1,2,7-trimethyl-2,7-dihydro-1H-diindolo[2,3-a:2,3-c]carbazole | 75833-83-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 1,2,7-trimethyl-2,7-dihydro-1H-diindolo[2,3-a:2,3-c]carbazole
• 英文别名: N,N-Dimethyl-diindole[3,2-a;2,3-c]N-methylcarbazole；9,18,21-trimethyl-9,18,21-triazaheptacyclo[18.7.0.02,10.03,8.011,19.012,17.022,27]heptacosa-1,3,5,7,10,12,14,16,19,22,24,26-dodecaene
• CAS: 75833-83-9
• 化学式: C₂₇H₂₁N₃
• 分子量: 387.484
• InChiKey: ZXUCNYSYYPJAGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  30
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  14.8
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  乙酸-N-甲基吲哚氧基酯 在 三氟乙酸 作用下， 反应 2.0h， 以48%的产率得到1,2,7-trimethyl-2,7-dihydro-1H-diindolo[2,3-a:2,3-c]carbazole
  参考文献：
  名称：

  三吲哚苯及其相关化合物的合成与研究

  摘要：

  不对称的N，N，N-三甲基三吲哚苯3已经通过几种途径合成，包括吲哚的O-乙酸酯的环三聚。该冷凝涉及原位形成的前体的3→2重排。类似的Wagner-Meerwein重排在LAH还原3,3-二吲哚基羟吲哚中也很普遍。

  DOI：

  10.1016/0040-4020(80)85060-5

文献信息

• Palladium-catalysed decarboxylative nitrile insertion via C–H activation or self-coupling of indole-2-carboxylic acids: a new route to indolocarbolines and triindoles
  作者：R. N. Prasad Tulichala、K. C. Kumara Swamy

  DOI：10.1039/c5cc03160e

  日期：——

  Palladium catalysed-reaction of indole carboxylic acids with nitriles in the presence of Ag2CO3 proceeds via decarboxylative dual C-H activation leading to the nitrile insertion products, triazaindeno-fluorenes (indolocarbolines); in the absence...

  在Ag2CO3存在下，吲哚羧酸与腈的钯催化反应通过脱羧双CH活化进行，从而产生腈插入产物三氮杂茚基芴（吲哚并咔啉）；离席期间...
• Hydrogen storage by reversible hydrogenation of pi-conjugated substrates
  申请人：Pez Peter Guido

  公开号：US20050002857A1

  公开（公告）日：2005-01-06

  Processes are provided for the storage and release of hydrogen by means of a substantially reversible catalytic hydrogenation of extended pi-conjugated substrates which include large polycyclic aromatic hydrocarbons, polycyclic aromatic hydrocarbons with nitrogen heteroatoms, polycyclic aromatic hydrocarbons with oxygen heteroatoms, polycyclic aromatic hydrocarbons with alkyl, alkoxy, nitrile, ketone, ether or polyether substituents, pi-conjugated molecules comprising 5 membered rings, pi-conjugated molecules comprising six and five membered rings with nitrogen or oxygen hetero atoms, and extended pi-conjugated organic polymers. The hydrogen, contained in the at least partially hydrogenated form of the extended pi-conjugated system, can be facilely released for use by a catalytic dehydrogenation of the latter in the presence of a dehydrogenation catalyst which can be effected by lowering the hydrogen gas pressure, generally to pressures greater than 0.1 bar or raising the temperature to less than 250° C. or less, or by a combination of these two process parameters.

  本发明提供了通过对扩展的π-共轭基质进行基本可逆的催化加氢来储存和释放氢气的工艺、具有烷基、烷氧基、腈基、酮基、醚基或聚醚基取代基的多环芳香烃，由 5 个成员环组成的π-共轭分子，由具有氮或氧杂质原子的 6 个和 5 个成员环组成的π-共轭分子，以及扩展的π-共轭有机聚合物。扩展π-共轭体系的至少部分氢化形式中含有的氢，可以在脱氢催化剂的存在下，通过催化脱氢反应方便地释放出来，脱氢反应可以通过降低氢气压力（一般压力大于 0.1 巴）或将温度升高到低于 250 摄氏度或更低，或通过这两种工艺参数的组合来实现。
• Dehydrogenation of liquid fuel in microchannel catalytic reactor
  申请人：Toseland Allen Bernard

  公开号：US20060143981A1

  公开（公告）日：2006-07-06

  The present invention is an improved process for the storage and delivery of hydrogen by the reversible hydrogenation/dehydrogenation of an organic compound wherein the organic compound is initially in its hydrogenated state. The improvement in the route to generating hydrogen is in the dehydrogenation step and recovery of the dehydrogenated organic compound resides in the following steps: introducing a hydrogenated organic compound to a microchannel reactor incorporating a dehydrogenation catalyst; effecting dehydrogenation of said hydrogenated organic compound under conditions whereby said hydrogenated organic compound is present as a liquid phase; generating a reaction product comprised of a liquid phase dehydrogenated organic compound and gaseous hydrogen; separating the liquid phase dehydrogenated organic compound from gaseous hydrogen; and, recovering the hydrogen and liquid phase dehydrogenated organic compound.

  本发明是一种通过有机化合物的可逆氢化/脱氢来储存和输送氢气的改进工艺，其中有机化合物最初处于氢化状态。氢气生成路线的改进在于脱氢步骤和脱氢有机化合物的回收，具体步骤如下：将氢化有机化合物引入含有脱氢催化剂的微通道反应器；在所述氢化有机化合物以液相形式存在的条件下对所述氢化有机化合物进行脱氢；生成由液相脱氢有机化合物和气态氢组成的反应产物；将液相脱氢有机化合物与气态氢分离；以及回收氢和液相脱氢有机化合物。
• Carloni, Patricia; Greci, Leonardio; Iacussi, Marco, Journal of Chemical Research, Miniprint, 1996, # 8, p. 1924 - 1945
  作者：Carloni, Patricia、Greci, Leonardio、Iacussi, Marco、Rossetti, Monica、Stipa, Pierluigi、et al.

  DOI：——

  日期：——
• BERGMAN J.; EKLUND N., TETRAHEDRON, 1980, 36, NO 10, 1445-1450
  作者：BERGMAN J.、 EKLUND N.

  DOI：——

  日期：——