Deca-7,9-diyn-1-ol | 333754-08-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Deca-7,9-diyn-1-ol
• CAS: 333754-08-8
• 化学式: C₁₀H₁₄O
• 分子量: 150.221
• InChiKey: WPELVRWLJJHKFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Deca-7,9-diyn-1-ol 在 chromium(VI) oxide 、 copper(l) iodide 、 硫酸 、 三乙胺 、 palladium dichloride 作用下， 以 甲醇 为溶剂， 生成 (Z)-hexadec-11-en-7,9-diynoic acid
  参考文献：
  名称：

  Synthesis of Polyacetylenic Acids Isolated from Heisteria acuminata

  摘要：

  [GRAPHICS]Four linear polyacetylenic compounds were synthesized. Pentadeca-6,8,10-triynoic acid 1 and octadeca-8,10,12-triynoic acid 2 were synthesized by using acetylene coupling reactions. The syntheses of (Z)-hexadec-11-en-7,9-diynoic acid 3 and (Z)-octadec-12-en-7,9-diynoic acid 4 by using vinylic telluride coupling reactions were accomplished.

  DOI：

  10.1021/ol006946v
• 作为产物：
  描述：

  2-辛炔-1-醇 在 四氢吡咯 、 sodium hydroxide 、 copper(l) iodide 、 正丁基锂 、 碘 、 potassium salt of 1,3-diaminopropane 作用下， 以 四氢呋喃 、 xylene 为溶剂， 生成 Deca-7,9-diyn-1-ol
  参考文献：
  名称：

  Synthesis of Polyacetylenic Acids Isolated from Heisteria acuminata

  摘要：

  [GRAPHICS]Four linear polyacetylenic compounds were synthesized. Pentadeca-6,8,10-triynoic acid 1 and octadeca-8,10,12-triynoic acid 2 were synthesized by using acetylene coupling reactions. The syntheses of (Z)-hexadec-11-en-7,9-diynoic acid 3 and (Z)-octadec-12-en-7,9-diynoic acid 4 by using vinylic telluride coupling reactions were accomplished.

  DOI：

  10.1021/ol006946v

文献信息

• Synthesis of Polyacetylenic Acids Isolated from <i>Heisteria</i> <i>a</i><i>cuminata</i>
  作者：Gilson Zeni、Rodrigo B. Panatieri、Eliseo Lissner、Paulo H. Menezes、Antonio L. Braga、Hélio A. Stefani

  DOI：10.1021/ol006946v

  日期：2001.3.1

  [GRAPHICS]Four linear polyacetylenic compounds were synthesized. Pentadeca-6,8,10-triynoic acid 1 and octadeca-8,10,12-triynoic acid 2 were synthesized by using acetylene coupling reactions. The syntheses of (Z)-hexadec-11-en-7,9-diynoic acid 3 and (Z)-octadec-12-en-7,9-diynoic acid 4 by using vinylic telluride coupling reactions were accomplished.