1-p-tolylamino-,2,3,4,5,5-pentamethoxycarbonylcyclopentadiene | 122630-52-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1-p-tolylamino-,2,3,4,5,5-pentamethoxycarbonylcyclopentadiene
• 英文别名: Pentamethyl 5-(4-methylanilino)cyclopenta-2,4-diene-1,1,2,3,4-pentacarboxylate
• CAS: 122630-52-8
• 化学式: C₂₂H₂₃NO₁₀
• 分子量: 461.425
• InChiKey: VHDFHFDQNLWNOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  33
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  144
• 氢给体数：
  1
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  5-bromo-1,2,3,4,5-pentamethoxycarbonylcyclopentadiene 、 Ag(di-p-tolyltriazine) 以 苯 为溶剂， 以80%的产率得到1-p-tolylamino-,2,3,4,5,5-pentamethoxycarbonylcyclopentadiene
  参考文献：
  名称：

  Mikhailov, I.E.; Dushenko, G.A., Russian Journal of Organic Chemistry, 1989, vol. 25, # 1.2, p. 185 - 186

  摘要：

  DOI：

文献信息

• CATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND CATALYST CONTAINING CATALYST COMPONENT AND USE THEREOF
  申请人：Beijing Lihe Technology Ltd.

  公开号：US20170088642A1

  公开（公告）日：2017-03-30

  A catalyst component for olefin polymerization, comprising Mg, Ti, a halogen and an electron donor, wherein the electron donor is at least one unsaturated ring-substituted diacid ester compound. Also provided is a catalyst containing the catalyst component and the use of the catalyst in an olefin polymerization, e.g., propylene polymerization.

  一种用于烯烃聚合的催化剂组分，包括Mg、Ti、卤素和电子给体，其中电子给体至少为一种不饱和环取代二酸酯化合物。还提供了含有该催化剂组分的催化剂以及在烯烃聚合中使用该催化剂，例如丙烯聚合。
• MIXAJLOV, I. E.;DUSHENKO, G. A., ZH. ORGAN. XIMII, 25,(1989) N 1, S. 203-204
  作者：MIXAJLOV, I. E.、DUSHENKO, G. A.

  DOI：——

  日期：——
• OLEFIN POLYMERIZATION CATALYST CARRIER, SOLID CATALYST COMPONENT AND USE THEREOF
  申请人：Renqiu Lihe Technology Ltd.

  公开号：US20190169328A1

  公开（公告）日：2019-06-06

  A method of making an olefin polymerization catalyst carrier with a general structure formula of Mg(OR I ) n (OR II ) 2-n , wherein: 0≤n≤2, and R I and R II can be the same or different and are each independently selected from a C 1 -C 20 hydrocarbon group by reacting an alcohol with a metal magnesium powder under the protection of nitrogen in the presence of a halogen or a halogen-containing compound to obtain a first product, and subjecting the product to a treatment pressure of from 0.2 to 5.0 MPa at a treatment temperature of from 80 to 200° C. for a duration of between 2 minutes and 6 hours. Also provided is a method of making an olefin polymerization solid catalyst component which includes the catalyst carrier, a titanium compound, and at least one electron donor compound.
• Mikhailov, I.E.; Dushenko, G.A., Russian Journal of Organic Chemistry, 1989, vol. 25, # 1.2, p. 185 - 186
  作者：Mikhailov, I.E.、Dushenko, G.A.

  DOI：——

  日期：——