1,3,4-Tris(prop-2-enyl)imidazol-1-ium;iodide

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1,3,4-Tris(prop-2-enyl)imidazol-1-ium;iodide
• 英文别名: 1,3,4-tris(prop-2-enyl)imidazol-1-ium;iodide
• 化学式: C12H17IN2
• 分子量: 316.18
• InChiKey: MCUZKCSKEQRQFB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.12
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  8.8
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Process for the co-production of acetic acid and acetic anhydride
  申请人：Ineos Acetyls UK Limited

  公开号：US10988432B2

  公开（公告）日：2021-04-27

  Continuous process for co-production of acetic acid and acetic anhydride by contacting carbon monoxide with a liquid reaction composition containing methyl acetate, dimethyl ether or a mixture thereof, a Group VIII metal catalyst, methyl iodide, acetic acid, acetic anhydride, and water in a concentration of 0.1 wt % or less, withdrawing liquid reaction composition from the reaction zone, introducing at least a portion thereof into a flash separation zone, and removing from the flash separation zone a vapor fraction containing acetic anhydride, acetic acid and methyl iodide and a liquid fraction containing acetic anhydride, and Group VIII metal catalyst. The liquid reaction composition and the withdrawn liquid reaction composition introduced into the flash separation zone contains a Group IA and/or Group IIA metal salt and the molar ratio of acetic acid to acetic anhydride in the vapor fraction removed from the flash separation zone is greater than or equal to 1.

  联合生产醋酸和醋酐的连续工艺 将一氧化碳与含有醋酸甲酯、二甲醚或其混合物、第 VIII 族金属催化剂、碘甲烷、醋酸、醋酐和浓度为 0.1 wt % 或更低，从反应区抽出液体反应组合物，将其中至少一部分引入闪蒸分离区，并从闪蒸分离区除去含有醋酸酐、醋酸和甲基碘的蒸气馏分以及含有醋酸酐和 VIII 族金属催化剂的液体馏分。引入闪蒸分离区的液体反应组合物和抽出的液体反应组合物含有IA族和/或IIA族金属盐，从闪蒸分离区抽出的蒸气馏分中乙酸与乙酸酐的摩尔比大于或等于1。
• PROCESS
  申请人：BP Chemicals Limited

  公开号：EP2964602A2

  公开（公告）日：2016-01-13
• [EN] PROCESS<br/>[FR] PROCÉDÉ
  申请人：BP CHEM INT LTD

  公开号：WO2014135664A2

  公开（公告）日：2014-09-12

  A continuous process for the co-production of acetic acid and acetic anhydride by (a) contacting carbon monoxide with a liquid reaction composition comprising methyl acetate, dimethyl ether or a mixture thereof, a Group VIII metal catalyst, methyl iodide, acetic acid, acetic anhydride, water in a concentration of 0.1 wt% or less, (b) withdrawing liquid reaction composition from the reaction zone and introducing at least a portion of the withdrawn liquid reaction composition into a flash separation zone, and (c) removing from the flash separation zone a vapour fraction comprising acetic anhydride, acetic acid and methyl iodide and a liquid fraction comprising acetic anhydride, and Group VIII metal catalyst in which at least one of the liquid reaction composition and the withdrawn liquid reaction composition introduced into the flash separation zone comprises at least one metal salt selected from salts of Group IA and Group IIA metals and the molar ratio of acetic acid to acetic anhydride in the vapour fraction removed from the flash separation zone is maintained at greater than or equal to 1, preferably greater than or equal to 1.2.