeno[1,2-c]pyridazin-5-one；3-[2'-(5-oxoindeno[1,2-c]pyridazin-3-yl)-9,9'-spirobi[fluorene]-2-yl]indeno[1,2-c]pyridazin-5-one
• CAS: 1231916-64-5
• 化学式: C₄₇H₂₄N₄O₂
• 分子量: 676.733
• InChiKey: FEZUTEBMTPHEDF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  53
• 可旋转键数：
  2
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.02
• 拓扑面积：
  85.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,7'-di-3,4-diazafluorenone-9,9'-spirobifluorene 、 biphenyl-2-yl-lithium 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of Diaza-Analogue of Fluorenone and Spirobifluorene

  摘要：

  The effective syntheses of diaza-analogue of fluorenone and spirobifluorene with N=N bond has been conducted with the using of ninhydrin and corresponding acetyl derivatives of arenes. Single-crystal X-ray diffraction of 2-(spirobifluoren-2-yl)- 3,4-dizaspirobifluorene (4a) proved the conformation.

  DOI：

  10.3987/com-09-11898
• 作为产物：
  描述：

  9,9'-螺二芴 在 二硫化碳 、 aluminum (III) chloride 、 一水合肼 、 溶剂黄146 作用下， 生成 2,7'-di-3,4-diazafluorenone-9,9'-spirobifluorene
  参考文献：
  名称：

  Synthesis of Diaza-Analogue of Fluorenone and Spirobifluorene

  摘要：

  The effective syntheses of diaza-analogue of fluorenone and spirobifluorene with N=N bond has been conducted with the using of ninhydrin and corresponding acetyl derivatives of arenes. Single-crystal X-ray diffraction of 2-(spirobifluoren-2-yl)- 3,4-dizaspirobifluorene (4a) proved the conformation.

  DOI：

  10.3987/com-09-11898

文献信息

• Synthesis of Diaza-Analogue of Fluorenone and Spirobifluorene
  作者：Qian-Cai Liu、Jie Tang

  DOI：10.3987/com-09-11898

  日期：——

  The effective syntheses of diaza-analogue of fluorenone and spirobifluorene with N=N bond has been conducted with the using of ninhydrin and corresponding acetyl derivatives of arenes. Single-crystal X-ray diffraction of 2-(spirobifluoren-2-yl)- 3,4-dizaspirobifluorene (4a) proved the conformation.