bis(p-bromobenzoyl) disulfide | 16020-57-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(p-bromobenzoyl) disulfide
• 英文别名: p,p'-Dibromdibenzoyldisulfid；bis-(4-bromo-benzoyl)-disulfane；Bis-(4-brom-benzoyl)-disulfan；S-(4-bromobenzoyl)sulfanyl 4-bromobenzenecarbothioate
• CAS: 16020-57-8
• 化学式: C₁₄H₈Br₂O₂S₂
• 分子量: 432.156
• InChiKey: KBCCITYAXQCOCH-UHFFFAOYSA-N

物化性质

• 熔点：
  115 °C
• 沸点：
  536.0±60.0 °C(Predicted)
• 密度：
  1.795±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  84.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-溴苯甲酰氯 在 polyethylene glycol 400 、 sodium disulfide 作用下， 以 苯 为溶剂， 反应 3.0h， 以89%的产率得到bis(p-bromobenzoyl) disulfide
  参考文献：
  名称：

  A Convenient Method for the Synthesis of Diacyl Disulfides

  摘要：

  A simple and general method for the synthesis of diacyl disulfides is reported. Sulfur is allowed to react with sodium hydroxide to give sodium disulfide at 65 degrees C under PTC, which can react with acyl halides to afford diacyl disulfides in good to excellent isolated yields. The effects of solvents and phase transfer catalysts are discussed.

  DOI：

  10.1080/00397919508013426

文献信息

• Aroyl disulfides as promoter-modifiers for copolymerization of butadiene and styrene
  作者：Robert L. Frank、James R. Blegen、Archie Deutschman

  DOI：10.1002/pol.1948.120030108

  日期：1948.2

  veratroyl, p-bromobenzoyl, p-phenylbenzoyl, p-benzoylbenzoyl, p-methylsulfonylbenzoyl, p(N,N-dimethylsulfonamido)-benzoyl and -naphthoyl disulfides are promoters of the emulsion copolymerization of butadiene and styrene, but exhibit little effect on the polymer properties. Furoyl, phenyl, p-chlorophenyl and p-bromophenyl disulfides are neither promoters nor modifiers.

  苯甲酰基、茴香酰基、藜芦酰基、对溴苯甲酰基、对苯基苯甲酰基、对苯甲酰基苯甲酰基、对甲磺酰基苯甲酰基、对(N,N-二甲基磺酰氨基)-苯甲酰基和-萘甲酰基二硫化物是丁二烯和苯乙烯乳液共聚的促进剂，但表现出很小对聚合物性能的影响。呋喃酰基、苯基、对氯苯基和对溴苯基二硫化物既不是促进剂也不是改性剂。
• PROCESS FOR PRODUCING POLYMER TERMINATED WITH OPTIONALLY PROTECTED FUNCTIONAL GROUP
  申请人：KURARAY Co. LTD.

  公开号：EP0704460A1

  公开（公告）日：1996-04-03

  A process for producing polymers having terminal functional group which may be protected, comprises polymerizing a radical-polymerizable monomer with a polymerization initiator comprising at least one member selected from the group (A) consisting of thio-S-carboxylic acids represented by the following general formula (1) and dithiocarboxylic acids represented by the following general formula (2) and at least one member selected from the group (B) consisting of polysulfides represented by the following general formula (3), polysulfides represented by the following general formula (4) and sulfoxides: wherein R¹ represents a hydrocarbon group which may have a substituent including functional group; wherein R² represents a hydrocarbon group which may have a substituent including functional group; wherein R³ and R⁴ each represents a hydrocarbon group which may have a substituent including functional group and n is an integer of 2 or more; and         R⁵- (S)m- R⁶     (4) wherein R⁵ and R⁶ each represents a hydrocarbon group having a functional group and m is an integer of 2 or more. This process can produce polymers with which functional groups have been introduced into one end or both ends thereof, irrespective of the rate of polymerization or the degree of polymerization of the polymer that forms.

  一种生产具有可被保护的末端官能团的聚合物的工艺，包括用聚合引发剂聚合可自由基聚合的单体，聚合引发剂包括至少一种选自以下通式(1)代表的硫代-S-羧酸和以下通式(2)代表的二硫代羧酸组成的基团(A)，以及至少一种选自以下通式(3)代表的多硫化物、以下通式(4)代表的多硫化物和氧化硫组成的基团(B)： 其中 R¹ 代表烃基，该烃基可能具有包括官能团在内的取代基； 其中 R² 代表可具有包括官能团在内的取代基的烃基； 其中 R³ 和 R⁴ 各自代表一个可具有包括官能团在内的取代基的烃基，且 n 为 2 或 2 以上的整数；以及 R⁵- (S)m- R⁶ (4) 其中，R⁵ 和 R⁶ 分别代表具有官能团的烃基，m 为 2 或 2 以上的整数。无论聚合速度或形成的聚合物的聚合度如何，该工艺都能生产出在一端或两端引入官能团的聚合物。
• US5847061A
  申请人：——

  公开号：US5847061A

  公开（公告）日：1998-12-08
• A Convenient Method for the Synthesis of Diacyl Disulfides
  作者：Jin-xian Wang(Chin-Hsien Wang)、Wenfeng Cui、Yulai Hu、Kai Zhao

  DOI：10.1080/00397919508013426

  日期：1995.3

  A simple and general method for the synthesis of diacyl disulfides is reported. Sulfur is allowed to react with sodium hydroxide to give sodium disulfide at 65 degrees C under PTC, which can react with acyl halides to afford diacyl disulfides in good to excellent isolated yields. The effects of solvents and phase transfer catalysts are discussed.