triphenyltin(IV)pyrrolidinyldithiocarbamate | 26879-86-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: triphenyltin(IV)pyrrolidinyldithiocarbamate
• 英文别名: [Sn(pyrrolidinedithiocarbamate)(C6H5)3]；1-{[(Triphenylstannyl)sulfanyl]carbonothioyl}pyrrolidine；triphenylstannyl pyrrolidine-1-carbodithioate
• CAS: 26879-86-7
• 化学式: C₂₃H₂₃NS₂Sn
• 分子量: 496.284
• InChiKey: BUYQXSDRNWNFTO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.77
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  60.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  triphenyltin(IV)pyrrolidinyldithiocarbamate 以 neat (no solvent) 为溶剂， 生成 tin (II) sulfide 、 tin(III) sulfide
  参考文献：
  名称：

  Synthesis, characterisation and thermal decomposition of tin(IV) dithiocarbamate derivatives – single source precursors for tin sulfide powders

  摘要：

  The reaction of ammonium pyrrolidinedithiocarbamate with SnPh2Cl2 and SnPh3Cl produced in good yield the compounds [Sn{S2CN(CH2)(4)}(2){C6H5}(2)] (.) toluene (1) and Sn{S2CN(CH2)(4)}{C6H5}(3) (2). They were fully characterised by multinuclear NMR [H-1, C-13{H-1} and Sn-119{H-1}] and Sn-119 Mossbauer spectroscopies. In addition the structure of 1 was determined, and 2 was revised by X-ray crystallographic studies. Finally, thermal decomposition experiments were carried out for both compounds in nitrogen and the residues were characterised by X-ray powder diffraction (XRD), X-ray electron probe microanalysis (EPMA), scanning electron microscopy (SEM) and Sn-119 Mossbauer spectroscopy. The results clearly indicate the formation of a mixture of gamma-Sn2S3 and SnS, both orthorhombic phases. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.06.007
• 作为产物：
  描述：

  三苯基氯化锡 、 sodium pyrrolidine-N-carbodithioate 以 乙醇 为溶剂， 以91%的产率得到triphenyltin(IV)pyrrolidinyldithiocarbamate
  参考文献：
  名称：

  Diorganotin（IV）二硫代氨基甲酸酯配合物作为阴离子结合的显色传感器

  摘要：

  一种双核chlorodiphenyltin（IV）二硫代氨基甲酸配合物（1）和通式博士四个单核配合物2的Sn（S 2 CNR）氯（2，3，5，和6）已经被合成和表征无论是在固态和溶液。对于复合物的X射线结构1，3和6证实锡原子，其中二硫代氨基甲酸不对称配位体的螯合物的金属中心的五配位几何构周围。如119所示在Sn NMR光谱学中，固态观察到的五配位几何保留在溶液中。这些chlorodiphenyltin（IV）二硫代氨基甲酸配合物在生物学相关的阴离子，如醋酸盐，通式的二羧酸的存在下的稳定性- OOC-（CH 2）ñ -COO - （Ñ  = 2-8），磷酸二氢盐，硫酸氢盐，和卤化物已在乙腈溶液中进行了检查。对于所有这些有机锡（IV）配合物，配位体的位移（即，氯离子和二硫代氨基甲酸酯）是在单阴离子（例如乙酸根，磷酸二氢根，硫酸氢根和氟离子）的存在下发生的。基于UV-Vis，1 H，13 C和119

  DOI：

  10.1016/j.poly.2009.09.010

文献信息

• Organogermanium(IV), -tin(IV) and -lead(IV) esters of tetramethylenedithiocarbamic acid. The crystal and molecular structure of (tetramethylenedithiocarbamato)triphenyltin(IV) and lead(IV)
  作者：E. M. Holt、F. A. K. Nasser、A. Wilson、J. J. Zuckerman

  DOI：10.1021/om00131a001

  日期：1985.12
• Zhu, Dezhong; Zhang, Rufen; Ma, Chunlin, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2002, vol. 41, # 8, p. 1634 - 1638
  作者：Zhu, Dezhong、Zhang, Rufen、Ma, Chunlin、Yin, Handong

  DOI：——

  日期：——
• Diorganotin(IV) dithiocarbamate complexes as chromogenic sensors of anion binding
  作者：Juan Pablo Fuentes-Martínez、Isaim Toledo-Martínez、Perla Román-Bravo、Patricia García y García、Carolina Godoy-Alcántar、Marcela López-Cardoso、Hugo Morales-Rojas

  DOI：10.1016/j.poly.2009.09.010

  日期：2009.12

  in solution. The stability of these chlorodiphenyltin(IV) dithiocarbamate complexes in the presence of biologically relevant anions such as acetate, dicarboxylates of general formula −OOC-(CH2)n-COO− (n = 2–8), dihydrogenphosphate, hydrogensulfate, and halides has been examined in acetonitrile solutions. For all of these organotin(IV) complexes the displacement of the coordinated ligands (i.e., chloride

  一种双核chlorodiphenyltin（IV）二硫代氨基甲酸配合物（1）和通式博士四个单核配合物2的Sn（S 2 CNR）氯（2，3，5，和6）已经被合成和表征无论是在固态和溶液。对于复合物的X射线结构1，3和6证实锡原子，其中二硫代氨基甲酸不对称配位体的螯合物的金属中心的五配位几何构周围。如119所示在Sn NMR光谱学中，固态观察到的五配位几何保留在溶液中。这些chlorodiphenyltin（IV）二硫代氨基甲酸配合物在生物学相关的阴离子，如醋酸盐，通式的二羧酸的存在下的稳定性- OOC-（CH 2）ñ -COO - （Ñ  = 2-8），磷酸二氢盐，硫酸氢盐，和卤化物已在乙腈溶液中进行了检查。对于所有这些有机锡（IV）配合物，配位体的位移（即，氯离子和二硫代氨基甲酸酯）是在单阴离子（例如乙酸根，磷酸二氢根，硫酸氢根和氟离子）的存在下发生的。基于UV-Vis，1 H，13 C和119
• Synthesis, characterisation and thermal decomposition of tin(IV) dithiocarbamate derivatives – single source precursors for tin sulfide powders
  作者：D.C. Menezes、G.M. de Lima、A.O. Porto、C.L. Donnici、J.D. Ardisson、A.C. Doriguetto、J. Ellena

  DOI：10.1016/j.poly.2004.06.007

  日期：2004.7

  The reaction of ammonium pyrrolidinedithiocarbamate with SnPh2Cl2 and SnPh3Cl produced in good yield the compounds [SnS2CN(CH2)(4)}(2)C6H5}(2)] (.) toluene (1) and SnS2CN(CH2)(4)}C6H5}(3) (2). They were fully characterised by multinuclear NMR [H-1, C-13H-1} and Sn-119H-1}] and Sn-119 Mossbauer spectroscopies. In addition the structure of 1 was determined, and 2 was revised by X-ray crystallographic studies. Finally, thermal decomposition experiments were carried out for both compounds in nitrogen and the residues were characterised by X-ray powder diffraction (XRD), X-ray electron probe microanalysis (EPMA), scanning electron microscopy (SEM) and Sn-119 Mossbauer spectroscopy. The results clearly indicate the formation of a mixture of gamma-Sn2S3 and SnS, both orthorhombic phases. (C) 2004 Elsevier Ltd. All rights reserved.