Tert-butyl 2-[5-tert-butyl-2-methoxy-3-[1-[(2-methylpropan-2-yl)oxycarbonyl]pyrrol-2-yl]phenyl]pyrrole-1-carboxylate | 1170252-03-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Tert-butyl 2-[5-tert-butyl-2-methoxy-3-[1-[(2-methylpropan-2-yl)oxycarbonyl]pyrrol-2-yl]phenyl]pyrrole-1-carboxylate
• CAS: 1170252-03-5
• 化学式: C₂₉H₃₈N₂O₅
• 分子量: 494.631
• InChiKey: BFKUTDGAGSJUGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  71.7
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  Tert-butyl 2-[5-tert-butyl-2-methoxy-3-[1-[(2-methylpropan-2-yl)oxycarbonyl]pyrrol-2-yl]phenyl]pyrrole-1-carboxylate 在 三溴化硼 、 碳酸氢钠 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 1.17h， 生成 4-tert-butyl-2,6-bis(1H-pyrrol-2-yl)phenol
  参考文献：
  名称：

  CYCLIC COMPOUND, ITS METAL COMPLEX, AND MODIFIED METAL COMPLEX

  摘要：

  公开号：

  EP2239263B1
• 作为产物：
  描述：

  1-N-Boc-pyrrole-2-boronic acid 、 1,3-二溴-5-叔丁基-2-甲氧基苯 在 2-双环己基膦-2',6'-二甲氧基联苯 、 tris-(dibenzylideneacetone)dipalladium(0) potassium dihydrogenphosphate 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 9.0h， 生成 Tert-butyl 2-[5-tert-butyl-2-methoxy-3-[1-[(2-methylpropan-2-yl)oxycarbonyl]pyrrol-2-yl]phenyl]pyrrole-1-carboxylate
  参考文献：
  名称：

  CYCLIC COMPOUND, ITS METAL COMPLEX, AND MODIFIED METAL COMPLEX

  摘要：

  公开号：

  EP2239263B1

文献信息

• CATHODE CATALYST FOR AIR SECONDARY BATTERY AND AIR SECONDARY BATTERY
  申请人：Koshino Nobuyoshi

  公开号：US20140066290A1

  公开（公告）日：2014-03-06

  The present invention provides a cathode catalyst for an air secondary cell having both excellent oxygen reduction activity and excellent water oxidation activity, and an air secondary cell that uses the catalyst. The present invention relates to a cathode catalyst for an air secondary cell in which the catalyst contains a polynuclear metal complex.

  本发明提供了一种空气二次电池的阴极催化剂，具有优异的氧还原活性和优异的水氧化活性，并且使用该催化剂的空气二次电池。本发明涉及一种空气二次电池的阴极催化剂，其中该催化剂包含多核金属配合物。
• CYCLIC COMPOUND, ITS METAL COMPLEX AND MODIFIED METAL COMPLEX
  申请人：Matsunaga Tadafumi

  公开号：US20110015059A1

  公开（公告）日：2011-01-20

  A compound represented by formula (1): wherein Y 1 to Y 4 each independently represent any one of the following groups: in which R α represents a hydrogen atom or a monovalent hydrocarbon group; P 1 to P 4 each independently represent a group of atoms necessary for forming a heterocyclic ring together with each of Y 1 to Y 4 and the two carbon atoms adjacent to each of Y 1 to Y 4 , respectively; P 5 and P 6 each independently represent a group of atoms necessary for forming a cyclic skeleton together with the carbon atom to which Z 1 bonds or Z 2 bonds and the two carbon atoms adjacent to the carbon atom to which Z 1 bonds or Z 2 bonds; P 1 and P 2 , P 2 and P 6 , P 6 and P 4 , P 4 and P 3 , P 3 and P 5 , and P 5 and P 1 may further combine with each other to form a ring; Q 1 and Q 2 each independently represent a connecting group or a direct binding; and Z 1 and Z 2 each independently represent any one of the following groups; —NR β 2 , —OR β , —SR β , —PR β 2 in which R β represents a hydrogen atom or a monovalent hydrocarbon group, and when plural R β s are present, these plural R β s may be the same or different from each other.
• US8546291B2
  申请人：——

  公开号：US8546291B2

  公开（公告）日：2013-10-01
• US9236613B2
  申请人：——

  公开号：US9236613B2

  公开（公告）日：2016-01-12
• CYCLIC COMPOUND, ITS METAL COMPLEX, AND MODIFIED METAL COMPLEX
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2239263B1

  公开（公告）日：2014-01-15