(2R,6S)-4-[4-[11-(2,6-dimethylphenyl)sulfanyl-1',1'-diethyl-10-methoxy-5-(4-methoxyphenyl)spiro[6-oxapentacyclo[12.7.0.02,7.08,13.015,20]henicosa-1(14),2(7),3,8,10,12,15,17,19-nonaene-21,4'-cyclohexane]-5-yl]phenyl]-2,6-dimethylmorpholine

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• 英文名称: (2R,6S)-4-[4-[11-(2,6-dimethylphenyl)sulfanyl-1',1'-diethyl-10-methoxy-5-(4-methoxyphenyl)spiro[6-oxapentacyclo[12.7.0.02,7.08,13.015,20]henicosa-1(14),2(7),3,8,10,12,15,17,19-nonaene-21,4'-cyclohexane]-5-yl]phenyl]-2,6-dimethylmorpholine
• 化学式: C₅₇H₆₁NO₄S
• 分子量: 856.182
• InChiKey: OJAJYBDHFAYACM-XWXRRGIBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.7
• 重原子数：
  63
• 可旋转键数：
  9
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  65.5
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• CHROMENE COMPOUND AND CURABLE COMPOSITION
  申请人：TOKUYAMA CORPORATION

  公开号：US20140225050A1

  公开（公告）日：2014-08-14

  A chromene compound which has a sulfur-containing substituent represented by the following formula (2) at the 6-position and/or 7-position carbon atom of an indeno (2,1-f)naphtho(1,2-b)pyran structure and is excellent in photochromic properties and stability at a high temperature. (In the above formula, ring X is an aromatic hydrocarbon ring or aromatic heterocyclic ring, R 3 and R 4 are each independently an alkyl group, haloalkyl group, cycloalkyl group, alkoxy group, amino group, heterocyclic group containing a ring member nitrogen atom and bonded to the ring X bonded thereto via the nitrogen atom, halogen atom, aryloxy group or aryl group, and “a” is an integer of 0 to 4.)

  一种含有硫取代基的色烯化合物，其在indeno（2,1-f）naphtho（1,2-b）pyran结构的6-位和/或7-位碳原子处，用以下式子（2）表示，并且具有优异的光致变色性能和高温稳定性。（在上述式子中，环X是芳香族烃环或芳香族杂环环，R3和R4各自独立地是烷基，卤代烷基，环烷基，烷氧基，氨基，含有环成员氮原子并通过氮原子与环X结合的杂环基，卤素原子，芳氧基或芳基，而“a”是0到4的整数。）
• PHOTOCHROMIC CURABLE COMPOSITION, CURED PRODUCT THEREOF AND LAMINATE INCLUDING THE CURED PRODUCT
  申请人：TOKUYAMA CORPORATION

  公开号：US20160002524A1

  公开（公告）日：2016-01-07

  A curable composition which comprises a carbonate-based polymerizable monomer represented by the following formula, other polymerizable monomers and a photochromic compound, can be used even under high-temperature and high-humidity conditions without any problems and provides a cured product having excellent photochromic properties. wherein A and A′ are each a linear or branched alkylene group having 2 to 15 carbon atoms, “a” is an average value of 1 to 20, when there are a plurality of A's, A's may be the same or different, R 1 is a hydrogen atom or methyl group, and R 2 is a (meth)acryloyloxy group or hydroxyl group.

  可治愈组合物包括以下化学式所表示的碳酸酯基可聚合单体、其他可聚合单体和光致变色化合物，即使在高温高湿环境下也可以使用，而且提供具有出色光致变色性能的固化产物。其中，A和A'是具有2至15个碳原子的线性或支链烷基，"a"是1至20的平均值，当有多个A时，A可以相同或不同，R1是氢原子或甲基基团，R2是（甲基）丙烯酰氧基团或羟基。
• PHOTOCHROMIC CURABLE COMPOSITION
  申请人：Tokuyama Corporation

  公开号：EP3020734A1

  公开（公告）日：2016-05-18

  A photochromic curable composition comprising (A) a polymerizable monomer component that contains a (meth)acrylic polymerizable monomer (X), and (B) a photochromic compound, wherein the (meth)acrylic polymerizable monomer (X) is constituted by 80 to 97 parts by mass of a polyfunctional monomer (Xp) having not less than two (meth) acrylic groups in a molecule thereof, and 3 to 20 parts by mass of a monofunctional monomer (Xm) having one (meth) acrylic group in a molecule thereof, the monofunctional polymerizable monomer (Xm) is constituted by an epoxy group-containing monomer (Xm1) and an isocyanate group-containing monomer (Xm2), and the isocyanate group-containing monomer (Xm2) and the epoxy group-containing monomer (Xm1) are contained at a mass ratio of Xm2/Xm1 = 3 to 40.

  一种光致变色可固化组合物，包括(A)含有(甲基)丙烯酸可聚合单体(X)的可聚合单体组分，以及(B)光致变色化合物，其中(甲基)丙烯酸可聚合单体(X)由 80 至 97 份（按质量份）的多官能团单体(Xp)构成，在其分子中具有不少于两个(甲基)丙烯酸基团、单官能团可聚合单体（Xm）由 3 至 20 份（质量分数）的含环氧基单体 （Xm1）和含异氰酸酯基单体（Xm2）构成，而含异氰酸酯基单体（Xm2）和含环氧基单体 （Xm1）的质量分数分别为 80 至 97 份（质量分数）和 3 至 20 份（质量分数）的含一 个（甲基）丙烯酸基团的单官能团单体（Xm）构成。 含异氰酸酯基团单体（Xm2）和含环氧基团单体（Xm1）的质量比为 Xm2/Xm1 = 3 至 40。
• Photocurable resin composition
  申请人：TOKUYAMA CORPORATION

  公开号：US10884334B2

  公开（公告）日：2021-01-05

  To provide a photocurable resin composition comprising an N-vinyl amide compound, a polyfunctional (meth)acrylate monomer and a photopolymerization initiator and having excellent adhesion to an optical substrate and free from an appearance defect such as a crack or shrinkage and a laminate having a coat layer obtained by curing the photocurable resin composition.

  提供一种光固化树脂组合物，该组合物由 N-乙烯基酰胺化合物、多官能度（甲基）丙烯酸酯单体和光聚合引发剂组成，与光学基板具有良好的粘附性，且无裂纹或收缩等外观缺陷，还提供一种具有通过固化该光固化树脂组合物而获得的涂层的层压板。
• US8916071B2
  申请人：——

  公开号：US8916071B2

  公开（公告）日：2014-12-23