N-phenyl-1-[2-[[1-(3-triethoxysilylpropyl)triazol-4-yl]methoxy]phenyl]methanimine | 1548801-73-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: N-phenyl-1-[2-[[1-(3-triethoxysilylpropyl)triazol-4-yl]methoxy]phenyl]methanimine
• CAS: 1548801-73-5
• 化学式: C₂₅H₃₄N₄O₄Si
• 分子量: 482.655
• InChiKey: QIBKIALJZLOFEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.05
• 重原子数：
  34
• 可旋转键数：
  15
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  80
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  3-氯丙基三乙氧基硅烷 在 sodium azide 、 溴化三(三苯基磷)铜 、 三乙胺 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 19.0h， 生成 N-phenyl-1-[2-[[1-(3-triethoxysilylpropyl)triazol-4-yl]methoxy]phenyl]methanimine
  参考文献：
  名称：

  Synthesis of polyfunctional triethoxysilanes by ‘click silylation’

  摘要：

  The copper-catalyzed 'click silylation' has been exploited for the chemical modification of gamma-azidopropyltriethoxysilane (AzPTES) with a wide range of terminal alkynes (la-lv) in a one-pot operation. The novel 1,2,3-triazole-triethoxysilane derivatives (2a-2v) were synthesized by this procedure and comprehensively characterized by IR spectra, H-1 and C-13 NMR, and HRMS studies. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.12.037

文献信息

• Synthesis of polyfunctional triethoxysilanes by ‘click silylation’
  作者：Gurjaspreet Singh、Satinderpal Singh Mangat、Jandeep Singh、Aanchal Arora、Ramesh K. Sharma

  DOI：10.1016/j.tetlet.2013.12.037

  日期：2014.1

  The copper-catalyzed 'click silylation' has been exploited for the chemical modification of gamma-azidopropyltriethoxysilane (AzPTES) with a wide range of terminal alkynes (la-lv) in a one-pot operation. The novel 1,2,3-triazole-triethoxysilane derivatives (2a-2v) were synthesized by this procedure and comprehensively characterized by IR spectra, H-1 and C-13 NMR, and HRMS studies. (C) 2013 Elsevier Ltd. All rights reserved.